Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration
Publication type: Journal Article
Publication date: 2019-02-22
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
30793606
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Chemodivergent annulative couplings have been realized between N-methoxy benzamides and 1,3-enynes via Rh-catalyzed C-H activation and 1,4-Rh migration. Under Rh/copper catalyzed aerobic conditions, the nitrogen annulation occurred as the major pathway. The chemoselectivity was switched to the oxygen annulation under proper condition control with stoichiometric amounts of Cu(II) oxidant and NaOAc. Both coupling systems proceeded with a broad scope and functional group tolerance.
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41
Total citations:
41
Citations from 2024:
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(20%)
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GOST
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Sun J. et al. Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration // Organic Letters. 2019. Vol. 21. No. 6. pp. 1789-1793.
GOST all authors (up to 50)
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Sun J., Bai D., Wang P., Wang K., Zheng G., Li X. Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration // Organic Letters. 2019. Vol. 21. No. 6. pp. 1789-1793.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.9b00363
UR - https://doi.org/10.1021/acs.orglett.9b00363
TI - Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration
T2 - Organic Letters
AU - Sun, Jiaqiong
AU - Bai, Dachang
AU - Wang, Peiyuan
AU - Wang, Kuan
AU - Zheng, Guangfan
AU - Li, Xingwei
PY - 2019
DA - 2019/02/22
PB - American Chemical Society (ACS)
SP - 1789-1793
IS - 6
VL - 21
PMID - 30793606
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Sun,
author = {Jiaqiong Sun and Dachang Bai and Peiyuan Wang and Kuan Wang and Guangfan Zheng and Xingwei Li},
title = {Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration},
journal = {Organic Letters},
year = {2019},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.orglett.9b00363},
number = {6},
pages = {1789--1793},
doi = {10.1021/acs.orglett.9b00363}
}
Cite this
MLA
Copy
Sun, Jiaqiong, et al. “Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration.” Organic Letters, vol. 21, no. 6, Feb. 2019, pp. 1789-1793. https://doi.org/10.1021/acs.orglett.9b00363.