Properties of highly porous aerogels prepared from ultra-high molecular weight polyethylene
Publication type: Journal Article
Publication date: 2019-11-01
scimago Q1
wos Q2
SJR: 0.843
CiteScore: 7.7
Impact factor: 4.5
ISSN: 00323861, 18732291
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Aerogels were prepared via supercritical CO2 (SC CO2) extraction of a solvent – hexadecane or o-xylene – from the swollen ultra-high molecular weight polyethylene (UHMWPE, GUR 4120). This protocol produced highly porous flaky structures containing a polymodal system of pores. The specific surface area of the porous UHMWPE samples lay between 15 and 104 m2/g, the density was 0.03–0.07 g/cm3, and the porosity was 93–97% depending on the swelling solvent amount. The degree of crystallinity reached 94%. Dynamic mechanical analysis of prepared aerogels was performed. All the samples demonstrated high damping ability. Tan δ value of 0.42–0.48 at 90–110 °C was achieved. UHMWPE aerogels revealed high thermal conductivity up to 2.3 W/(m·К).
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GOST
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Lermontov S. A. et al. Properties of highly porous aerogels prepared from ultra-high molecular weight polyethylene // Polymer. 2019. Vol. 182. p. 121824.
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Lermontov S. A., Malkova A. N., Sipyagina N. A., Straumal E. A., Maksimkin A. V., Kolesnikov E., Senatov F. S. Properties of highly porous aerogels prepared from ultra-high molecular weight polyethylene // Polymer. 2019. Vol. 182. p. 121824.
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RIS
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TY - JOUR
DO - 10.1016/j.polymer.2019.121824
UR - https://linkinghub.elsevier.com/retrieve/pii/S0032386119308304
TI - Properties of highly porous aerogels prepared from ultra-high molecular weight polyethylene
T2 - Polymer
AU - Lermontov, Sergey A
AU - Malkova, Alena N
AU - Sipyagina, Nataliya A
AU - Straumal, Elena A
AU - Maksimkin, Aleksey V
AU - Kolesnikov, Evgeny
AU - Senatov, Fedor S
PY - 2019
DA - 2019/11/01
PB - Elsevier
SP - 121824
VL - 182
SN - 0032-3861
SN - 1873-2291
ER -
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@article{2019_Lermontov,
author = {Sergey A Lermontov and Alena N Malkova and Nataliya A Sipyagina and Elena A Straumal and Aleksey V Maksimkin and Evgeny Kolesnikov and Fedor S Senatov},
title = {Properties of highly porous aerogels prepared from ultra-high molecular weight polyethylene},
journal = {Polymer},
year = {2019},
volume = {182},
publisher = {Elsevier},
month = {nov},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0032386119308304},
pages = {121824},
doi = {10.1016/j.polymer.2019.121824}
}