Synthesis, structure and dioxygen reactivity of Ni(II) complexes with mono-, bis-, tetra- and hexa-oxime ligands
1
Higher Chemical College RAS, Miusskaya square 9, 125047 Moscow, Russia
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Publication type: Journal Article
Publication date: 2014-03-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Four nickel complexes with β-(oximinoalkyl)amine ligands OxnHn containing one (Ox1H1), two (Ox2H2), four (Ox4H4) and six (Ox6H6) oxime groups were synthesized and characterized by elemental analysis, FTIR, HRMS and single crystal X-ray diffraction. β-Oximinoalkylamines OxnHn act as polydentate ligands forming five-membered chelate rings, in which nickel is coordinated with both amine and oxime nitrogen atoms. In all structurally characterized complexes, OH-groups of oximes arms are involved in hydrogen bonding with counterions (Cl−), which are located in the inner or outer coordination sphere of the nickel atom. Two new structural types of pseudo-octahedral Ni(II) β-oximinoalkylamine complexes containing two ligands per one nickel ion (Ni(Ox1H1)2Cl2 and Ni(Ox2H2)2Cl2) were identified. Dioxygen reactivity of the obtained complexes in aerobic oxidation of triphenylphosphine was studied. Bis-oxime complex Ni(Ox2H2)2Cl2 was found to be the most active promoter of triphenylphosphine oxidation among the synthesized nickel complexes.
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Boyko Y. D. et al. Synthesis, structure and dioxygen reactivity of Ni(II) complexes with mono-, bis-, tetra- and hexa-oxime ligands // Polyhedron. 2014. Vol. 71. pp. 24-33.
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Boyko Y. D., Sukhorukov A. Yu., Semakin A. N., Nelyubina Y. V., Ananyev I. V., Rangappa K., Ioffe S. L. Synthesis, structure and dioxygen reactivity of Ni(II) complexes with mono-, bis-, tetra- and hexa-oxime ligands // Polyhedron. 2014. Vol. 71. pp. 24-33.
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TY - JOUR
DO - 10.1016/j.poly.2014.01.003
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538714000114
TI - Synthesis, structure and dioxygen reactivity of Ni(II) complexes with mono-, bis-, tetra- and hexa-oxime ligands
T2 - Polyhedron
AU - Boyko, Yaroslav D
AU - Sukhorukov, Alexey Yu
AU - Semakin, Artem N
AU - Nelyubina, Yulia V.
AU - Ananyev, Ivan V
AU - Rangappa, K.
AU - Ioffe, Sema L.
PY - 2014
DA - 2014/03/01
PB - Elsevier
SP - 24-33
VL - 71
SN - 0277-5387
SN - 1873-3719
ER -
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@article{2014_Boyko,
author = {Yaroslav D Boyko and Alexey Yu Sukhorukov and Artem N Semakin and Yulia V. Nelyubina and Ivan V Ananyev and K. Rangappa and Sema L. Ioffe},
title = {Synthesis, structure and dioxygen reactivity of Ni(II) complexes with mono-, bis-, tetra- and hexa-oxime ligands},
journal = {Polyhedron},
year = {2014},
volume = {71},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538714000114},
pages = {24--33},
doi = {10.1016/j.poly.2014.01.003}
}