Chemistry of Materials, volume 31, issue 9, pages 3324-3332
High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis
Seredych Mykola
1
,
Pinto David
1
,
Alhabeb Mohamed
1
,
Precetti Eliot
1
,
Deysher Grayson
1
,
Anasori Babak
1
,
Kurra Narendra
1
,
Publication type: Journal Article
Publication date: 2019-04-03
Journal:
Chemistry of Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.6
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Two-dimensional (2D) transition-metal carbides and nitrides (MXenes) have attracted significant attention due to their electronic, electrochemical, chemical, and optical properties. However, understanding of their thermal stability is still lacking. To date, MXenes are synthesized via top-down wet chemical etching, which intrinsically results in surface terminations. Here, we provide detailed insight into the surface terminations of three carbide MXenes (Ti3C2Tx, Mo2CTx, and Nb2CTx) by performing thermal gravimetric analysis with mass spectrometry analysis (TA–MS) up to 1500 °C under a He atmosphere. This specific technique enables probing surface terminations including hydroxyl (−OH), oxy (═O), and fluoride (−F) and intercalated species, such as salts and structural water. The MXene hydrophilicity depends on the type of etching (hydrofluoric acid concentration and/or mixed acid composition) and subsequent delamination conditions. We show that the amount of structural water in Ti3C2Tx increases with decre...
Citations by journals
2
4
6
8
10
12
14
16
|
|
ACS Nano
|
ACS Nano
16 publications, 5.59%
|
ACS applied materials & interfaces
|
ACS applied materials & interfaces
10 publications, 3.5%
|
Chemical Engineering Journal
|
Chemical Engineering Journal
10 publications, 3.5%
|
ACS Applied Nano Materials
|
ACS Applied Nano Materials
8 publications, 2.8%
|
Journal of Materials Chemistry A
|
Journal of Materials Chemistry A
8 publications, 2.8%
|
Advanced Materials
|
Advanced Materials
6 publications, 2.1%
|
Journal of Energy Chemistry
|
Journal of Energy Chemistry
5 publications, 1.75%
|
Small
|
Small
5 publications, 1.75%
|
Advanced Materials Interfaces
|
Advanced Materials Interfaces
5 publications, 1.75%
|
ACS Applied Energy Materials
|
ACS Applied Energy Materials
5 publications, 1.75%
|
Angewandte Chemie
|
Angewandte Chemie
4 publications, 1.4%
|
Small Methods
|
Small Methods
4 publications, 1.4%
|
Carbon
|
Carbon
4 publications, 1.4%
|
Journal of Alloys and Compounds
|
Journal of Alloys and Compounds
4 publications, 1.4%
|
Journal of Energy Storage
|
Journal of Energy Storage
4 publications, 1.4%
|
Advanced Functional Materials
|
Advanced Functional Materials
4 publications, 1.4%
|
Angewandte Chemie - International Edition
|
Angewandte Chemie - International Edition
4 publications, 1.4%
|
Journal of Physical Chemistry C
|
Journal of Physical Chemistry C
4 publications, 1.4%
|
Nano-Micro Letters
|
Nano-Micro Letters
3 publications, 1.05%
|
Nano Energy
|
Nano Energy
3 publications, 1.05%
|
Electrochimica Acta
|
Electrochimica Acta
3 publications, 1.05%
|
Coordination Chemistry Reviews
|
Coordination Chemistry Reviews
3 publications, 1.05%
|
Journal of Power Sources
|
Journal of Power Sources
3 publications, 1.05%
|
2D Materials
|
2D Materials
3 publications, 1.05%
|
Journal of Physical Chemistry Letters
|
Journal of Physical Chemistry Letters
3 publications, 1.05%
|
ACS Catalysis
|
ACS Catalysis
3 publications, 1.05%
|
RSC Advances
|
RSC Advances
3 publications, 1.05%
|
ChemistrySelect
|
ChemistrySelect
3 publications, 1.05%
|
Journal of Materials Science and Technology
|
Journal of Materials Science and Technology
2 publications, 0.7%
|
2
4
6
8
10
12
14
16
|
Citations by publishers
10
20
30
40
50
60
70
80
90
|
|
Elsevier
|
Elsevier
88 publications, 30.77%
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
66 publications, 23.08%
|
Wiley
|
Wiley
44 publications, 15.38%
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
25 publications, 8.74%
|
Springer Nature
|
Springer Nature
21 publications, 7.34%
|
IOP Publishing
|
IOP Publishing
9 publications, 3.15%
|
American Institute of Physics (AIP)
|
American Institute of Physics (AIP)
7 publications, 2.45%
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
5 publications, 1.75%
|
Cambridge University Press
|
Cambridge University Press
4 publications, 1.4%
|
Taylor & Francis
|
Taylor & Francis
2 publications, 0.7%
|
Walter de Gruyter
|
Walter de Gruyter
2 publications, 0.7%
|
Frontiers Media S.A.
|
Frontiers Media S.A.
