Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, volume 265, pages 120393

Effects of ms-aryl substitution on the structure and spectral properties of new CH(Ar)-bis(BODIPY) luminophores

Antina Lubov A ¹

Antina Elena V ¹

Ksenofontov Alexander A

Berezin Mikhail B

Kalyagin Alexander A ¹

R. Islamov Daut ^{2, 3}

Ksenofontov A.L. ¹

Pavelyev Roman S. ³

Lodochnikova Olga A. ^{3, 4}

Berezin Mikhail Y. ¹

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G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Str., 153045 Ivanovo, Russia |

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 8 Arbuzov, 420088, Kazan, Russian Federation

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Kazan Federal University, 18 Kremlyovskaya St., 420008 Kazan, Russian Federation |

⁴

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 8 Arbuzov, 420088 Kazan, Russian Federation.

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Publication type: Journal Article

Publication date: 2022-01-01

Elsevier

Journal: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

Quartile SCImago

Quartile WOS

Impact factor: 4.4

ISSN: 13861425

DOI: 10.1016/j.saa.2021.120393

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Spectroscopy

Analytical Chemistry

Atomic and Molecular Physics, and Optics

Instrumentation

Abstract

• New CH(Ar)-bis(BODIPY)s were synthesized; • The CH(Ar)-bis(BODIPY)s are characterized by conformational mobility; • The CH(Ar)-bis(BODIPY)s are highly sensitive to the environment nature; • The CH(MeOPh)-bis(BODIPY) 3 is the most sensitive towards medium microviscosity; • Dye 3 is promising as a fluorescent sensor of environment local polarity and viscosity. In this article, we present synthesis, spectral characteristics, and results of DFT calculations of new CH(R)-bis(BODIPY) 1 – 3 . They are characterized by the conformational mobility and sensitivity of fluorescence to polarity, proton-, electron donor ability and viscosity of the solvation environment. It is shown that fluorescence intensity of 1 – 3 increases in the homologous series of alcohols (ethanol, 1-propanol, 1-butanol, 1-octanol, 1-decanol) mainly due to decrease of medium acidic properties. The viscosity of the medium effects on the 1 – 3 fluorescence in a lesser degree. Compared to 1 and 2, the 3 is the most sensitive towards viscosity both in low-viscosity homologous alcohols and in high-viscosity ethanol-glycerol mixtures. In this regard, the sensitivity of fluorescence of CH(MeOPh)-bis(BODIPY) (compound 3 ) to the viscosity was studied in binary mixtures of polar DMF and low-polarity toluene with castor and vaseline oils, as well as to the macroviscosity of the solvate environment in mixtures of toluene with polystyrene. Prospects of the practical application of CH(R)-bis(BODIPY)s are proposed for the analysis of polarity, proton-donor properties and viscosity of the medium.

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	1
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 1, 16.67% Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 1 publication, 16.67%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 16.67% Coordination Chemistry Reviews 1 publication, 16.67%
Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 1, 16.67% Physical Chemistry Chemical Physics 1 publication, 16.67%
Journal of Molecular Liquids	Journal of Molecular Liquids, 1, 16.67% Journal of Molecular Liquids 1 publication, 16.67%
Journal of Photochemistry and Photobiology A: Chemistry	Journal of Photochemistry and Photobiology A: Chemistry, 1, 16.67% Journal of Photochemistry and Photobiology A: Chemistry 1 publication, 16.67%
Journal of Luminescence	Journal of Luminescence, 1, 16.67% Journal of Luminescence 1 publication, 16.67%
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Elsevier	Elsevier, 5, 83.33% Elsevier 5 publications, 83.33%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 16.67% Royal Society of Chemistry (RSC) 1 publication, 16.67%
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Antina E. V. et al. Effects of ms-aryl substitution on the structure and spectral properties of new CH(Ar)-bis(BODIPY) luminophores // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2022. Vol. 265. p. 120393.

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Antina E. V., Kalyagin A. A., Ksenofontov A. A., R. Islamov D., Berezin M. B., Antina L. A., Ksenofontov A., Pavelyev R. S., Lodochnikova O. A., Berezin M. Y. Effects of ms-aryl substitution on the structure and spectral properties of new CH(Ar)-bis(BODIPY) luminophores // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2022. Vol. 265. p. 120393.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.saa.2021.120393

UR - https://doi.org/10.1016%2Fj.saa.2021.120393

TI - Effects of ms-aryl substitution on the structure and spectral properties of new CH(Ar)-bis(BODIPY) luminophores

T2 - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

AU - Antina, Elena V

AU - Kalyagin, Alexander A

AU - Ksenofontov, Alexander A

AU - R. Islamov, Daut

AU - Berezin, Mikhail B

AU - Antina, Lubov A

AU - Ksenofontov, A.L.

AU - Pavelyev, Roman S.

AU - Lodochnikova, Olga A.

AU - Berezin, Mikhail Y.

PY - 2022

DA - 2022/01/01 00:00:00

PB - Elsevier

SP - 120393

VL - 265

SN - 1386-1425

ER -

BibTex

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BibTex Copy

@article{2022_Antina,

author = {Elena V Antina and Alexander A Kalyagin and Alexander A Ksenofontov and Daut R. Islamov and Mikhail B Berezin and Lubov A Antina and A.L. Ksenofontov and Roman S. Pavelyev and Olga A. Lodochnikova and Mikhail Y. Berezin},

title = {Effects of ms-aryl substitution on the structure and spectral properties of new CH(Ar)-bis(BODIPY) luminophores},

journal = {Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy},

year = {2022},

volume = {265},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016%2Fj.saa.2021.120393},

pages = {120393},

doi = {10.1016/j.saa.2021.120393}

}

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Publisher

Elsevier

Journal

Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

Quartile SCImago

Quartile WOS

Impact factor

4.4

ISSN

13861425 (Print)

Labs

Chemistry and molecular photonics of dipyrromethene dyes and phosphors

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