Open Access
Ultramicroscopy
—
Том 194
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Номера страниц: 108-116
Chirality transitions and transport properties of individual few-walled carbon nanotubes as revealed by in situ TEM probing
Tang D., Kvashnin D.G., Cretu O., Nemoto Y., Uesugi F., Takeguchi M., Zhou X., Hsia F., Liu C., Sorokin P.B., Kawamoto N., Mitome M., Cheng H., Golberg D., Bando Y.
Тип документа: Journal Article
Дата публикации: 2018-11-01
Название журнала: Ultramicroscopy
Издатель: Elsevier
Квартиль по SCImago: Q1
Квартиль по Web of Science: Q1
Импакт-фактор 2021: 2.99
ISSN: 03043991, 18792723
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Instrumentation
Краткое описание
Physical properties of carbon nanotubes (CNTs) are closely related to the atomic structure, i.e. the chirality. It is highly desirable to develop a technique to modify their chirality and control the resultant transport properties. Herein, we present an in situ transmission electron microscopy (TEM) probing method to monitor the chirality transition and transport properties of individual few-walled CNTs. The changes of tube structure including the chirality are stimulated by programmed bias pulses and associated Joule heating. The chirality change of each shell is analyzed by nanobeam electron diffraction. Supported by molecular dynamics simulations, a preferred chirality transition path is identified, consistent with the Stone-Wales defect formation and dislocation sliding mechanism. The electronic transport properties are measured along with the structural changes, via fabricating transistors using the individual nanotubes as the suspended channels. Metal-to-semiconductor transitions are observed along with the chirality changes as confirmed by both the electron diffraction and electrical measurements. Apart from providing an alternative route to control the chirality of CNTs, the present work demonstrates the rare possibility of obtaining the dynamic structure-properties relationships at the atomic and molecular levels.
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1. Tang D.-M. и др. Chirality transitions and transport properties of individual few-walled carbon nanotubes as revealed by in situ TEM probing // Ultramicroscopy. 2018. Т. 194. С. 108–116.
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TY - JOUR
DO - 10.1016/j.ultramic.2018.07.012
UR - http://dx.doi.org/10.1016/j.ultramic.2018.07.012
TI - Chirality transitions and transport properties of individual few-walled carbon nanotubes as revealed by in situ TEM probing
T2 - Ultramicroscopy
AU - Tang, Dai-Ming
AU - Kvashnin, Dmitry G.
AU - Cretu, Ovidiu
AU - Nemoto, Yoshihiro
AU - Uesugi, Fumihiko
AU - Takeguchi, Masaki
AU - Zhou, Xin
AU - Hsia, Feng-Chun
AU - Liu, Chang
AU - Sorokin, Pavel B.
AU - Kawamoto, Naoyuki
AU - Mitome, Masanori
AU - Cheng, Hui-Ming
AU - Golberg, Dmitri
AU - Bando, Yoshio
PY - 2018
DA - 2018/11
PB - Elsevier BV
SP - 108-116
VL - 194
SN - 0304-3991
ER -
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@article{2018,
doi = {10.1016/j.ultramic.2018.07.012},
url = {https://doi.org/10.1016%2Fj.ultramic.2018.07.012},
year = 2018,
month = {nov},
publisher = {Elsevier {BV}},
volume = {194},
pages = {108--116},
author = {Dai-Ming Tang and Dmitry G. Kvashnin and Ovidiu Cretu and Yoshihiro Nemoto and Fumihiko Uesugi and Masaki Takeguchi and Xin Zhou and Feng-Chun Hsia and Chang Liu and Pavel B. Sorokin and Naoyuki Kawamoto and Masanori Mitome and Hui-Ming Cheng and Dmitri Golberg and Yoshio Bando},
title = {Chirality transitions and transport properties of individual few-walled carbon nanotubes as revealed by in situ {TEM} probing}
}
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Tang, Dai-Ming et al. “Chirality Transitions and Transport Properties of Individual Few-Walled Carbon Nanotubes as Revealed by in Situ TEM Probing.” Ultramicroscopy 194 (2018): 108–116. Crossref. Web.