Tetrahedron Letters, volume 57, issue 9, pages 979-982

Synthesis and photophysical properties of a new BODIPY-based siloxane dye

Pakhomov Alexey A. 1
Stukalova Maria V 2
Surin Nikolay M. 3
Cherkaev Georgy V 3
Martynov Vladimir I. 1
Publication typeJournal Article
Publication date2016-03-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.8
ISSN00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
A fluorescent dye comprising four BODIPY derivatives conjugated to a cyclotetrasiloxane core was synthesized by consecutive hydrosilylation and esterification reactions. Photophysical properties of the dye in various organic solvents were investigated. It was shown that due to a fourfold extinction coefficient increase and a moderate quantum yield decrease the brightness of the tetra-BODIPY dye in low-polarity solvents, calculated per molecule, increased 3 times when compared to mono-BODIPY. By contrast, in polar solvents there was a dramatic drop in brightness apparently associated with intramolecular interactions of the low-polar BODIPY chromophores.

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Pakhomov A. A. et al. Synthesis and photophysical properties of a new BODIPY-based siloxane dye // Tetrahedron Letters. 2016. Vol. 57. No. 9. pp. 979-982.
GOST all authors (up to 50) Copy
Pakhomov A. A., Kononevich Y. N., Stukalova M. V., Svidchenko E. A., Surin N. M., Cherkaev G. V., Shchegolikhina O. I., Martynov V. I., Muzafarov A. M. Synthesis and photophysical properties of a new BODIPY-based siloxane dye // Tetrahedron Letters. 2016. Vol. 57. No. 9. pp. 979-982.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.tetlet.2016.01.059
UR - https://doi.org/10.1016%2Fj.tetlet.2016.01.059
TI - Synthesis and photophysical properties of a new BODIPY-based siloxane dye
T2 - Tetrahedron Letters
AU - Pakhomov, Alexey A.
AU - Kononevich, Yuriy N
AU - Stukalova, Maria V
AU - Svidchenko, Evgeniya A.
AU - Surin, Nikolay M.
AU - Cherkaev, Georgy V
AU - Shchegolikhina, Olga I.
AU - Martynov, Vladimir I.
AU - Muzafarov, Aziz M.
PY - 2016
DA - 2016/03/01 00:00:00
PB - Elsevier
SP - 979-982
IS - 9
VL - 57
SN - 0040-4039
SN - 1873-3581
ER -
BibTex |
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BibTex Copy
@article{2016_Pakhomov,
author = {Alexey A. Pakhomov and Yuriy N Kononevich and Maria V Stukalova and Evgeniya A. Svidchenko and Nikolay M. Surin and Georgy V Cherkaev and Olga I. Shchegolikhina and Vladimir I. Martynov and Aziz M. Muzafarov},
title = {Synthesis and photophysical properties of a new BODIPY-based siloxane dye},
journal = {Tetrahedron Letters},
year = {2016},
volume = {57},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016%2Fj.tetlet.2016.01.059},
number = {9},
pages = {979--982},
doi = {10.1016/j.tetlet.2016.01.059}
}
MLA
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MLA Copy
Pakhomov, Alexey A., et al. “Synthesis and photophysical properties of a new BODIPY-based siloxane dye.” Tetrahedron Letters, vol. 57, no. 9, Mar. 2016, pp. 979-982. https://doi.org/10.1016%2Fj.tetlet.2016.01.059.
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