Structure-defining interactions in the salt cocrystals of [(Me5 C5 )2 Fe]+I3 −–XC6 H4 OH (X = Cl, I): weak noncovalent vs. strong ionic bonding
Publication type: Journal Article
Publication date: 2020-09-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
In the cocrystalline salts [(Me5C5)2Fe]+I3−/(4-XC6H4OH) (X = Cl, I), the directionality of X ⋯ I − I 2 halogen bonds is a significant packing factor notwithstanding their relatively low energies (∼10 kcal mol−1), as compared to the fivefold stronger ionic bonding between [(Me5C5)2Fe+] and [I3]− (∼50 kcal mol−1). This adds significant details to the structural landscape of [(Me5C5)2Fe+]I3 and offers an illustrative example of the stronger structure-defining effect of halogen bonding over the hydrogen one.
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Torubaev Y. V. et al. Structure-defining interactions in the salt cocrystals of [(Me5C5)2Fe]+I3−–XC6H4OH (X = Cl, I): weak noncovalent vs. strong ionic bonding // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 580-582.
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Torubaev Y. V., Skabitsky I. V., Lyssenko K. A. Structure-defining interactions in the salt cocrystals of [(Me5C5)2Fe]+I3−–XC6H4OH (X = Cl, I): weak noncovalent vs. strong ionic bonding // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 580-582.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.009
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943620302339
TI - Structure-defining interactions in the salt cocrystals of [(Me5C5)2Fe]+I3−–XC6H4OH (X = Cl, I): weak noncovalent vs. strong ionic bonding
T2 - Mendeleev Communications
AU - Torubaev, Yu. V.
AU - Skabitsky, I. V.
AU - Lyssenko, Konstantin A.
PY - 2020
DA - 2020/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 580-582
IS - 5
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2020_Torubaev,
author = {Yu. V. Torubaev and I. V. Skabitsky and Konstantin A. Lyssenko},
title = {Structure-defining interactions in the salt cocrystals of [(Me5C5)2Fe]+I3−–XC6H4OH (X = Cl, I): weak noncovalent vs. strong ionic bonding},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943620302339},
number = {5},
pages = {580--582},
doi = {10.1016/j.mencom.2020.09.009}
}
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MLA
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Torubaev, Yu. V., et al. “Structure-defining interactions in the salt cocrystals of [(Me5C5)2Fe]+I3−–XC6H4OH (X = Cl, I): weak noncovalent vs. strong ionic bonding.” Mendeleev Communications, vol. 30, no. 5, Sep. 2020, pp. 580-582. https://linkinghub.elsevier.com/retrieve/pii/S0959943620302339.