Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, volume 278, pages 121366

Aggregation behavior and spectroscopic properties of red-emitting distyryl-BODIPY in aqueous solution, Langmuir-Schaefer films and Pluoronic® F127 micelles

Antina Lubov A ¹

Bumagina Natalia A ¹

Kalinkina Valeria A ^{1, 2}

Lukanov Michail M ^{1, 2}

Ksenofontov Alexander A ¹

Kazak Alexandr ^{3, 4}

Berezin Mikhail B ¹

Antina Elena V ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Str., 153045 Ivanovo, Russia |

Ivanovo State University of Chemistry and Technology, 7 Sheremetievskiy Av., 153000 Ivanovo, Russia |

Moscow Region State University, Very Voloshinoy St., 24, 141014, Mytishchi, Russia |

⁴

Nanomaterials Research Institute, Ivanovo State University, Ermak str., 39, 153025 Ivanovo, Russia |

Publication type: Journal Article

Publication date: 2022-10-01

Elsevier

Journal: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

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Quartile WOS

Impact factor: 4.4

ISSN: 13861425

DOI: 10.1016/j.saa.2022.121366

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Spectroscopy

Analytical Chemistry

Atomic and Molecular Physics, and Optics

Instrumentation

Abstract

Red-emitting distyryl substituted BODIPY dyes are among the most promising luminophors for bioimaging and optics applications. However, the practical application of BODIPYs is limited due to their high hydrophobicity and tendency to aggregate in aqueous organic solutions and solid phase. In this article, we propose an elegant solution to this problem. To this end, we carried out the detailed experimental and quantum-chemical study of the structural and spectral features of BF2-ms-phenyl-5,5'-bis(4-dimethylaminostyryl)-3,3'-dimethyl-2,2'-dipyrromethene (distyryl-BDP). The particular attention was paid to analysis of high sensitivity of the distyryl-BDP spectral characteristics to the solvent properties, and also the aggregation behavior features both in water-organic media and in mono- and multilayer Langmuir-Schaefer films. We selected the best conditions to obtain the hydrophilic micellar structures of distyryl-BDP with Pluronic® F127 having a high efficiency of dye solubilization. This method increasing the solubility improves the distyryl-BDP transport efficiency in physiological aqueous media. The aqueous solutions of distyryl-BDP-Pl micelles show the intense fluorescence in the phototherapy window region (λfl = 739 nm).

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Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 1, 20% Physical Chemistry Chemical Physics 1 publication, 20%
Journal of Molecular Liquids	Journal of Molecular Liquids, 1, 20% Journal of Molecular Liquids 1 publication, 20%
Applied Surface Science	Applied Surface Science, 1, 20% Applied Surface Science 1 publication, 20%
Journal of Photochemistry and Photobiology A: Chemistry	Journal of Photochemistry and Photobiology A: Chemistry, 1, 20% Journal of Photochemistry and Photobiology A: Chemistry 1 publication, 20%
Journal of Luminescence	Journal of Luminescence, 1, 20% Journal of Luminescence 1 publication, 20%
	1

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Elsevier	Elsevier, 4, 80% Elsevier 4 publications, 80%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 20% Royal Society of Chemistry (RSC) 1 publication, 20%
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Antina L. A. et al. Aggregation behavior and spectroscopic properties of red-emitting distyryl-BODIPY in aqueous solution, Langmuir-Schaefer films and Pluoronic® F127 micelles // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2022. Vol. 278. p. 121366.

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Antina L. A., Bumagina N. A., Kalinkina V. A., Lukanov M. M., Ksenofontov A. A., Kazak A., Berezin M. B., Antina E. V. Aggregation behavior and spectroscopic properties of red-emitting distyryl-BODIPY in aqueous solution, Langmuir-Schaefer films and Pluoronic® F127 micelles // Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2022. Vol. 278. p. 121366.

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RIS Copy

TY - JOUR

DO - 10.1016/j.saa.2022.121366

UR - https://doi.org/10.1016%2Fj.saa.2022.121366

TI - Aggregation behavior and spectroscopic properties of red-emitting distyryl-BODIPY in aqueous solution, Langmuir-Schaefer films and Pluoronic® F127 micelles

T2 - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

AU - Antina, Lubov A

AU - Bumagina, Natalia A

AU - Kalinkina, Valeria A

AU - Lukanov, Michail M

AU - Ksenofontov, Alexander A

AU - Kazak, Alexandr

AU - Berezin, Mikhail B

AU - Antina, Elena V

PY - 2022

DA - 2022/10/01 00:00:00

PB - Elsevier

SP - 121366

VL - 278

SN - 1386-1425

ER -

BibTex

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BibTex Copy

@article{2022_Antina,

author = {Lubov A Antina and Natalia A Bumagina and Valeria A Kalinkina and Michail M Lukanov and Alexander A Ksenofontov and Alexandr Kazak and Mikhail B Berezin and Elena V Antina},

title = {Aggregation behavior and spectroscopic properties of red-emitting distyryl-BODIPY in aqueous solution, Langmuir-Schaefer films and Pluoronic® F127 micelles},

journal = {Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy},

year = {2022},

volume = {278},

publisher = {Elsevier},

month = {oct},

url = {https://doi.org/10.1016%2Fj.saa.2022.121366},

pages = {121366},

doi = {10.1016/j.saa.2022.121366}

}

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Publisher

Elsevier

Journal

Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

Quartile SCImago

Quartile WOS

Impact factor

4.4

ISSN

13861425 (Print)

Labs

Chemistry and molecular photonics of dipyrromethene dyes and phosphors

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