Elsevier
Polyhedron
,  volume 26 ,  issue 12 ,  pages 2864-2870

Reduction-induced o-C-H bond activation of pyridine with decamethylzirconocene dichloride

Publication type: Journal Article
Publication date: 2007-07-01
Elsevier
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Treatment of decamethylzirconocene dichloride (η5-Cp∗)2ZrCl2 with amalgamated magnesium in pyridine results in formation of the o-C–H bond activation product [η5-C5Me5]2ZrH[η2-κC,N-C5H4N] (1). X-ray diffraction analysis (solid state) and NMR spectroscopy data (solutions) reveal the lateral positioning of the nitrogen atom in 1. At elevated temperatures, complex 1 smoothly rearranges into its isomer 2 with medial positioning of the N-atom. The parameters of equilibrium between 1 and 2 were measured at different temperatures. A reaction of 1 or a mixture of 1 and 2 (ca. 1:10) with CDCl3 smoothly and under mild conditions leads to one and the same η2-pyridyl chloride complex [η5-C5Me5]2ZrCl[η2-κC,N-C5H4N] (3) with medial positioning of the N-atom. The thermodynamic and mechanistic concepts of the paper are discussed with application of the DFT computational data.
Found 
Found 

Top-30

Journals

1
2
3
4
5
6
Organometallics
Organometallics, 6, 30%
Organometallics
6 publications, 30%
Russian Chemical Bulletin
Russian Chemical Bulletin, 2, 10%
Russian Chemical Bulletin
2 publications, 10%
Chemical Reviews
Chemical Reviews, 2, 10%
Chemical Reviews
2 publications, 10%
Doklady Physical Chemistry
Doklady Physical Chemistry, 1, 5%
Doklady Physical Chemistry
1 publication, 5%
Journal of Organometallic Chemistry
Journal of Organometallic Chemistry, 1, 5%
Journal of Organometallic Chemistry
1 publication, 5%
Angewandte Chemie
Angewandte Chemie, 1, 5%
Angewandte Chemie
1 publication, 5%
Angewandte Chemie - International Edition
Angewandte Chemie - International Edition, 1, 5%
Angewandte Chemie - International Edition
1 publication, 5%
Inorganic Chemistry
Inorganic Chemistry, 1, 5%
Inorganic Chemistry
1 publication, 5%
ACS Catalysis
ACS Catalysis, 1, 5%
ACS Catalysis
1 publication, 5%
Annual Reports Section A (Inorganic Chemistry)
Annual Reports Section A (Inorganic Chemistry), 1, 5%
Annual Reports Section A (Inorganic Chemistry)
1 publication, 5%
Chemical Science
Chemical Science, 1, 5%
Chemical Science
1 publication, 5%
Dalton Transactions
Dalton Transactions, 1, 5%
Dalton Transactions
1 publication, 5%
1
2
3
4
5
6

Publishers

2
4
6
8
10
American Chemical Society (ACS)
American Chemical Society (ACS), 10, 50%
American Chemical Society (ACS)
10 publications, 50%
Royal Society of Chemistry (RSC)
Royal Society of Chemistry (RSC), 3, 15%
Royal Society of Chemistry (RSC)
3 publications, 15%
Springer Nature
Springer Nature, 2, 10%
Springer Nature
2 publications, 10%
Elsevier
Elsevier, 2, 10%
Elsevier
2 publications, 10%
Wiley
Wiley, 2, 10%
Wiley
2 publications, 10%
Pleiades Publishing
Pleiades Publishing, 1, 5%
Pleiades Publishing
1 publication, 5%
2
4
6
8
10
  • We do not take into account publications without a DOI.
  • Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
20
Share
Cite this
GOST |
Cite this
GOST Copy
Krut’ko D. P. et al. Reduction-induced o-C-H bond activation of pyridine with decamethylzirconocene dichloride // Polyhedron. 2007. Vol. 26. No. 12. pp. 2864-2870.
GOST all authors (up to 50) Copy
Krut’ko D. P., Kirsanov R. S., Belov S. A., Borzov M. V., Churakov A. V., Howard J. A. Reduction-induced o-C-H bond activation of pyridine with decamethylzirconocene dichloride // Polyhedron. 2007. Vol. 26. No. 12. pp. 2864-2870.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.poly.2007.01.036
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538707000708
TI - Reduction-induced o-C-H bond activation of pyridine with decamethylzirconocene dichloride
T2 - Polyhedron
AU - Krut’ko, Dmitrii P.
AU - Kirsanov, Roman S.
AU - Belov, Sergey A
AU - Borzov, Maxim V.
AU - Churakov, Andrei V.
AU - Howard, Judith A.
PY - 2007
DA - 2007/07/01
PB - Elsevier
SP - 2864-2870
IS - 12
VL - 26
SN - 0277-5387
SN - 1873-3719
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Krut’ko,
author = {Dmitrii P. Krut’ko and Roman S. Kirsanov and Sergey A Belov and Maxim V. Borzov and Andrei V. Churakov and Judith A. Howard},
title = {Reduction-induced o-C-H bond activation of pyridine with decamethylzirconocene dichloride},
journal = {Polyhedron},
year = {2007},
volume = {26},
publisher = {Elsevier},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538707000708},
number = {12},
pages = {2864--2870},
doi = {10.1016/j.poly.2007.01.036}
}
MLA
Cite this
MLA Copy
Krut’ko, Dmitrii P., et al. “Reduction-induced o-C-H bond activation of pyridine with decamethylzirconocene dichloride.” Polyhedron, vol. 26, no. 12, Jul. 2007, pp. 2864-2870. https://linkinghub.elsevier.com/retrieve/pii/S0277538707000708.