Journal of Power Sources, volume 480, pages 228840

KTiOPO4-structured electrode materials for metal-ion batteries: A review

Fedotov Stanislav S. ¹

Samarin Aleksandr Sh ¹

Antipov Evgeny V. ^{1, 2}

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Skoltech Center for Electrochemical Energy Storage, Skolkovo Institute of Science and Technology, 121205, Moscow, Russian Federation |

Department of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russian Federation |

Publication type: Journal Article

Publication date: 2020-12-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2020.228840

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Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

The success story of the triphylite-type LiFePO 4 immediately boosted the development of numerous classes of polyanion-based electrode materials for metal-ion batteries. A number of advantages including thermal and structural stability, polyanionic inductive effect, and variety of crystal types and chemical compositions render these materials attractive for grid and large-scale applications ensuring high safety standards, environmental friendliness and cost benefits. In this review, we focus on a specific family of polyanion-based electrode materials adopting the KTiOPO 4 -type structure that captured particular attention recently due to the unique 3D-framework. This framework features thermal, structural and long-term electrochemical cycling stability, fast ionic transport, possibility to accommodate two alkali ions per transition metal cation enabling multi-electron transitions, and unprecedented high electrode potentials for a specific redox couple among all known polyanion materials. The recent advances and overview of KTiOPO 4 -type and related positive and negative electrode materials for metal-ion batteries are presented with a special emphasis on the interrelations between crystal structure peculiarities and electrochemical properties. • Review summarizes recent development on KTiOPO 4 -structured electrode materials. • Rapidly growing family of materials amounts to more than 20 representatives. • KTiOPO 4 -related 3D-framework features fast ionic transport and overall stability. • Structural peculiarities results in extraordinarily high electrode potentials. • Two-electron transitions turn out enabled with an appropriate redox center.

By date By citations

Citations by journals

	1 2
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 2, 5.26% Journal of the Electrochemical Society 2 publications, 5.26%
Journal of Power Sources	Journal of Power Sources, 2, 5.26% Journal of Power Sources 2 publications, 5.26%
Energy Storage Materials	Energy Storage Materials, 2, 5.26% Energy Storage Materials 2 publications, 5.26%
Chemistry of Materials	Chemistry of Materials, 2, 5.26% Chemistry of Materials 2 publications, 5.26%
Chemical Science	Chemical Science, 2, 5.26% Chemical Science 2 publications, 5.26%
Inorganic Chemistry	Inorganic Chemistry, 1, 2.63% Inorganic Chemistry 1 publication, 2.63%
Nature Communications	Nature Communications, 1, 2.63% Nature Communications 1 publication, 2.63%
Solid State Ionics	Solid State Ionics, 1, 2.63% Solid State Ionics 1 publication, 2.63%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 2.63% ACS Applied Energy Materials 1 publication, 2.63%
Physical Review B	Physical Review B, 1, 2.63% Physical Review B 1 publication, 2.63%
Light: Science and Applications	Light: Science and Applications, 1, 2.63% Light: Science and Applications 1 publication, 2.63%
Advanced Functional Materials	Advanced Functional Materials, 1, 2.63% Advanced Functional Materials 1 publication, 2.63%
Journal of Energy Chemistry	Journal of Energy Chemistry, 1, 2.63% Journal of Energy Chemistry 1 publication, 2.63%
Science Bulletin	Science Bulletin, 1, 2.63% Science Bulletin 1 publication, 2.63%
Journal of Solid State Chemistry	Journal of Solid State Chemistry, 1, 2.63% Journal of Solid State Chemistry 1 publication, 2.63%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 2.63% Journal of Physical Chemistry C 1 publication, 2.63%
Energy & Fuels	Energy & Fuels, 1, 2.63% Energy & Fuels 1 publication, 2.63%
Materials Letters	Materials Letters, 1, 2.63% Materials Letters 1 publication, 2.63%
Physical Review Research	Physical Review Research, 1, 2.63% Physical Review Research 1 publication, 2.63%
Clean Technologies	Clean Technologies, 1, 2.63% Clean Technologies 1 publication, 2.63%
Physical Review Materials	Physical Review Materials, 1, 2.63% Physical Review Materials 1 publication, 2.63%
Advanced Energy Materials	Advanced Energy Materials, 1, 2.63% Advanced Energy Materials 1 publication, 2.63%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 2.63% ACS applied materials & interfaces 1 publication, 2.63%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 2.63% Journal of Alloys and Compounds 1 publication, 2.63%
Green Energy and Environment	Green Energy and Environment, 1, 2.63% Green Energy and Environment 1 publication, 2.63%
Dalton Transactions	Dalton Transactions, 1, 2.63% Dalton Transactions 1 publication, 2.63%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 2.63% Angewandte Chemie - International Edition 1 publication, 2.63%
Angewandte Chemie	Angewandte Chemie, 1, 2.63% Angewandte Chemie 1 publication, 2.63%
Crystals	Crystals, 1, 2.63% Crystals 1 publication, 2.63%
	1 2

Citations by publishers

	2 4 6 8 10
Elsevier	Elsevier, 10, 26.32% Elsevier 10 publications, 26.32%
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 18.42% American Chemical Society (ACS) 7 publications, 18.42%
Wiley	Wiley, 5, 13.16% Wiley 5 publications, 13.16%
American Physical Society (APS)	American Physical Society (APS), 3, 7.89% American Physical Society (APS) 3 publications, 7.89%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 7.89% Royal Society of Chemistry (RSC) 3 publications, 7.89%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 3, 7.89% Multidisciplinary Digital Publishing Institute (MDPI) 3 publications, 7.89%
Springer Nature	Springer Nature, 2, 5.26% Springer Nature 2 publications, 5.26%
The Electrochemical Society	The Electrochemical Society, 2, 5.26% The Electrochemical Society 2 publications, 5.26%
KeAi Communications Co.	KeAi Communications Co., 1, 2.63% KeAi Communications Co. 1 publication, 2.63%
	2 4 6 8 10

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Fedotov S. S. et al. KTiOPO4-structured electrode materials for metal-ion batteries: A review // Journal of Power Sources. 2020. Vol. 480. p. 228840.

GOST all authors (up to 50) Copy

Fedotov S. S., Samarin A. S., Antipov E. V. KTiOPO4-structured electrode materials for metal-ion batteries: A review // Journal of Power Sources. 2020. Vol. 480. p. 228840.

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2020.228840

UR - https://doi.org/10.1016%2Fj.jpowsour.2020.228840

TI - KTiOPO4-structured electrode materials for metal-ion batteries: A review

T2 - Journal of Power Sources

AU - Fedotov, Stanislav S.

AU - Samarin, Aleksandr Sh

AU - Antipov, Evgeny V.

PY - 2020

DA - 2020/12/01 00:00:00

PB - Elsevier

SP - 228840

VL - 480

SN - 0378-7753

ER -

BibTex

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BibTex Copy

@article{2020_Fedotov,

author = {Stanislav S. Fedotov and Aleksandr Sh Samarin and Evgeny V. Antipov},

title = {KTiOPO4-structured electrode materials for metal-ion batteries: A review},

journal = {Journal of Power Sources},

year = {2020},

volume = {480},

publisher = {Elsevier},

month = {dec},

url = {https://doi.org/10.1016%2Fj.jpowsour.2020.228840},

pages = {228840},

doi = {10.1016/j.jpowsour.2020.228840}

}

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Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)

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