Reactive and Functional Polymers, volume 164, pages 104932

Low-melting phthalonitrile monomers containing maleimide group: Synthesis, dual-curing behavior, thermal and mechanical properties

Nechausov S S ¹

Kepman A.V. ¹

Morozov O S ¹

Bulgakov B A

Babkin A.V.

Aleksanova A A ¹

Bulgakov Boris ¹

Babkin Alexander ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

M.V. Lomonosov Moscow State University, Department of Chemistry, Division of Chemical Technology and New Materials, 119991, Leninskie gory st, 1-11, Moscow, Russia |

Publication type: Journal Article

Publication date: 2021-07-01

Elsevier

Journal: Reactive and Functional Polymers

Quartile SCImago

Quartile WOS

Impact factor: 5.1

ISSN: 13815148

DOI: 10.1016/j.reactfunctpolym.2021.104932

Copy DOI

Materials Chemistry

General Chemistry

Biochemistry

General Chemical Engineering

Polymers and Plastics

Environmental Chemistry

Abstract

Abstract Novel dual-functional phthalonitrile monomers containing a maleimide group were synthesized and characterized. Ortho, meta, and para isomers were obtained and only the meta-isomer can be considered as a low melting phthalonitrile monomer with a melting point of 107.4°С. Analysis of the dual-curing behavior of monomers showed radical homopolymerization of maleimides followed by phthalonitrile polymerization with the formation of isoindoline, triazine, and phthalocyanine ring structures. Two alternative copolymerization processes of maleimide groups via ene reaction and ring-opening amidation were investigated. The approach of dual-curing maleimide and phthalonitrile fragments in a single molecule allowed combining the excellent inherent mechanical properties of bismaleimide resins and the outstanding thermo-oxidative stability of phthalonitriles. After curing of both functional groups impact strength was as high as 11.81 kJ m−2, flexural strength was 108 MPa, Young's modulus was 4.38 GPa. On the contrary, Tg of this polymeric system was above 370°С and T5% was higher than 450°С in air.

By date By citations

Citations by journals

	1 2 3
Polymer	Polymer, 3, 15% Polymer 3 publications, 15%
ACS Applied Polymer Materials	ACS Applied Polymer Materials, 2, 10% ACS Applied Polymer Materials 2 publications, 10%
Reactive and Functional Polymers	Reactive and Functional Polymers, 2, 10% Reactive and Functional Polymers 2 publications, 10%
Materials Today Communications	Materials Today Communications, 1, 5% Materials Today Communications 1 publication, 5%
Journal of Polymer Research	Journal of Polymer Research, 1, 5% Journal of Polymer Research 1 publication, 5%
Iranian Polymer Journal (English Edition)	Iranian Polymer Journal (English Edition), 1, 5% Iranian Polymer Journal (English Edition) 1 publication, 5%
Thermochimica Acta	Thermochimica Acta, 1, 5% Thermochimica Acta 1 publication, 5%
European Polymer Journal	European Polymer Journal, 1, 5% European Polymer Journal 1 publication, 5%
Journal of Applied Polymer Science	Journal of Applied Polymer Science, 1, 5% Journal of Applied Polymer Science 1 publication, 5%
Journal of Coordination Chemistry	Journal of Coordination Chemistry, 1, 5% Journal of Coordination Chemistry 1 publication, 5%
Journal of Fluorescence	Journal of Fluorescence, 1, 5% Journal of Fluorescence 1 publication, 5%
Journal of Polymer Science	Journal of Polymer Science, 1, 5% Journal of Polymer Science 1 publication, 5%
Composites Science and Technology	Composites Science and Technology, 1, 5% Composites Science and Technology 1 publication, 5%
Polymer Science - Series B	Polymer Science - Series B, 1, 5% Polymer Science - Series B 1 publication, 5%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 5% Chemical Engineering Journal 1 publication, 5%
High Performance Polymers	High Performance Polymers, 1, 5% High Performance Polymers 1 publication, 5%
	1 2 3

