Polyhedron, volume 85, pages 800-808
Mononuclear ruthenium(II) and rhodium(III) complexes with S-[4-(2,2:6′,2″-terpyridin-4′-yl)phenoxy]butyl ethanethioate and 4′-[4-(1,2-dithiolane-3-yl)butylcarboxy)phenyl]-2,2′:6′,2″-terpyridine: Synthesis, electrochemistry, antibacterial activity and catalytical application
Beloglazkina Elena K.
1, 2
,
Majouga Alexander G.
1, 2
,
Manzheliy Eugeniy A
3
,
Moiseeva Anna A.
3
,
Linkova Yulia V
4
,
Zyk Nikolai V.
3
Publication type: Journal Article
Publication date: 2015-01-01
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis and characterization of novel sulfur-containing terpyridine ligands and their ruthenium and rhodium complexes [Ru(tpy)2](PF6)2, [Rh(tpy)2](PF6)3, [Ru(phen)(tpy)Cl](PF6), [Rh(phen)(tpy)](PF6)2 (phen = phenanthroline; tpy = S-[4-(2,2:6′,2″-terpyridin-4′-yl)phenoxy]butyl ethanethioate or 4′-[4-(1,2-dithiolane-3-yl)butylcarboxy)phenyl]-2,2′:6′,2″-terpyridine) have been described. The complexes are redox-active, showing both metal-centered and ligand-centered processes. The data of electrochemical study confirm the chemisorption of complexes on the gold electrode surface. The antibacterial activity of the synthesized complexes was tested against two pathogens (Micrococcus luteus and Pseudomonas aeruginosa) by the well diffusion method. A biological study indicated that two complexes exhibit a good activity against M. luteus and the activity of symmetrical ruthenium complex [Ru(tpy-C4H4-O-C(O)-(CH2)4-C3H5S2)2](PF6)2 is better than the activity of the commercially available antibiotics streptomycin and kanamycin. It was shown that the ruthenium terpyridine–phenanthroline complex [Ru(phen)(Tpy-C6H4-O-(CH2)4-SCOCH3)Cl]PF6 efficiently catalyzed the oxidation of triphenylphosphine to triphenylphosphine oxide and styrene to styrene oxide with iodosobenzene in mild conditions.
Citations by journals
|
1
2
3
|
|
|
Moscow University Physics Bulletin (English Translation of Vestnik Moskovskogo Universiteta, Fizika)
|
Moscow University Physics Bulletin (English Translation of Vestnik Moskovskogo Universiteta, Fizika)
3 publications, 16.67%
|
|
Polyhedron
|
Polyhedron
3 publications, 16.67%
|
|
Bulletin of the Russian Academy of Sciences: Physics
|
Bulletin of the Russian Academy of Sciences: Physics
2 publications, 11.11%
|
|
ChemistrySelect
|
ChemistrySelect
2 publications, 11.11%
|
|
Coordination Chemistry Reviews
|
Coordination Chemistry Reviews
1 publication, 5.56%
|
|
Journal of Inorganic Biochemistry
|
Journal of Inorganic Biochemistry
1 publication, 5.56%
|
|
ChemPhotoChem
|
ChemPhotoChem
1 publication, 5.56%
|
|
Chemistry - An Asian Journal
|
Chemistry - An Asian Journal
1 publication, 5.56%
|
|
Chemical Society Reviews
|
Chemical Society Reviews
1 publication, 5.56%
|
|
Organometallics
|
Organometallics
1 publication, 5.56%
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
1 publication, 5.56%
|
|
1
2
3
|
Citations by publishers
|
1
2
3
4
5
6
|
|
|
Pleiades Publishing
|
Pleiades Publishing
6 publications, 33.33%
|
|
Elsevier
|
Elsevier
5 publications, 27.78%
|
|
Wiley
|
Wiley
4 publications, 22.22%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
1 publication, 5.56%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
1 publication, 5.56%
|
|
1
2
3
4
5
6
