Talanta, volume 202, pages 51-58
Potentialities of differently-stabilized silver nanoparticles for spectrophotometric determination of peroxides
Apyari V V
1, 2, 3
,
Dmitrienko S G
,
Garshev A V
4, 5
,
Zolotov Yu.A
5, 6
,
Terenteva E A
1, 2, 3
,
Kolomnikova A R
1, 2, 3
,
Dmitrienko S
1, 2, 3
1
Chemistry department
2
Leninskie Gory 1-3 119991 Moscow Russia
|
5
Publication type: Journal Article
Publication date: 2019-09-01
Analytical Chemistry
Abstract
One of the possible ways for using silver nanoparticles (AgNPs) in spectrophotometry is their application for the determination of oxidizing agents, based on oxidative destruction of these nanoobjects. This process depends on the structure of AgNPs surface layer, which is essentially affected by the chosen stabilizer. To assess influence of the nanoparticle stabilizer and the nature of the analyte, possibilities of AgNPs covered with stabilizers of three types (citrate, polyvinylpyrrolidone, and polyhexamethylene guanidinium) for the spectrophotometric determination of hydrogen peroxide and differently substituted organic peroxides were studied. The approach is based on AgNPs oxidation leading to discoloration of the solution monitored spectrophotometrically. Different selectivity of the oxidation depending on the stabilizer was shown. Effects of various factors (time of interaction, pH, concentration of AgNPs) on the oxidation and analytical performance of the procedure were investigated. The method allows for the determination of hydrogen peroxide, peracetic acid, m-chloroperbenzoic acid, and t-butylhydroperoxide in the range of 0.3-1.5, 0.1-0.8, 1.0-7.5, and 1-7 μg mL-1 and with the limits of detection of 0.1, 0.04, 0.3, and 0.3 μg mL-1, respectively. The analysis can be performed using either spectrophotometry or naked-eye detection.
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1 publication, 4.55%
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1 publication, 4.55%
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Taylor & Francis
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1 publication, 4.55%
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IntechOpen, 1, 4.55%
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1 publication, 4.55%
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Pleiades Publishing
1 publication, 4.55%
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1
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3
4
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9
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Apyari V. V. et al. Potentialities of differently-stabilized silver nanoparticles for spectrophotometric determination of peroxides // Talanta. 2019. Vol. 202. pp. 51-58.
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Apyari V. V., Terenteva E. A., Kolomnikova A. R., Garshev A. V., Dmitrienko S. G., Zolotov Y., Dmitrienko S. Potentialities of differently-stabilized silver nanoparticles for spectrophotometric determination of peroxides // Talanta. 2019. Vol. 202. pp. 51-58.
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TY - JOUR
DO - 10.1016/j.talanta.2019.04.056
UR - https://doi.org/10.1016%2Fj.talanta.2019.04.056
TI - Potentialities of differently-stabilized silver nanoparticles for spectrophotometric determination of peroxides
T2 - Talanta
AU - Apyari, V V
AU - Terenteva, E A
AU - Kolomnikova, A R
AU - Garshev, A V
AU - Dmitrienko, S G
AU - Zolotov, Yu.A
AU - Dmitrienko, S
PY - 2019
DA - 2019/09/01 00:00:00
PB - Elsevier
SP - 51-58
VL - 202
SN - 0039-9140
SN - 1873-3573
ER -
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@article{2019_Apyari,
author = {V V Apyari and E A Terenteva and A R Kolomnikova and A V Garshev and S G Dmitrienko and Yu.A Zolotov and S Dmitrienko},
title = {Potentialities of differently-stabilized silver nanoparticles for spectrophotometric determination of peroxides},
journal = {Talanta},
year = {2019},
volume = {202},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016%2Fj.talanta.2019.04.056},
pages = {51--58},
doi = {10.1016/j.talanta.2019.04.056}
}