Citations by publishers

	2 4 6 8 10
Elsevier	Elsevier, 10, 50% Elsevier 10 publications, 50%
Springer Nature	Springer Nature, 3, 15% Springer Nature 3 publications, 15%
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 10% American Chemical Society (ACS) 2 publications, 10%
Wiley	Wiley, 2, 10% Wiley 2 publications, 10%
Taylor & Francis	Taylor & Francis, 1, 5% Taylor & Francis 1 publication, 5%
Pleiades Publishing	Pleiades Publishing, 1, 5% Pleiades Publishing 1 publication, 5%
SAGE	SAGE, 1, 5% SAGE 1 publication, 5%
	2 4 6 8 10

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[1,9,8,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["5","45","40","10"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Polymer","ACS Applied Polymer Materials","Reactive and Functional Polymers","Materials Today Communications","Journal of Polymer Research","Iranian Polymer Journal (English Edition)","Thermochimica Acta","European Polymer Journal","Journal of Applied Polymer Science","Journal of Coordination Chemistry","Journal of Fluorescence","Journal of Polymer Science","Composites Science and Technology","Polymer Science - Series B","Chemical Engineering Journal","High Performance Polymers"],"ids":[19955,25373,5047,12228,22642,21491,15904,17319,513,23053,21006,25771,13825,1523,16275,18553],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/ruydfaB80LDjlkYqsfOeUAZohOIODyq7bQzis5O7_medium.webp"],"datasets":[{"label":"","data":[3,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[15,10,10,5,5,5,5,5,5,5,5,5,5,5,5,5],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Springer Nature","American Chemical Society (ACS)","Wiley","Taylor & Francis","Pleiades Publishing","SAGE"],"ids":[17,8,40,11,18,101,31],"codes":[0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/ruydfaB80LDjlkYqsfOeUAZohOIODyq7bQzis5O7_medium.webp"],"datasets":[{"label":"","data":[10,3,2,2,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[50,15,10,10,5,5,5],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Metrics

Cite this

GOST |

Cite this

GOST Copy

Nechausov S. S. et al. Low-melting phthalonitrile monomers containing maleimide group: Synthesis, dual-curing behavior, thermal and mechanical properties // Reactive and Functional Polymers. 2021. Vol. 164. p. 104932.

GOST all authors (up to 50) Copy

Nechausov S. S., Aleksanova A. A., Morozov O. S., Bulgakov B. A., Babkin A., Kepman A., Bulgakov B., Babkin A. Low-melting phthalonitrile monomers containing maleimide group: Synthesis, dual-curing behavior, thermal and mechanical properties // Reactive and Functional Polymers. 2021. Vol. 164. p. 104932.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.reactfunctpolym.2021.104932

UR - https://doi.org/10.1016%2Fj.reactfunctpolym.2021.104932

TI - Low-melting phthalonitrile monomers containing maleimide group: Synthesis, dual-curing behavior, thermal and mechanical properties

T2 - Reactive and Functional Polymers

AU - Nechausov, S S

AU - Aleksanova, A A

AU - Morozov, O S

AU - Bulgakov, B A

AU - Babkin, A.V.

AU - Kepman, A.V.

AU - Bulgakov, Boris

AU - Babkin, Alexander

PY - 2021

DA - 2021/07/01 00:00:00

PB - Elsevier

SP - 104932

VL - 164

SN - 1381-5148

ER -

BibTex

Cite this

BibTex Copy

@article{2021_Nechausov,

author = {S S Nechausov and A A Aleksanova and O S Morozov and B A Bulgakov and A.V. Babkin and A.V. Kepman and Boris Bulgakov and Alexander Babkin},

title = {Low-melting phthalonitrile monomers containing maleimide group: Synthesis, dual-curing behavior, thermal and mechanical properties},

journal = {Reactive and Functional Polymers},

year = {2021},

volume = {164},

publisher = {Elsevier},

month = {jul},

url = {https://doi.org/10.1016%2Fj.reactfunctpolym.2021.104932},

pages = {104932},

doi = {10.1016/j.reactfunctpolym.2021.104932}

}

Found error?

Publisher

Elsevier

Journal

Reactive and Functional Polymers

Quartile SCImago

Quartile WOS

Impact factor

5.1

ISSN

13815148 (Print)

Labs

Laboratory of Chemistry and Technology of Composite Materials

Profiles