Modulation of transversal conductivity of europium(III) bisphthalocyaninate ultrathin films by peripheral substitution
Publication type: Journal Article
Publication date: 2019-12-01
scimago Q2
wos Q3
SJR: 0.419
CiteScore: 3.9
Impact factor: 2.0
ISSN: 00406090, 18792731
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Surfaces and Interfaces
Abstract
Abstract In the present work, we demonstrate that transversal conductivity and, consequently, electrochemical activity of ultrathin solid films of two structurally similar octa-butoxy and tetra-crown-ether substituted europium bisphthalocyaninates are quite different. It is shown that presence of the crown moieties allows excellent transfer of charge through monomolecular ultrathin films of respectively substituted complex. This enables their redox-multistability, which can be utilized in molecular logic and information storage devices. On the other hand, transversal charge transfer is inhibited in the films of octa-butoxy-substituted bisphthalocyaninate, which might be promising for organic field-effect transistor applications.
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15
Total citations:
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Citations from 2024:
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(26%)
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Shokurov A. V. et al. Modulation of transversal conductivity of europium(III) bisphthalocyaninate ultrathin films by peripheral substitution // Thin Solid Films. 2019. Vol. 692. p. 137591.
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Shokurov A. V., Kutsybala D. S., Martynov A. G., Raitman O. A., Arslanov V., Gorbunova Y. G., Tsivadze A. Y., Selektor S. L. Modulation of transversal conductivity of europium(III) bisphthalocyaninate ultrathin films by peripheral substitution // Thin Solid Films. 2019. Vol. 692. p. 137591.
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RIS
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TY - JOUR
DO - 10.1016/j.tsf.2019.137591
UR - https://linkinghub.elsevier.com/retrieve/pii/S0040609019306194
TI - Modulation of transversal conductivity of europium(III) bisphthalocyaninate ultrathin films by peripheral substitution
T2 - Thin Solid Films
AU - Shokurov, Alexander V.
AU - Kutsybala, D S
AU - Martynov, Alexander G.
AU - Raitman, Oleg A.
AU - Arslanov, V.V
AU - Gorbunova, Yulia G.
AU - Tsivadze, A. Yu.
AU - Selektor, Sofiya L.
PY - 2019
DA - 2019/12/01
PB - Elsevier
SP - 137591
VL - 692
SN - 0040-6090
SN - 1879-2731
ER -
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BibTex (up to 50 authors)
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@article{2019_Shokurov,
author = {Alexander V. Shokurov and D S Kutsybala and Alexander G. Martynov and Oleg A. Raitman and V.V Arslanov and Yulia G. Gorbunova and A. Yu. Tsivadze and Sofiya L. Selektor},
title = {Modulation of transversal conductivity of europium(III) bisphthalocyaninate ultrathin films by peripheral substitution},
journal = {Thin Solid Films},
year = {2019},
volume = {692},
publisher = {Elsevier},
month = {dec},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0040609019306194},
pages = {137591},
doi = {10.1016/j.tsf.2019.137591}
}