New synthesis route for obtaining carbon-free hexagonal RE manganites via novel simple individual precursors. The interplay between magnetic and thermodynamic properties of hexagonal RMnO3(R = Ho–Yb, Y)
A Gavrikov
1
,
Pavel S Koroteev
1
,
Andreas K Kostopoulos
2
,
Denis Kirdyankin
1
,
K. S. Gavrichev
1
,
Floriana Tuna
2
,
Zhanna Dobrokhotova
1
Publication type: Journal Article
Publication date: 2017-01-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract New simple heterometallic ionic complexes [Mn(MeCN)6][R(NO3)5] (R = Ho (1), Er (2), Tm (3), Yb (4), Y (5)) were synthesised, structurally characterized and their thermal behavior was investigated. Complexes under study were proposed as precursors for corresponding pure, carbon-free rare-earth hexagonal manganites RMnO3 (P63cm). Procedures for the preparation of RMnO3 were optimized. The magnetic behavior of RMnO3 was studied. The Cp(T) dependences for RMnO3 in the range of 5–340 K were first measured by adiabatic calorimetry, and the smoothed values of the standard thermodynamic functions Cp0(T), S0(T), Φ0(T), and ΔH0(T) were calculated for the first time. The interplay between magnetic and thermodynamic properties of RMnO3 was shown.
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Total citations:
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Citations from 2024:
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Gavrikov A. et al. New synthesis route for obtaining carbon-free hexagonal RE manganites via novel simple individual precursors. The interplay between magnetic and thermodynamic properties of hexagonal RMnO3(R = Ho–Yb, Y) // Polyhedron. 2017. Vol. 122. pp. 184-193.
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Gavrikov A., Koroteev P. S., Ilyukhin A. B., Efimov N. N., Kostopoulos A. K., Baranchikov A., Tyurin A. G., Kirdyankin D., Gavrichev K. S., Tuna F., Dobrokhotova Z. New synthesis route for obtaining carbon-free hexagonal RE manganites via novel simple individual precursors. The interplay between magnetic and thermodynamic properties of hexagonal RMnO3(R = Ho–Yb, Y) // Polyhedron. 2017. Vol. 122. pp. 184-193.
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TY - JOUR
DO - 10.1016/j.poly.2016.11.028
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538716306118
TI - New synthesis route for obtaining carbon-free hexagonal RE manganites via novel simple individual precursors. The interplay between magnetic and thermodynamic properties of hexagonal RMnO3(R = Ho–Yb, Y)
T2 - Polyhedron
AU - Gavrikov, A
AU - Koroteev, Pavel S
AU - Ilyukhin, Andrey B.
AU - Efimov, Nikolay N.
AU - Kostopoulos, Andreas K
AU - Baranchikov, Aleksandr
AU - Tyurin, Aleksandr Georgievich
AU - Kirdyankin, Denis
AU - Gavrichev, K. S.
AU - Tuna, Floriana
AU - Dobrokhotova, Zhanna
PY - 2017
DA - 2017/01/01
PB - Elsevier
SP - 184-193
VL - 122
SN - 0277-5387
SN - 1873-3719
ER -
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BibTex (up to 50 authors)
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@article{2017_Gavrikov,
author = {A Gavrikov and Pavel S Koroteev and Andrey B. Ilyukhin and Nikolay N. Efimov and Andreas K Kostopoulos and Aleksandr Baranchikov and Aleksandr Georgievich Tyurin and Denis Kirdyankin and K. S. Gavrichev and Floriana Tuna and Zhanna Dobrokhotova},
title = {New synthesis route for obtaining carbon-free hexagonal RE manganites via novel simple individual precursors. The interplay between magnetic and thermodynamic properties of hexagonal RMnO3(R = Ho–Yb, Y)},
journal = {Polyhedron},
year = {2017},
volume = {122},
publisher = {Elsevier},
month = {jan},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538716306118},
pages = {184--193},
doi = {10.1016/j.poly.2016.11.028}
}