1 publication, 0.35%
|
American Association for the Advancement of Science (AAAS)
|
American Association for the Advancement of Science (AAAS)
1 publication, 0.35%
|
Proceedings of the National Academy of Sciences (PNAS)
|
Proceedings of the National Academy of Sciences (PNAS)
1 publication, 0.35%
|
American Physical Society (APS)
|
American Physical Society (APS)
1 publication, 0.35%
|
Chinese Ceramic Society
|
Chinese Ceramic Society, 1, 0.35%
Chinese Ceramic Society
1 publication, 0.35%
|
10
20
30
40
50
60
70
80
90
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0],"codes":[0,0,0,0,0,0],"imageUrls":["","","","","",""],"datasets":[{"label":"Citations number","data":[13,41,61,85,63,23],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["4.55","14.34","21.33","29.72","22.03","8.04"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["ACS Nano","ACS applied materials & interfaces","Chemical Engineering Journal","ACS Applied Nano Materials","Journal of Materials Chemistry A","Advanced Materials","Journal of Energy Chemistry","Small","Advanced Materials Interfaces","ACS Applied Energy Materials","Angewandte Chemie","Small Methods","Carbon","Journal of Alloys and Compounds","Journal of Energy Storage","Advanced Functional Materials","Angewandte Chemie - International Edition","Journal of Physical Chemistry C","Nano-Micro Letters","Nano Energy","Electrochimica Acta","Coordination Chemistry Reviews","Journal of Power Sources","2D Materials","Journal of Physical Chemistry Letters","ACS Catalysis","RSC Advances","ChemistrySelect","Journal of Materials Science and Technology"],"ids":[8724,1458,16275,1600,14919,25159,20653,9872,18764,6419,25450,4145,37,4015,18623,7715,19215,8859,7765,23236,15613,13437,14844,22357,21963,4873,3100,8021,21620],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[16,10,10,8,8,6,5,5,5,5,4,4,4,4,4,4,4,4,3,3,3,3,3,3,3,3,3,3,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[5.59,3.5,3.5,2.8,2.8,2.1,1.75,1.75,1.75,1.75,1.4,1.4,1.4,1.4,1.4,1.4,1.4,1.4,1.05,1.05,1.05,1.05,1.05,1.05,1.05,1.05,1.05,1.05,0.7],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","American Chemical Society (ACS)","Wiley","Royal Society of Chemistry (RSC)","Springer Nature","IOP Publishing","American Institute of Physics (AIP)","Multidisciplinary Digital Publishing Institute (MDPI)","Cambridge University Press","Taylor & Francis","Walter de Gruyter","Frontiers Media S.A.","American Association for the Advancement of Science (AAAS)","Proceedings of the National Academy of Sciences (PNAS)","American Physical Society (APS)","Chinese Ceramic Society"],"ids":[17,40,11,123,8,2075,250,202,1,18,4,208,189,162,1539,2953],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/cF81zWlLdkmYekymGuDcSdvgBGNKaIDoMoeJtHS1_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/s10mcsCV4OAUg9O2KrqOquQC0PhyLMI8hUUkuflM_medium.webp","\/storage\/images\/resized\/mxFdPe9qujsfvfYfcN0QOclAiYORFb0xrRlwV8gs_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp",""],"datasets":[{"label":"","data":[88,66,44,25,21,9,7,5,4,2,2,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[30.77,23.08,15.38,8.74,7.34,3.15,2.45,1.75,1.4,0.7,0.7,0.35,0.35,0.35,0.35,0.35],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Seredych M. et al. High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis // Chemistry of Materials. 2019. Vol. 31. No. 9. pp. 3324-3332.
GOST all authors (up to 50)
Copy
Seredych M., Shuck C. E., Pinto D., Alhabeb M., Precetti E., Deysher G., Anasori B., Kurra N., Gogotsi Y. High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis // Chemistry of Materials. 2019. Vol. 31. No. 9. pp. 3324-3332.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.9b00397
UR - https://doi.org/10.1021%2Facs.chemmater.9b00397
TI - High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis
T2 - Chemistry of Materials
AU - Pinto, David
AU - Precetti, Eliot
AU - Seredych, Mykola
AU - Shuck, Christopher Eugene
AU - Alhabeb, Mohamed
AU - Anasori, Babak
AU - Gogotsi, Yury
AU - Deysher, Grayson
AU - Kurra, Narendra
PY - 2019
DA - 2019/04/03 00:00:00
PB - American Chemical Society (ACS)
SP - 3324-3332
IS - 9
VL - 31
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex
Copy
@article{2019_Seredych
author = {David Pinto and Eliot Precetti and Mykola Seredych and Christopher Eugene Shuck and Mohamed Alhabeb and Babak Anasori and Yury Gogotsi and Grayson Deysher and Narendra Kurra},
title = {High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis},
journal = {Chemistry of Materials},
year = {2019},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021%2Facs.chemmater.9b00397},
number = {9},
pages = {3324--3332},
doi = {10.1021/acs.chemmater.9b00397}
}
Cite this
MLA
Copy
Seredych, Mykola, et al. “High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis.” Chemistry of Materials, vol. 31, no. 9, Apr. 2019, pp. 3324-3332. https://doi.org/10.1021%2Facs.chemmater.9b00397.