Materials Science and Engineering B: Solid-State Materials for Advanced Technology, volume 255, pages 114519
Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties
Petukhova Y V
1
,
Alekseeva E V
,
Levin O. V.
1
,
Kudinova A.A.
1
,
BOBRYSHEVA N. P.
1
,
OSMOLOWSKY M. G.
1
,
Osmolovskaya O M
1
,
Publication type: Journal Article
Publication date: 2020-05-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.6
ISSN: 09215107
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
Abstract A novel approach to regulate nanoparticles morphology using capping agents (etidronic, succinic, tartaric and salicylic acids) in hydrothermal synthesis is presented. UV–Vis and FTIR spectra showed that influence of the capping agents is based on the interaction with particles surface during the solid phase formation. For na-VO2 nanorods a 1st order phase transition at 275 K was demonstrated using vibration sample magnetometry. Differential scanning calorimetry showed that this transition is accompanied by 2nd order transition at 320 K. Decrease in rods thickness and length for sal-VO2 and suc-VO2 made the transition less expressed and its temperature lowered from 275 to 150 K. Addition of tartaric and etidronic acids led to change of particles shape from rods to spheres and eliminated all the transitional changes in magnetic properties. Charge-discharge tests revealed that initial discharge capacity of nanorods was 100 mA h g−1, which is three times higher than that of spheres.
Citations by journals
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Journal of Hazardous Materials
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Journal of Hazardous Materials
1 publication, 50%
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1
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Citations by publishers
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Elsevier
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Elsevier
1 publication, 50%
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Kudinova A. et al. Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties // Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2020. Vol. 255. p. 114519.
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Kudinova A., BOBRYSHEVA N. P., OSMOLOWSKY M. G., Alekseeva E. V., Levin O. V., Osmolovskaya O. M., Petukhova Y. V., Alekseeva E. V. Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties // Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2020. Vol. 255. p. 114519.
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TY - JOUR
DO - 10.1016/j.mseb.2020.114519
UR - https://doi.org/10.1016%2Fj.mseb.2020.114519
TI - Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties
T2 - Materials Science and Engineering B: Solid-State Materials for Advanced Technology
AU - Kudinova, A.A.
AU - BOBRYSHEVA, N. P.
AU - OSMOLOWSKY, M. G.
AU - Alekseeva, E V
AU - Levin, O. V.
AU - Osmolovskaya, O M
AU - Petukhova, Y V
AU - Alekseeva, Elena V.
PY - 2020
DA - 2020/05/01 00:00:00
PB - Elsevier
SP - 114519
VL - 255
SN - 0921-5107
ER -
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@article{2020_Kudinova,
author = {A.A. Kudinova and N. P. BOBRYSHEVA and M. G. OSMOLOWSKY and E V Alekseeva and O. V. Levin and O M Osmolovskaya and Y V Petukhova and Elena V. Alekseeva},
title = {Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties},
journal = {Materials Science and Engineering B: Solid-State Materials for Advanced Technology},
year = {2020},
volume = {255},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016%2Fj.mseb.2020.114519},
pages = {114519},
doi = {10.1016/j.mseb.2020.114519}
}
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