Journal of Supercritical Fluids, volume 150, pages 40-48
Exfoliation of layered yttrium hydroxide by rapid expansion of supercritical suspensions
Ustinovich Konstantin B
1
,
Rodina Anfisa A
2
,
Lebedev Vasiliy A
2
,
Pokrovskiy Oleg
1
,
Yorov Kh E
2
,
Gavrikov A
1
,
Baranchikov Alexander E
3, 4
,
Ivanov V. V.
3, 5
Publication type: Journal Article
Publication date: 2019-08-01
Journal:
Journal of Supercritical Fluids
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.9
ISSN: 08968446
Physical and Theoretical Chemistry
General Chemical Engineering
Condensed Matter Physics
Abstract
Abstract Rapid expansion of supercritical suspensions was used for the first time to push apart the layers in a layered metal hydroxide structure. Treatment with supercritical CO2 resulted in significant changes in interlayer distances in yttrium hydroxide intercalated with dodecyl sulfate anions. According to XRD, SEM, TEM, nitrogen adsorption and IR-spectroscopy measurements, the structure and composition of the layered material depended substantially on the pressure of supercritical CO2. Low pressure treatment (75–200 atm) resulted in a significant increase (by 20%) in the interlayer distance, while higher pressures did not affect the interlayer distance, but increased the specific surface area of the material (from ∼10 to 74 m2/g). Supercritically treated layered yttrium hydroxide exfoliated readily in toluene under ultrasonication. The re-assembly of exfoliated layers upon solvent evaporation was identified using time-resolved XRD. No effect of supercritical CO2 treatment was observed for layered yttrium hydroxide intercalated with nitrate, oleate and stearate anions.
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1 publication, 7.69%
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Citations by publishers
1
2
3
4
5
|
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Elsevier
|
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5 publications, 38.46%
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|
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2 publications, 15.38%
|
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|
Royal Society of Chemistry (RSC)
2 publications, 15.38%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.69%
|
Pleiades Publishing
|
Pleiades Publishing
1 publication, 7.69%
|
The Chemical Society of Japan
|
The Chemical Society of Japan
1 publication, 7.69%
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1
2
3
4
5
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Yapryntsev A. et al. Exfoliation of layered yttrium hydroxide by rapid expansion of supercritical suspensions // Journal of Supercritical Fluids. 2019. Vol. 150. pp. 40-48.
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Yapryntsev A., Ustinovich K. B., Rodina A. A., Lebedev V. A., Pokrovskiy O., Yorov Kh. E., Gavrikov A., Baranchikov A. E., Ivanov V. V. Exfoliation of layered yttrium hydroxide by rapid expansion of supercritical suspensions // Journal of Supercritical Fluids. 2019. Vol. 150. pp. 40-48.
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TY - JOUR
DO - 10.1016/j.supflu.2019.04.012
UR - https://doi.org/10.1016%2Fj.supflu.2019.04.012
TI - Exfoliation of layered yttrium hydroxide by rapid expansion of supercritical suspensions
T2 - Journal of Supercritical Fluids
AU - Yapryntsev, Alexey
AU - Ustinovich, Konstantin B
AU - Rodina, Anfisa A
AU - Lebedev, Vasiliy A
AU - Pokrovskiy, Oleg
AU - Yorov, Kh E
AU - Gavrikov, A
AU - Baranchikov, Alexander E
AU - Ivanov, V. V.
PY - 2019
DA - 2019/08/01 00:00:00
PB - Elsevier
SP - 40-48
VL - 150
SN - 0896-8446
ER -
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@article{2019_Yapryntsev
author = {Alexey Yapryntsev and Konstantin B Ustinovich and Anfisa A Rodina and Vasiliy A Lebedev and Oleg Pokrovskiy and Kh E Yorov and A Gavrikov and Alexander E Baranchikov and V. V. Ivanov},
title = {Exfoliation of layered yttrium hydroxide by rapid expansion of supercritical suspensions},
journal = {Journal of Supercritical Fluids},
year = {2019},
volume = {150},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016%2Fj.supflu.2019.04.012},
pages = {40--48},
doi = {10.1016/j.supflu.2019.04.012}
}