Science of the Total Environment, volume 761, pages 144506

GC-HRMS with complimentary ionization techniques for target and non-target screening for chemical exposure: Expanding the insights of the air pollution markers in Moscow snow

Mazur D M ¹

Detenchuk E A ¹

Sosnova A A ¹

Artaev Viatcheslav ²

Artaev V B

Lebedev A. T. ¹

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Lomonosov Moscow State University, Chemistry Department, Leninskie Gory, 1, 3, Moscow 119991, Russia. |

LECO Corporation, 3000 Lakeview Avenue, St. Joseph, MI, USA |

Publication type: Journal Article

Publication date: 2021-03-01

Elsevier

Journal: Science of the Total Environment

Quartile SCImago

Quartile WOS

Impact factor: 9.8

ISSN: 00489697, 18791026

DOI: 10.1016/j.scitotenv.2020.144506

Copy DOI

Environmental Chemistry

Environmental Engineering

Pollution

Waste Management and Disposal

Abstract

Environmental exposure assessment is an important step in establishing a list of local priority pollutants and finding the sources of the threats for proposing appropriate protection measures. Exposome targeted and non-targeted analysis as well as suspect screening may be applied to reveal these pollutants. The non-targeted screening is a challenging task and requires the application of the most powerful analytical tools available, assuring wide analytical coverage, sensitivity, identification reliability, and quantitation. Moscow, Russia, is the largest and most rapidly growing European city. That rapid growth is causing changes in the environment which require periodic clarification of the real environmental situation regarding the presence of the classic pollutants and possible new contaminants. Gas chromatography – high resolution time-of-flight mass spectrometry (GC-HR-TOFMS) with electron ionization (EI), positive chemical ionization (PCI), and electron capture negative ionization (ECNI) ion sources were used for the analysis of Moscow snow samples collected in the early spring of 2018 in nine different locations. Collection of snow samples represents an efficient approach for the estimation of long-term air pollution, due to accumulation and preservation of environmental contaminants by snow during winter period. The high separation power of GC, complementary ionization methods, high mass accuracy, and wide mass range of TOFMS allowed for the identification of several hundred organic compounds belonging to the various classes of pollutants, exposure to which could represent a danger to the health of the population. Although quantitative analysis was not a primary aim of the study, targeted analysis revealed that some priority pollutants exceeded the established safe levels. Thus, dibutylphthalate concentration was over 10-fold higher than its safe level (0.001 mg/L), while benz[a]pyrene concentration exceeded Russian maximal permissible concentration value of 5 ng/L in three samples. The large amount of information generated during the combination of targeted and non-targeted analysis and screening samples for suspects makes it feasible to apply the big data analysis to observe the trends and tendencies in the pollution exposome across the city.

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Citations by journals

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Journal of Analytical Chemistry	Journal of Analytical Chemistry, 3, 11.11% Journal of Analytical Chemistry 3 publications, 11.11%
Chemosphere	Chemosphere, 2, 7.41% Chemosphere 2 publications, 7.41%
Molecules	Molecules, 2, 7.41% Molecules 2 publications, 7.41%
Science of the Total Environment	Science of the Total Environment, 2, 7.41% Science of the Total Environment 2 publications, 7.41%
Environmental Geochemistry and Health	Environmental Geochemistry and Health, 1, 3.7% Environmental Geochemistry and Health 1 publication, 3.7%
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Rapid Communications in Mass Spectrometry	Rapid Communications in Mass Spectrometry, 1, 3.7% Rapid Communications in Mass Spectrometry 1 publication, 3.7%
Analytical and Bioanalytical Chemistry	Analytical and Bioanalytical Chemistry, 1, 3.7% Analytical and Bioanalytical Chemistry 1 publication, 3.7%
Atmosphere	Atmosphere, 1, 3.7% Atmosphere 1 publication, 3.7%
Chemosensors	Chemosensors, 1, 3.7% Chemosensors 1 publication, 3.7%
Toxicologie Analytique et Clinique	Toxicologie Analytique et Clinique, 1, 3.7% Toxicologie Analytique et Clinique 1 publication, 3.7%
Microchemical Journal	Microchemical Journal, 1, 3.7% Microchemical Journal 1 publication, 3.7%
Atmospheric Environment	Atmospheric Environment, 1, 3.7% Atmospheric Environment 1 publication, 3.7%
Analytical Methods	Analytical Methods, 1, 3.7% Analytical Methods 1 publication, 3.7%
Exposome	Exposome, 1, 3.7% Exposome 1 publication, 3.7%
Current Opinion in Biotechnology	Current Opinion in Biotechnology, 1, 3.7% Current Opinion in Biotechnology 1 publication, 3.7%
Construction and Building Materials	Construction and Building Materials, 1, 3.7% Construction and Building Materials 1 publication, 3.7%
Chemical and Biological Technologies in Agriculture	Chemical and Biological Technologies in Agriculture, 1, 3.7% Chemical and Biological Technologies in Agriculture 1 publication, 3.7%
Water Research	Water Research, 1, 3.7% Water Research 1 publication, 3.7%
Journal of Applied Polymer Science	Journal of Applied Polymer Science, 1, 3.7% Journal of Applied Polymer Science 1 publication, 3.7%
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Citations by publishers

