Polyhedron, volume 177, pages 114298
Cluster core growth upon the decarbonylation of cyclopentadienyl-iron-dicarbonyl ferrocenyltelluride CpFe(CO)2TeFc: Fe1Te1 to Fe3Te3
Torubaev Yu. V.
1
,
Sakharov S G
1
,
Grinberg V A
2
,
Pasynskii A A
,
Shapovalov S S
,
Tikhonova O G
1
,
Skabitsky I V
,
Pavlova A. V.
3
,
Skabitsky I. V.
1
,
Publication type: Journal Article
Publication date: 2020-02-01
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Formal substitution of aryl group on to the ferrocenyl in [CpFe(CO)(μ-TeR)]2 (R = Ar, Fc) complex dramatically changes its Fe2Te2 core structure and chemical properties. Introduction of electron-rich and bulky ferrocenyl moiety instead of Ph in [CpFe(CO)TePh]2 provide flattening of Fe2Te2 core in [CpFe(CO)(μ-TeFc)]2 (1), further photochemical decarbonylation resulting unusual [(CpFe)3(μ-TeFc)3(μ-CO)(CO)] cluster (2). The electrochemical oxidation of 1 shows two reversible one-electron oxidation waves attributed to oxidation of Fe2Te2 core. Chemical oxidation of 1 is accompanied by isomerization of its core and results in dicationic salt cis-[CpFe(CO)(μ-TeFc)]2 (PF6)2 (3). This study also provides an illustrative example of the increasing nuclearity in Fe1 → Fe2 → Fe3 row, upon the stepwise electron-compensating decarbonylation of iron-carbonyl complexes and (apart from this) insight into the distribution of toluene molecules inclusion inside the channels of crystals of compound 2.
Citations by journals
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2
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New Journal of Chemistry
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New Journal of Chemistry
2 publications, 66.67%
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
1 publication, 33.33%
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1
2
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Citations by publishers
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1
2
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
2 publications, 66.67%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 33.33%
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1
2
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Torubaev Y. V. et al. Cluster core growth upon the decarbonylation of cyclopentadienyl-iron-dicarbonyl ferrocenyltelluride CpFe(CO)2TeFc: Fe1Te1 to Fe3Te3 // Polyhedron. 2020. Vol. 177. p. 114298.
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Torubaev Y. V., Shapovalov S. S., Tikhonova O. G., Pavlova A. V., Skabitsky I. V., Pasynskii A. A., Grinberg V. A., Sakharov S. G., Shapovalov S. S., Skabitsky I. V., Pasynskii A. A. Cluster core growth upon the decarbonylation of cyclopentadienyl-iron-dicarbonyl ferrocenyltelluride CpFe(CO)2TeFc: Fe1Te1 to Fe3Te3 // Polyhedron. 2020. Vol. 177. p. 114298.
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TY - JOUR
DO - 10.1016/j.poly.2019.114298
UR - https://doi.org/10.1016%2Fj.poly.2019.114298
TI - Cluster core growth upon the decarbonylation of cyclopentadienyl-iron-dicarbonyl ferrocenyltelluride CpFe(CO)2TeFc: Fe1Te1 to Fe3Te3
T2 - Polyhedron
AU - Torubaev, Yu. V.
AU - Shapovalov, S S
AU - Tikhonova, O G
AU - Pavlova, A. V.
AU - Skabitsky, I V
AU - Pasynskii, A A
AU - Grinberg, V A
AU - Sakharov, S G
AU - Shapovalov, Sergey S.
AU - Skabitsky, I. V.
AU - Pasynskii, A. A.
PY - 2020
DA - 2020/02/01 00:00:00
PB - Elsevier
SP - 114298
VL - 177
SN - 0277-5387
ER -
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@article{2020_Torubaev,
author = {Yu. V. Torubaev and S S Shapovalov and O G Tikhonova and A. V. Pavlova and I V Skabitsky and A A Pasynskii and V A Grinberg and S G Sakharov and Sergey S. Shapovalov and I. V. Skabitsky and A. A. Pasynskii},
title = {Cluster core growth upon the decarbonylation of cyclopentadienyl-iron-dicarbonyl ferrocenyltelluride CpFe(CO)2TeFc: Fe1Te1 to Fe3Te3},
journal = {Polyhedron},
year = {2020},
volume = {177},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016%2Fj.poly.2019.114298},
pages = {114298},
doi = {10.1016/j.poly.2019.114298}
}