Chemistry of Materials, volume 31, issue 9, pages 3324-3332

High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis

Publication typeJournal Article
Publication date2019-04-03
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor8.6
ISSN08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Two-dimensional (2D) transition-metal carbides and nitrides (MXenes) have attracted significant attention due to their electronic, electrochemical, chemical, and optical properties. However, understanding of their thermal stability is still lacking. To date, MXenes are synthesized via top-down wet chemical etching, which intrinsically results in surface terminations. Here, we provide detailed insight into the surface terminations of three carbide MXenes (Ti3C2Tx, Mo2CTx, and Nb2CTx) by performing thermal gravimetric analysis with mass spectrometry analysis (TA–MS) up to 1500 °C under a He atmosphere. This specific technique enables probing surface terminations including hydroxyl (−OH), oxy (═O), and fluoride (−F) and intercalated species, such as salts and structural water. The MXene hydrophilicity depends on the type of etching (hydrofluoric acid concentration and/or mixed acid composition) and subsequent delamination conditions. We show that the amount of structural water in Ti3C2Tx increases with decre...

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GOST Copy
Seredych M. et al. High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis // Chemistry of Materials. 2019. Vol. 31. No. 9. pp. 3324-3332.
GOST all authors (up to 50) Copy
Seredych M., Shuck C. E., Pinto D., Alhabeb M., Precetti E., Deysher G., Anasori B., Kurra N., Gogotsi Y. High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis // Chemistry of Materials. 2019. Vol. 31. No. 9. pp. 3324-3332.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.chemmater.9b00397
UR - https://doi.org/10.1021%2Facs.chemmater.9b00397
TI - High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis
T2 - Chemistry of Materials
AU - Pinto, David
AU - Precetti, Eliot
AU - Seredych, Mykola
AU - Shuck, Christopher Eugene
AU - Alhabeb, Mohamed
AU - Anasori, Babak
AU - Gogotsi, Yury
AU - Deysher, Grayson
AU - Kurra, Narendra
PY - 2019
DA - 2019/04/03 00:00:00
PB - American Chemical Society (ACS)
SP - 3324-3332
IS - 9
VL - 31
SN - 0897-4756
SN - 1520-5002
ER -
BibTex |
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BibTex Copy
@article{2019_Seredych
author = {David Pinto and Eliot Precetti and Mykola Seredych and Christopher Eugene Shuck and Mohamed Alhabeb and Babak Anasori and Yury Gogotsi and Grayson Deysher and Narendra Kurra},
title = {High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis},
journal = {Chemistry of Materials},
year = {2019},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021%2Facs.chemmater.9b00397},
number = {9},
pages = {3324--3332},
doi = {10.1021/acs.chemmater.9b00397}
}
MLA
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MLA Copy
Seredych, Mykola, et al. “High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis.” Chemistry of Materials, vol. 31, no. 9, Apr. 2019, pp. 3324-3332. https://doi.org/10.1021%2Facs.chemmater.9b00397.
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