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2016,2017,2018,2019,2020,2021,2022,2023],"ids":[0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","",""],"datasets":[{"label":"Citations number","data":[2,3,5,3,0,1,2,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["11.11","16.67","27.78","16.67",0,"5.56","11.11","11.11"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Moscow University Physics Bulletin (English Translation of Vestnik Moskovskogo Universiteta, Fizika)","Polyhedron","Bulletin of the Russian Academy of Sciences: Physics","ChemistrySelect","Coordination Chemistry Reviews","Journal of Inorganic Biochemistry","ChemPhotoChem","Chemistry - An Asian Journal","Chemical Society Reviews","Organometallics","Russian Journal of Coordination Chemistry\/Koordinatsionnaya Khimiya"],"ids":[3806,21269,21419,8021,13437,6830,25567,10120,20586,1409,12054],"codes":[0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp"],"datasets":[{"label":"","data":[3,3,2,2,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[16.67,16.67,11.11,11.11,5.56,5.56,5.56,5.56,5.56,5.56,5.56],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Pleiades Publishing","Elsevier","Wiley","Royal Society of Chemistry (RSC)","American Chemical Society (ACS)"],"ids":[101,17,11,123,40],"codes":[0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[6,5,4,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,27.78,22.22,5.56,5.56],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Beloglazkina E. K. et al. Mononuclear ruthenium(II) and rhodium(III) complexes with S-[4-(2,2:6′,2″-terpyridin-4′-yl)phenoxy]butyl ethanethioate and 4′-[4-(1,2-dithiolane-3-yl)butylcarboxy)phenyl]-2,2′:6′,2″-terpyridine: Synthesis, electrochemistry, antibacterial activity and catalytical application // Polyhedron. 2015. Vol. 85. pp. 800-808.
GOST all authors (up to 50)
Copy
Beloglazkina E. K., Majouga A. G., Manzheliy E. A., Moiseeva A. A., Linkova Y. V., Zyk N. V. Mononuclear ruthenium(II) and rhodium(III) complexes with S-[4-(2,2:6′,2″-terpyridin-4′-yl)phenoxy]butyl ethanethioate and 4′-[4-(1,2-dithiolane-3-yl)butylcarboxy)phenyl]-2,2′:6′,2″-terpyridine: Synthesis, electrochemistry, antibacterial activity and catalytical application // Polyhedron. 2015. Vol. 85. pp. 800-808.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.poly.2014.09.037
UR - https://doi.org/10.1016%2Fj.poly.2014.09.037
TI - Mononuclear ruthenium(II) and rhodium(III) complexes with S-[4-(2,2:6′,2″-terpyridin-4′-yl)phenoxy]butyl ethanethioate and 4′-[4-(1,2-dithiolane-3-yl)butylcarboxy)phenyl]-2,2′:6′,2″-terpyridine: Synthesis, electrochemistry, antibacterial activity and catalytical application
T2 - Polyhedron
AU - Manzheliy, Eugeniy A
AU - Moiseeva, Anna A.
AU - Linkova, Yulia V
AU - Zyk, Nikolai V.
AU - Beloglazkina, Elena K.
AU - Majouga, Alexander G.
PY - 2015
DA - 2015/01/01 00:00:00
PB - Elsevier
SP - 800-808
VL - 85
SN - 0277-5387
ER -
Cite this
BibTex
Copy
@article{2015_Beloglazkina,
author = {Eugeniy A Manzheliy and Anna A. Moiseeva and Yulia V Linkova and Nikolai V. Zyk and Elena K. Beloglazkina and Alexander G. Majouga},
title = {Mononuclear ruthenium(II) and rhodium(III) complexes with S-[4-(2,2:6′,2″-terpyridin-4′-yl)phenoxy]butyl ethanethioate and 4′-[4-(1,2-dithiolane-3-yl)butylcarboxy)phenyl]-2,2′:6′,2″-terpyridine: Synthesis, electrochemistry, antibacterial activity and catalytical application},
journal = {Polyhedron},
year = {2015},
volume = {85},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.poly.2014.09.037},
pages = {800--808},
doi = {10.1016/j.poly.2014.09.037}
}