volume 30 issue 5 pages 679-682

Electrochemical instability of bis(trifluoromethylsulfonyl)imide based ionic liquids as solvents in high voltage electrolytes for potassium ion batteries

Publication typeJournal Article
Publication date2020-09-01
scimago Q3
wos Q3
SJR0.305
CiteScore3.0
Impact factor1.7
ISSN09599436, 1364551X
General Chemistry
Abstract
The feasibility of four ionic liquids containing bis(trifluoromethylsulfonyl) imide anion with different cations, namely 1-butyl-1-methylpyrrolidinium, 1-butyl-3-methylimidazolium, 1-methyl-1-propylpyrrolidinium and 1-ethyl-3-methylpyridinium, as solvents in an electrolyte of potassium ion batteries has been examined in half-cells with Al, Al2O3 as well as with practical cathode and anode materials. In spite of the previous reports on stability of ionic liquids with this anion in the 5 V limit, intrinsic electrochemical instability has been observed here both at high and low potentials, thus the investigated compounds can hardly be implemented in potassium ion cells due to their reactive nature.
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Morozova P. A. et al. Electrochemical instability of bis(trifluoromethylsulfonyl)imide based ionic liquids as solvents in high voltage electrolytes for potassium ion batteries // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 679-682.
GOST all authors (up to 50) Copy
Morozova P. A., Luchinin N. D., Rupasov D. P., Katorova N. S., Fedotov S. S., Nikitina V. A., Stevenson K. J., Abakumov A. M. Electrochemical instability of bis(trifluoromethylsulfonyl)imide based ionic liquids as solvents in high voltage electrolytes for potassium ion batteries // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 679-682.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2020.09.043
UR - https://doi.org/10.1016/j.mencom.2020.09.043
TI - Electrochemical instability of bis(trifluoromethylsulfonyl)imide based ionic liquids as solvents in high voltage electrolytes for potassium ion batteries
T2 - Mendeleev Communications
AU - Morozova, Polina A
AU - Luchinin, Nikita D
AU - Rupasov, Dmitry P.
AU - Katorova, Natalia S
AU - Fedotov, Stanislav S.
AU - Nikitina, Victoria A.
AU - Stevenson, Keith J
AU - Abakumov, Artem M.
PY - 2020
DA - 2020/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 679-682
IS - 5
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2020_Morozova,
author = {Polina A Morozova and Nikita D Luchinin and Dmitry P. Rupasov and Natalia S Katorova and Stanislav S. Fedotov and Victoria A. Nikitina and Keith J Stevenson and Artem M. Abakumov},
title = {Electrochemical instability of bis(trifluoromethylsulfonyl)imide based ionic liquids as solvents in high voltage electrolytes for potassium ion batteries},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://doi.org/10.1016/j.mencom.2020.09.043},
number = {5},
pages = {679--682},
doi = {10.1016/j.mencom.2020.09.043}
}
MLA
Cite this
MLA Copy
Morozova, Polina A., et al. “Electrochemical instability of bis(trifluoromethylsulfonyl)imide based ionic liquids as solvents in high voltage electrolytes for potassium ion batteries.” Mendeleev Communications, vol. 30, no. 5, Sep. 2020, pp. 679-682. https://doi.org/10.1016/j.mencom.2020.09.043.