Chemistry of Materials, volume 31, issue 17, pages 6590-6597

Surface Termination Dependent Work Function and Electronic Properties of Ti3C2Tx MXene

Schultz Thorsten 1, 2
Frey Nathan C 3
Park Soohyung 1, 6
May Steven James 5
Shenoy Vivek 3
Gogotsi Yury 4, 5
2
 
Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Berlin 14109, Germany
3
 
Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States
6
 
Advanced Analysis Center, Korea Institute of Science and Technology, Seoul 02792, Korea
Publication typeJournal Article
Publication date2019-04-04
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor8.6
ISSN08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
MXenes, an emerging family of 2D transition metal carbides and nitrides, have shown promise in various applications, such as energy storage, electromagnetic interference shielding, conductive thin films, photonics, and photothermal therapy. Their metallic nature, wide range of optical absorption, and tunable surface chemistry are the key to their success in those applications. The physical properties of MXenes are known to be strongly dependent on their surface terminations. In this study, we investigated the electronic properties of Ti3C2Tx for different surface terminations, as achieved by different annealing temperatures, with the help of photoelectron spectroscopy, inverse photoelectron spectroscopy, and density functional theory calculations. We find that fluorine occupies solely the face-centered cubic adsorption site, whereas oxygen initially occupies at least two different adsorption sites, followed by a rearrangement after fluorine desorption at high annealing temperatures. The measured electroni...

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Schultz T. et al. Surface Termination Dependent Work Function and Electronic Properties of Ti3C2Tx MXene // Chemistry of Materials. 2019. Vol. 31. No. 17. pp. 6590-6597.
GOST all authors (up to 50) Copy
Schultz T., Frey N. C., Hantanasirisakul K., Park S., May S. J., Shenoy V., Gogotsi Y., Rappich J. Surface Termination Dependent Work Function and Electronic Properties of Ti3C2Tx MXene // Chemistry of Materials. 2019. Vol. 31. No. 17. pp. 6590-6597.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.chemmater.9b00414
UR - https://doi.org/10.1021%2Facs.chemmater.9b00414
TI - Surface Termination Dependent Work Function and Electronic Properties of Ti3C2Tx MXene
T2 - Chemistry of Materials
AU - Schultz, Thorsten
AU - Frey, Nathan C
AU - Hantanasirisakul, Kanit
AU - Park, Soohyung
AU - Gogotsi, Yury
AU - Rappich, Jörg
AU - May, Steven James
AU - Shenoy, Vivek
PY - 2019
DA - 2019/04/04 00:00:00
PB - American Chemical Society (ACS)
SP - 6590-6597
IS - 17
VL - 31
SN - 0897-4756
SN - 1520-5002
ER -
BibTex |
Cite this
BibTex Copy
@article{2019_Schultz
author = {Thorsten Schultz and Nathan C Frey and Kanit Hantanasirisakul and Soohyung Park and Yury Gogotsi and Jörg Rappich and Steven James May and Vivek Shenoy},
title = {Surface Termination Dependent Work Function and Electronic Properties of Ti3C2Tx MXene},
journal = {Chemistry of Materials},
year = {2019},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021%2Facs.chemmater.9b00414},
number = {17},
pages = {6590--6597},
doi = {10.1021/acs.chemmater.9b00414}
}
MLA
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Schultz, Thorsten, et al. “Surface Termination Dependent Work Function and Electronic Properties of Ti3C2Tx MXene.” Chemistry of Materials, vol. 31, no. 17, Apr. 2019, pp. 6590-6597. https://doi.org/10.1021%2Facs.chemmater.9b00414.
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