Materials Research Bulletin, volume 87, pages 54-60
Doping of Bi4Fe5O13F with pentagonal Cairo lattice with Cr and Mn: Synthesis, structure and magnetic properties
Rozova Marina G
1
,
Grigoriev Vladislav V
1
,
Tyablikov Oleg A.
1
,
Filimonov Dmitry S
1
,
Zakharov Konstantin V.
2
,
Volkova O.
2, 3
,
Vasiliev Alexander
2, 3
,
Abakumov Artem M.
4, 5, 6
Publication type: Journal Article
Publication date: 2017-03-01
Journal:
Materials Research Bulletin
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 5.4
ISSN: 00255408
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
Abstract The substitution of Cr 3+ and Mn 3+ for Fe 3+ in the Bi 4 Fe 5 O 13 F oxyfluoride featuring the magnetically frustrated pentagonal Cairo lattice is reported. Bi 4 Fe 4.1 Cr 0.9 O 13 F and Bi 4 Fe 4.2 Mn 0.8 O 13 F have been prepared using a solid state reaction in inert atmosphere. Their crystal structures were studied with transmission electron microscopy, powder X-ray diffraction and 57 Fe Mossbauer spectroscopy (S.G. P 4 2 / mbc , a = 8.27836(2) A, c = 18.00330(9) A, R F = 0.031 (Bi 4 Fe 4.1 Cr 0.9 O 13 F), a = 8.29535(3) A, c = 18.0060(1) A, R F = 0.027 (Bi 4 Fe 4.2 Mn 0.8 O 13 F)). The structures are formed by infinite rutile-like chains of the edge-sharing BO 6 octahedra (B—transition metal cations) linked by the Fe 2 O 7 groups of two corner-sharing tetrahedra. The voids in thus formed framework are occupied by the Bi 4 F tetrahedra. The 57 Fe Mossbauer spectroscopy reveals that Cr 3+ and Mn 3+ replace Fe 3+ exclusively at the octahedral positions. The Mn- and Cr-doped compounds demonstrate antiferromagnetic ordering below T N = 165 K and 120 K, respectively.
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Physical Review B
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Physical Review B
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American Physical Society (APS)
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American Physical Society (APS)
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Rozova M. G. et al. Doping of Bi4Fe5O13F with pentagonal Cairo lattice with Cr and Mn: Synthesis, structure and magnetic properties // Materials Research Bulletin. 2017. Vol. 87. pp. 54-60.
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Rozova M. G., Grigoriev V. V., Tyablikov O. A., Filimonov D. S., Zakharov K. V., Volkova O., Vasiliev A., Antipov E. V., Abakumov A. M. Doping of Bi4Fe5O13F with pentagonal Cairo lattice with Cr and Mn: Synthesis, structure and magnetic properties // Materials Research Bulletin. 2017. Vol. 87. pp. 54-60.
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TY - JOUR
DO - 10.1016/j.materresbull.2016.11.018
UR - https://doi.org/10.1016%2Fj.materresbull.2016.11.018
TI - Doping of Bi4Fe5O13F with pentagonal Cairo lattice with Cr and Mn: Synthesis, structure and magnetic properties
T2 - Materials Research Bulletin
AU - Rozova, Marina G
AU - Grigoriev, Vladislav V
AU - Tyablikov, Oleg A.
AU - Filimonov, Dmitry S
AU - Zakharov, Konstantin V.
AU - Volkova, O.
AU - Vasiliev, Alexander
AU - Antipov, Evgeny V.
AU - Abakumov, Artem M.
PY - 2017
DA - 2017/03/01 00:00:00
PB - Elsevier
SP - 54-60
VL - 87
SN - 0025-5408
ER -
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@article{2017_Rozova,
author = {Marina G Rozova and Vladislav V Grigoriev and Oleg A. Tyablikov and Dmitry S Filimonov and Konstantin V. Zakharov and O. Volkova and Alexander Vasiliev and Evgeny V. Antipov and Artem M. Abakumov},
title = {Doping of Bi4Fe5O13F with pentagonal Cairo lattice with Cr and Mn: Synthesis, structure and magnetic properties},
journal = {Materials Research Bulletin},
year = {2017},
volume = {87},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016%2Fj.materresbull.2016.11.018},
pages = {54--60},
doi = {10.1016/j.materresbull.2016.11.018}
}