Oxidative Cyclization Protocol for the Preparation of Energetic 3-Amino-5-R-1,2,4-oxadiazoles
Publication type: Journal Article
Publication date: 2018-12-10
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
30525670
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
An efficient method has been developed for the synthesis of energetic 3-amino-5- R-1,2,4-oxadiazoles via iodobenzene diacetate (IBD)-mediated oxidative cyclization in high yields at ambient temperature. Compound 1c has a graphite-like structure, which has seldom been reported in bicyclic compounds. The reaction of 3-amino-5- R-1,2,4-oxadiazole derivatives with hydrazine monohydrate in THF gives products that are a function of the substituent. Energetic performance calculations show detonation properties superior to TNT with concomitant lower impact and friction sensitivities.
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Total citations:
33
Citations from 2024:
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(30%)
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GOST
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Tang, Y. et al. Oxidative Cyclization Protocol for the Preparation of Energetic 3-Amino-5-R-1,2,4-oxadiazoles // Organic Letters. 2018. Vol. 20. No. 24. pp. 8039-8042.
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Tang, Y., Imler G. H., Parrish D. A., Shreeve J. M. Oxidative Cyclization Protocol for the Preparation of Energetic 3-Amino-5-R-1,2,4-oxadiazoles // Organic Letters. 2018. Vol. 20. No. 24. pp. 8039-8042.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.8b03639
UR - https://doi.org/10.1021/acs.orglett.8b03639
TI - Oxidative Cyclization Protocol for the Preparation of Energetic 3-Amino-5-R-1,2,4-oxadiazoles
T2 - Organic Letters
AU - Tang,, Yongxing
AU - Imler, Gregory H
AU - Parrish, Damon A.
AU - Shreeve, Jean'ne M.
PY - 2018
DA - 2018/12/10
PB - American Chemical Society (ACS)
SP - 8039-8042
IS - 24
VL - 20
PMID - 30525670
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Tang,,
author = {Yongxing Tang, and Gregory H Imler and Damon A. Parrish and Jean'ne M. Shreeve},
title = {Oxidative Cyclization Protocol for the Preparation of Energetic 3-Amino-5-R-1,2,4-oxadiazoles},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.orglett.8b03639},
number = {24},
pages = {8039--8042},
doi = {10.1021/acs.orglett.8b03639}
}
Cite this
MLA
Copy
Tang,, Yongxing, et al. “Oxidative Cyclization Protocol for the Preparation of Energetic 3-Amino-5-R-1,2,4-oxadiazoles.” Organic Letters, vol. 20, no. 24, Dec. 2018, pp. 8039-8042. https://doi.org/10.1021/acs.orglett.8b03639.
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