	2 4 6 8 10 12
Elsevier	Elsevier, 11, 40.74% Elsevier 11 publications, 40.74%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 4, 14.81% Multidisciplinary Digital Publishing Institute (MDPI) 4 publications, 14.81%
Springer Nature	Springer Nature, 3, 11.11% Springer Nature 3 publications, 11.11%
Pleiades Publishing	Pleiades Publishing, 3, 11.11% Pleiades Publishing 3 publications, 11.11%
Wiley	Wiley, 2, 7.41% Wiley 2 publications, 7.41%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 3.7% Royal Society of Chemistry (RSC) 1 publication, 3.7%
Oxford University Press	Oxford University Press, 1, 3.7% Oxford University Press 1 publication, 3.7%
	2 4 6 8 10 12

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Mazur D. M. et al. GC-HRMS with complimentary ionization techniques for target and non-target screening for chemical exposure: Expanding the insights of the air pollution markers in Moscow snow // Science of the Total Environment. 2021. Vol. 761. p. 144506.

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Mazur D. M., Detenchuk E. A., Sosnova A. A., Artaev V. B., Artaev V., Lebedev A. T. GC-HRMS with complimentary ionization techniques for target and non-target screening for chemical exposure: Expanding the insights of the air pollution markers in Moscow snow // Science of the Total Environment. 2021. Vol. 761. p. 144506.

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Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.scitotenv.2020.144506

UR - https://doi.org/10.1016%2Fj.scitotenv.2020.144506

TI - GC-HRMS with complimentary ionization techniques for target and non-target screening for chemical exposure: Expanding the insights of the air pollution markers in Moscow snow

T2 - Science of the Total Environment

AU - Mazur, D M

AU - Detenchuk, E A

AU - Sosnova, A A

AU - Artaev, V B

AU - Lebedev, A. T.

AU - Artaev, Viatcheslav

PY - 2021

DA - 2021/03/01 00:00:00

PB - Elsevier

SP - 144506

VL - 761

SN - 0048-9697

SN - 1879-1026

ER -

BibTex

Cite this

BibTex Copy

@article{2021_Mazur,

author = {D M Mazur and E A Detenchuk and A A Sosnova and V B Artaev and A. T. Lebedev and Viatcheslav Artaev},

title = {GC-HRMS with complimentary ionization techniques for target and non-target screening for chemical exposure: Expanding the insights of the air pollution markers in Moscow snow},

journal = {Science of the Total Environment},

year = {2021},

volume = {761},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016%2Fj.scitotenv.2020.144506},

pages = {144506},

doi = {10.1016/j.scitotenv.2020.144506}

}

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Publisher

Elsevier

Journal

Science of the Total Environment

Quartile SCImago

Quartile WOS

Impact factor

9.8

ISSN

00489697 (Print)
18791026 (Electronic)

Labs

Laboratory of physico-chemical methods for the analysis of the structure of matter

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