New Sr1-x-zRx(NH4)zF2+x-z (R = Yb, Er) solid solution as precursor for high efficiency up-conversion luminophor and optical ceramics on the base of strontium fluoride
Yu A Rozhnova
1
,
Sergey Kuznetsov
2
,
A A Luginina
3
,
V. Voronov
2
,
Roman P Ermakov
2
,
V A Usachev
4
,
N E Kononenko
4
,
V. V. Ivanov
5
,
Publication type: Journal Article
Publication date: 2016-04-01
scimago Q1
wos Q2
SJR: 0.808
CiteScore: 8.5
Impact factor: 4.7
ISSN: 02540584, 18793312
Condensed Matter Physics
General Materials Science
Abstract
Abstract In this paper, we describe the use of self-fluorinating conditions for the thermal treatment of Sr1−x−y−zYbxEry(NH4)zF2+x+y−z precursor for the preparation of high-efficiency SrF2:Yb:Er up-converter powders. We report actual SrF2:Yb:Er compositions with up-conversion efficiencies exceeding 4% (pumping power 1 W/cm2 at 974 nm wavelength) and describe the synthesis of ceramics with higher than 80% transmittance at 0.42–7.0 μm. The latter ceramics can be used as a potential IR radiation visualizer. For the first time, we present an analysis of correlation between up-conversion luminescence energy yield and specimen composition for SrF2:Yb:Er nanopowders. Taking into account the observed erbium ion up-conversion luminescence in the red part of the visible spectrum, we recommend certain SrF2:Yb:Er compositions for practical application in photodynamic cancer therapy.
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Rozhnova Yu. A. et al. New Sr1-x-zRx(NH4)zF2+x-z (R = Yb, Er) solid solution as precursor for high efficiency up-conversion luminophor and optical ceramics on the base of strontium fluoride // Materials Chemistry and Physics. 2016. Vol. 172. pp. 150-157.
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Rozhnova Yu. A., Kuznetsov S., Luginina A. A., Voronov V., Ryabova A., Pominova D. V., Ermakov R. P., Usachev V. A., Kononenko N. E., Baranchikov A. E., Ivanov V. V., P. P. Fedorov P. P. F. New Sr1-x-zRx(NH4)zF2+x-z (R = Yb, Er) solid solution as precursor for high efficiency up-conversion luminophor and optical ceramics on the base of strontium fluoride // Materials Chemistry and Physics. 2016. Vol. 172. pp. 150-157.
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TY - JOUR
DO - 10.1016/j.matchemphys.2016.01.055
UR - https://linkinghub.elsevier.com/retrieve/pii/S0254058416300554
TI - New Sr1-x-zRx(NH4)zF2+x-z (R = Yb, Er) solid solution as precursor for high efficiency up-conversion luminophor and optical ceramics on the base of strontium fluoride
T2 - Materials Chemistry and Physics
AU - Rozhnova, Yu A
AU - Kuznetsov, Sergey
AU - Luginina, A A
AU - Voronov, V.
AU - Ryabova, Anastasia
AU - Pominova, Daria V.
AU - Ermakov, Roman P
AU - Usachev, V A
AU - Kononenko, N E
AU - Baranchikov, Alexander E
AU - Ivanov, V. V.
AU - P. P. Fedorov, P. P. Fedorov
PY - 2016
DA - 2016/04/01
PB - Elsevier
SP - 150-157
VL - 172
SN - 0254-0584
SN - 1879-3312
ER -
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@article{2016_Rozhnova,
author = {Yu A Rozhnova and Sergey Kuznetsov and A A Luginina and V. Voronov and Anastasia Ryabova and Daria V. Pominova and Roman P Ermakov and V A Usachev and N E Kononenko and Alexander E Baranchikov and V. V. Ivanov and P. P. Fedorov P. P. Fedorov},
title = {New Sr1-x-zRx(NH4)zF2+x-z (R = Yb, Er) solid solution as precursor for high efficiency up-conversion luminophor and optical ceramics on the base of strontium fluoride},
journal = {Materials Chemistry and Physics},
year = {2016},
volume = {172},
publisher = {Elsevier},
month = {apr},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0254058416300554},
pages = {150--157},
doi = {10.1016/j.matchemphys.2016.01.055}
}