Journal of Power Sources, volume 518, pages 230769

High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material

Buryak Nikita S ¹

Anishchenko Dmitrii V ^{2, 3}

Levin Eduard E. ²

Ryazantsev Sergey V ⁴

Martin-Diaconescu Vlad ⁵

Zakharkin Maxim V. ¹

Nikitina Victoria A. ^{2, 6}

Antipov Evgeny V. ^{2, 6}

Hide authors affiliations Show authors affiliations: 6 affiliations

Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1-3, Moscow 119991, Russia. |

Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, 119991, Russia |

Institute of Chemistry, St. Petersburg State University, Universitetskaya emb. 7/9, St. Petersburg, 199034, Russia |

⁴

Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel Str.3, Moscow, 121205, Russia |

⁵

ALBA Synchrotron Light Source, Barcelona, 08290, Spain |

⁶

Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel str. 3, Moscow, 121205, Russia |

Publication type: Journal Article

Publication date: 2022-01-01

Elsevier

Journal: Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor: 9.2

ISSN: 03787753

DOI: 10.1016/j.jpowsour.2021.230769

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Physical and Theoretical Chemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

The recently demonstrated possibility of high-voltage extraction of more than 2 Na ions per Na 4 MnV(PO 4 ) 3 formula unit is considered as a possible way to increase the specific energy of this material, which would open up prospects for its application in sodium-ion batteries. However, for the Na 4 MnV(PO 4 ) 3 material and for a wide group of related NASICON-structured materials, high-voltage Na extraction was demonstrated to lead to a rapid decrease in capacity and a sharp increase in hysteresis between the charge and discharge curves. In this work, we use electrochemical and structural analysis to elucidate the reasons for the degradation observed after deep desodiation of Na 4 MnV(PO 4 ) 3 . X-ray diffraction analysis of the electrodes after cycling demonstrates that a phase transformation is initiated when the anodic potential limit exceeds 3.8 V, which results in the formation of distorted NASICON-type phases and gradual amorphization. X-ray absorption spectroscopy studies suggest that the observed detrimental phase transitions might be triggered by the changes in the local environment of oxidized vanadium, which destabilize the structure. We thus demonstrate that the degradation of the Na 4 MnV(PO 4 ) 3 material is of thermodynamic origin, with its consequences being reflected in a dramatically decreased de/intercalation rates and a rapid deterioration in the material performance. • High-voltage Na extraction from Na 4 MnV(PO 4 ) 3 triggers surface amorphization. • Surface changes lead to a rapid capacity fade and a continuous increase in hysteresis. • Phase transition is likely due to the instability of V +5 in the desodiated structure.

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Buryak N. S. et al. High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material // Journal of Power Sources. 2022. Vol. 518. p. 230769.

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Buryak N. S., Anishchenko D. V., Levin E. E., Ryazantsev S. V., Martin-Diaconescu V., Zakharkin M. V., Nikitina V. A., Antipov E. V. High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material // Journal of Power Sources. 2022. Vol. 518. p. 230769.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.jpowsour.2021.230769

UR - https://doi.org/10.1016%2Fj.jpowsour.2021.230769

TI - High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material

T2 - Journal of Power Sources

AU - Buryak, Nikita S

AU - Levin, Eduard E.

AU - Ryazantsev, Sergey V

AU - Martin-Diaconescu, Vlad

AU - Zakharkin, Maxim V.

AU - Nikitina, Victoria A.

AU - Antipov, Evgeny V.

AU - Anishchenko, Dmitrii V

PY - 2022

DA - 2022/01/01 00:00:00

PB - Elsevier

SP - 230769

VL - 518

SN - 0378-7753

ER -

BibTex

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BibTex Copy

@article{2022_Buryak,

author = {Nikita S Buryak and Eduard E. Levin and Sergey V Ryazantsev and Vlad Martin-Diaconescu and Maxim V. Zakharkin and Victoria A. Nikitina and Evgeny V. Antipov and Dmitrii V Anishchenko},

title = {High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material},

journal = {Journal of Power Sources},

year = {2022},

volume = {518},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016%2Fj.jpowsour.2021.230769},

pages = {230769},

doi = {10.1016/j.jpowsour.2021.230769}

}

Found error?

Publisher

Elsevier

Journal

Journal of Power Sources

Quartile SCImago

Quartile WOS

Impact factor

9.2

ISSN

03787753 (Print)

Labs

Laboratory of Materials for Electrochemical Processes

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