Mendeleev Communications, volume 29, issue 4, pages 438-440
Selective Hofmann alkylation of aromatic-aliphatic diamines in the presence of carbon dioxide
Publication type: Journal Article
Publication date: 2019-07-01
Journal:
Mendeleev Communications
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Selective Hofmann alkylation at arylamino group in carbon dioxide medium was demonstrated on model diamines containing aliphatic and aromatic primary amino groups, namely, 2-H2NC6H4CH2NH2, 3-H2NC6H4CH(Me)NH2, and 4-H2NC6H4CH2CH2NH2. Depending on the spatial factors, di- or trialkylarylammonium derivatives are selectively formed in amide solvents (DMF, DMA) without additional base.
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Balybin A. G. et al. Selective Hofmann alkylation of aromatic-aliphatic diamines in the presence of carbon dioxide // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 438-440.
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Balybin A. G., Panov Y. M., Erkhova L. V., Lemenovskii D. A., Krut'ko D. P. Selective Hofmann alkylation of aromatic-aliphatic diamines in the presence of carbon dioxide // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 438-440.
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TY - JOUR
DO - 10.1016/j.mencom.2019.07.028
UR - https://doi.org/10.1016%2Fj.mencom.2019.07.028
TI - Selective Hofmann alkylation of aromatic-aliphatic diamines in the presence of carbon dioxide
T2 - Mendeleev Communications
AU - Balybin, Alexei G
AU - Panov, Yuri M
AU - Erkhova, Ludmila V
AU - Lemenovskii, Dmitry A
AU - Krut'ko, Dmitry P.
PY - 2019
DA - 2019/07/01 00:00:00
PB - Elsevier
SP - 438-440
IS - 4
VL - 29
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2019_Balybin,
author = {Alexei G Balybin and Yuri M Panov and Ludmila V Erkhova and Dmitry A Lemenovskii and Dmitry P. Krut'ko},
title = {Selective Hofmann alkylation of aromatic-aliphatic diamines in the presence of carbon dioxide},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016%2Fj.mencom.2019.07.028},
number = {4},
pages = {438--440},
doi = {10.1016/j.mencom.2019.07.028}
}
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MLA
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Balybin, Alexei G., et al. “Selective Hofmann alkylation of aromatic-aliphatic diamines in the presence of carbon dioxide.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 438-440. https://doi.org/10.1016%2Fj.mencom.2019.07.028.