Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, volume 268, pages 120635
High-pressure transformation of dithiazolylidene-dithiazolium polyiodide with N-H…N hydrogen bond: A Raman Spectroscopy study
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Publication type: Journal Article
Publication date: 2022-03-01
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor: 4.4
ISSN: 13861425
Spectroscopy
Analytical Chemistry
Atomic and Molecular Physics, and Optics
Instrumentation
Abstract
The insight into the behavior of polyiodides under non-ambient conditions can enrich the practical applications due to obtaining materials with adjustable and tunable conducting properties. In this work Raman spectroscopy study in the range 0 - 6.5 GPa has been performed for dithiazolylidene-dithiazolium zigzag polyiodide with N-H…N hydrogen bond. Variations of band positions in the low-wavenumber region of Raman spectra have been attributed to the changes in the anionic part of the unit cell. The association of different interacting polyiodide subunits at pressure above 1.5 GPa leads to the emergence of the bands at 98 and 115 cm-1 due to consistent vibrations in the I82- zigzag. The emergence of the band at 159 cm-1 above 0.28 GPa can be assigned to N-H…N hydrogen bond vibration. The obtained results depict undergoing structure transformations: the stronger are cation…cation and anion…anion interactions the more likely is the observation of conducting properties due to the formation of polyiodide zigzag and strongly-bound hydrogen-bonded fragment.
Citations by journals
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Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
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Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
1 publication, 50%
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Dalton Transactions
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Dalton Transactions
1 publication, 50%
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1
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Citations by publishers
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Elsevier
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Elsevier
1 publication, 50%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 50%
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1
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Yushina I. D. et al. High-pressure transformation of dithiazolylidene-dithiazolium polyiodide with N-H…N hydrogen bond: A Raman Spectroscopy study // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2022. Vol. 268. p. 120635.
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Yushina I. D., Krylov A., Bol'shakov O., Rakitin O. A., Bartashevich E. High-pressure transformation of dithiazolylidene-dithiazolium polyiodide with N-H…N hydrogen bond: A Raman Spectroscopy study // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2022. Vol. 268. p. 120635.
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TY - JOUR
DO - 10.1016/j.saa.2021.120635
UR - https://doi.org/10.1016%2Fj.saa.2021.120635
TI - High-pressure transformation of dithiazolylidene-dithiazolium polyiodide with N-H…N hydrogen bond: A Raman Spectroscopy study
T2 - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
AU - Yushina, Irina D.
AU - Krylov, A.S
AU - Bol'shakov, Oleg
AU - Rakitin, Oleg A.
AU - Bartashevich, Ekaterina
PY - 2022
DA - 2022/03/01 00:00:00
PB - Elsevier
SP - 120635
VL - 268
SN - 1386-1425
ER -
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@article{2022_Yushina,
author = {Irina D. Yushina and A.S Krylov and Oleg Bol'shakov and Oleg A. Rakitin and Ekaterina Bartashevich},
title = {High-pressure transformation of dithiazolylidene-dithiazolium polyiodide with N-H…N hydrogen bond: A Raman Spectroscopy study},
journal = {Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy},
year = {2022},
volume = {268},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016%2Fj.saa.2021.120635},
pages = {120635},
doi = {10.1016/j.saa.2021.120635}
}