Sensors and Actuators, B: Chemical, volume 251, pages 858-868

Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties

Ksenofontov Alexander A ¹

Guseva Galina B ¹

Antinа E V ¹

Khodov Ilya A. ^{2, 3}

Vyugin A I ¹

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G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Street, 153045, Ivanovo, Russia. |

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Street, 153045 Ivanovo, Russia |

Institute of Physics, Kazan Federal University, 18 Kremlyovskaya Street, 420008 Kazan, Russia |

Publication type: Journal Article

Publication date: 2017-11-01

Elsevier

Journal: Sensors and Actuators, B: Chemical

Quartile SCImago

Quartile WOS

Impact factor: 8.4

ISSN: 09254005

DOI: 10.1016/j.snb.2017.05.143

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Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

Electronic, Optical and Magnetic Materials

Condensed Matter Physics

Electrical and Electronic Engineering

Instrumentation

Abstract

It was found that 3,3′-, 2,3′ and 2,2′-zinc(II) bis(dipyrromethenate)s ([Zn2L2]) form stable supramolecular complexes of the composition [Zn2L2(DMSO)n] (n = 1 or 2) with dimethyl sulfoxide (DMSO). The [Zn2L2(DMSO)n] are stable in the solid phase and solutions. Composition, stability, and spectral-luminescent properties of the [Zn2L2(DMSO)n] crystal solvates were studied by means of FTIR, PXRD, 1H NMR, DOSY, absorption and fluorescence analyses. Spectroscopic studies showed that the quantum yields (φ) of [Zn2L2(DMSO)n] are lower (to ∼1.6–3.6 times) than quantum yields (φо) of [Zn2L2] in cyclohexane. Quantum-chemical study allowed to suggest the most likely mechanism of the DMSO molecules coordination on the coordinating centers of [Zn2L2]. It is demonstrated, that the high-energy coordination interactions (Zn − O) in [Zn2L2(DMSO)n] are the main cause of the fluorescence quenching of [Zn2L2] in the presence of DMSO. Fluorescence quenching of [Zn2L2] in the DMSO presence is based on the photoinduced electron transfer (PeT) mechanism. The obtained results are interesting for the development of new [Zn2L2] fluorescent sensors of the DMSO molecules.

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Elsevier	Elsevier, 12, 80% Elsevier 12 publications, 80%
Springer Nature	Springer Nature, 1, 6.67% Springer Nature 1 publication, 6.67%
Pleiades Publishing	Pleiades Publishing, 1, 6.67% Pleiades Publishing 1 publication, 6.67%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 6.67% Royal Society of Chemistry (RSC) 1 publication, 6.67%
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Ksenofontov A. A. et al. Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties // Sensors and Actuators, B: Chemical. 2017. Vol. 251. pp. 858-868.

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Ksenofontov A. A., Guseva G. B., Antinа E. V., Khodov I. A., Vyugin A. I. Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties // Sensors and Actuators, B: Chemical. 2017. Vol. 251. pp. 858-868.

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RIS Copy

TY - JOUR

DO - 10.1016/j.snb.2017.05.143

UR - https://doi.org/10.1016%2Fj.snb.2017.05.143

TI - Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties

T2 - Sensors and Actuators, B: Chemical

AU - Antinа, E V

AU - Vyugin, A I

AU - Ksenofontov, Alexander A

AU - Guseva, Galina B

AU - Khodov, Ilya A.

PY - 2017

DA - 2017/11/01 00:00:00

PB - Elsevier

SP - 858-868

VL - 251

SN - 0925-4005

ER -

BibTex

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BibTex Copy

@article{2017_Ksenofontov,

author = {E V Antinа and A I Vyugin and Alexander A Ksenofontov and Galina B Guseva and Ilya A. Khodov},

title = {Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties},

journal = {Sensors and Actuators, B: Chemical},

year = {2017},

volume = {251},

publisher = {Elsevier},

month = {nov},

url = {https://doi.org/10.1016%2Fj.snb.2017.05.143},

pages = {858--868},

doi = {10.1016/j.snb.2017.05.143}

}

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Publisher

Elsevier

Journal

Sensors and Actuators, B: Chemical

Quartile SCImago

Quartile WOS

Impact factor

8.4

ISSN

09254005 (Print)

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