Synthetic Metals, volume 286, pages 117028
Improving stability of perovskite solar cells using fullerene-polymer composite electron transport layer
Dremova Nadezhda N
1
,
Bredikhin Sergey I
2
,
Luchkin Sergey Yu
,
Tsarev Sergey A
,
Fedotov Yury S
,
Aldoshin Sergey M.
,
Frolova Lyubov A
,
Nikitenko Sergey L
,
Gordeeva Alexandra M
1
,
Laurenzen Hannah
3
,
Soloveva Elena A
2
,
Ustinova Marina I
1, 4
,
Nikitenko Sergey
1
,
Luchkin Sergey
4
,
Fedotov Yury
2
,
Tsarev Sergey
4
,
Olthof Selina
3
,
Aldoshin S. M.
1
,
3
Department of Chemistry, University of Cologne, Greinstrasse 4–6, 50939, Cologne, Germany
|
5
Faculty of Chemistry, Silesian University of Technology, Strzody 9, 44-100 Gliwice, Poland
|
Publication type: Journal Article
Publication date: 2022-05-01
Materials Chemistry
Metals and Alloys
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanical Engineering
Mechanics of Materials
Abstract
Perovskite solar cells (PSCs) have attracted significant attention due to their high efficiency and potential for low-cost manufacturing, but their commercialization is strongly impeded by low operational stability. The engineering of charge-transport layer materials have been recognized as an effective strategy to improve both stability and performance of PSCs. Here, we introduce a pyrrolo[3,4- c ]pyrrole-1,4-dione-based n-type copolymer as an electron transport material for perovskite solar cells. Using a composite of this polymer with the fullerene derivative [60]PCBM delivered an efficiency of 16.4% and enabled long-term operational stability of p-i-n perovskite solar cells. • New conjugated polymer P1 is presented as promising electron transport material (ETM). • Perovskite solar cells using individual P1 as ETM delivered efficiency of 13–14%. • Using an optimized blend of P1 with [60]PCBM delivered efficiency of > 16%. • Applying P1/[60]PCBM as ETM strongly enhanced the device operational stability. • The best devices retained ~70% of the initial efficiency after 1200 h of illumination.
Citations by journals
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Molecules
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Molecules
1 publication, 11.11%
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Polymers
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1 publication, 11.11%
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Processes
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1 publication, 11.11%
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Materials Today Chemistry
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Materials Today Chemistry
1 publication, 11.11%
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Journal of Materials Chemistry A
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Journal of Materials Chemistry A
1 publication, 11.11%
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Sustainable Energy and Fuels
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1 publication, 11.11%
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Synthetic Metals
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1 publication, 11.11%
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Organic Electronics
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Organic Electronics
1 publication, 11.11%
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Optik
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Optik
1 publication, 11.11%
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1
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Citations by publishers
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1
2
3
4
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Elsevier
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Elsevier
4 publications, 44.44%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 33.33%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
2 publications, 22.22%
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1
2
3
4
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Elnaggar M. M. et al. Improving stability of perovskite solar cells using fullerene-polymer composite electron transport layer // Synthetic Metals. 2022. Vol. 286. p. 117028.
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Frolova L. A., Aldoshin S. M., Bredikhin S. I., Dremova N. N., Tsarev S. A., Fedotov Y. S., Luchkin S. Yu., Soloveva E. A., Nikitenko S. L., Akkuratov A. V., Laurenzen H., Gordeeva A. M., Elnaggar M. M., Ustinova M. I., Nikitenko S., Luchkin S., Fedotov Y., Tsarev S., Stevenson K. J., Olthof S., Aldoshin S. M., Troshin P. A. Improving stability of perovskite solar cells using fullerene-polymer composite electron transport layer // Synthetic Metals. 2022. Vol. 286. p. 117028.
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TY - JOUR
DO - 10.1016/j.synthmet.2022.117028
UR - https://doi.org/10.1016%2Fj.synthmet.2022.117028
TI - Improving stability of perovskite solar cells using fullerene-polymer composite electron transport layer
T2 - Synthetic Metals
AU - Elnaggar, Mohamed M
AU - Frolova, Lyubov A
AU - Gordeeva, Alexandra M
AU - Laurenzen, Hannah
AU - Akkuratov, Alexander V.
AU - Nikitenko, Sergey L
AU - Soloveva, Elena A
AU - Luchkin, Sergey Yu
AU - Fedotov, Yury S
AU - Tsarev, Sergey A
AU - Dremova, Nadezhda N
AU - Bredikhin, Sergey I
AU - Aldoshin, Sergey M.
AU - Troshin, Pavel A.
AU - Ustinova, Marina I
AU - Nikitenko, Sergey
AU - Luchkin, Sergey
AU - Fedotov, Yury
AU - Tsarev, Sergey
AU - Stevenson, Keith J
AU - Olthof, Selina
AU - Aldoshin, S. M.
PY - 2022
DA - 2022/05/01 00:00:00
PB - Elsevier
SP - 117028
VL - 286
SN - 0379-6779
ER -
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@article{2022_Elnaggar,
author = {Mohamed M Elnaggar and Lyubov A Frolova and Alexandra M Gordeeva and Hannah Laurenzen and Alexander V. Akkuratov and Sergey L Nikitenko and Elena A Soloveva and Sergey Yu Luchkin and Yury S Fedotov and Sergey A Tsarev and Nadezhda N Dremova and Sergey I Bredikhin and Sergey M. Aldoshin and Pavel A. Troshin and Marina I Ustinova and Sergey Nikitenko and Sergey Luchkin and Yury Fedotov and Sergey Tsarev and Keith J Stevenson and Selina Olthof and S. M. Aldoshin},
title = {Improving stability of perovskite solar cells using fullerene-polymer composite electron transport layer},
journal = {Synthetic Metals},
year = {2022},
volume = {286},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016%2Fj.synthmet.2022.117028},
pages = {117028},
doi = {10.1016/j.synthmet.2022.117028}
}
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