Journal of Physical Chemistry C, volume 123, issue 38, pages 23661-23673

Unraveling the Two-Photon and Excited-State Absorptions of Aza-BODIPY Dyes for Optical Power Limiting in the SWIR Band

Pascal Simon ¹

Bellier Quentin ¹

David Sylvain ¹

Bouit Pierre Antoine ¹

Chi San Hui ²

Makarov Nikolay ²

Guennic Boris Le ³

Chibani Siwar ⁴

Berginc Gerard ^{5, 6}

Feneyrou Patrick ^{5, 6}

Jacquemin Denis ⁴

Perry Joseph Q. ²

Maury Olivier ¹

Andraud Chantal ¹

Hide authors affiliations Show authors affiliations: 6 affiliations

Univ. Lyon, ENS Lyon, CNRS, Université Lyon 1, Laboratoire de Chimie, UMR 5182, 46 Allée d’Italie, 69364 Lyon, France |

School of Chemistry and Biochemistry, Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive NW, Atlanta, Georgia 30332-0400, United States |

Univ. Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)—UMR 6226, 35000 Rennes, France |

⁴

Chimie et Interdisciplinarité, Synthèse, Analyse, Modélisation (CEISAM), UMR CNRS 6230, BP 92208, Université de Nantes, Rue de la Houssinière, 44322 Nantes Cedex 3, France |

⁵

Thales Research & Technology France, Route Départementale 128, 91767 Palaiseau Cedex, France |

⁶

Thales LAS France, 2 Avenue Gay Lussac, 78990 Élancourt, France |

Publication type: Journal Article

Publication date: 2019-09-05

American Chemical Society (ACS)

Journal: Journal of Physical Chemistry C

Quartile SCImago

Quartile WOS

Impact factor: 3.7

ISSN: 19327447, 19327455

DOI: 10.1021/acs.jpcc.9b08376

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Surfaces, Coatings and Films

Electronic, Optical and Magnetic Materials

Physical and Theoretical Chemistry

General Energy

Abstract

We describe the linear and nonlinear optical properties of substituted aza-boron-dipyrromethene (aza-BODIPY) dyes with a focus on the impact of the spatial position and electronic nature of the substituents. The experimental findings are rationalized through time-dependent density functional theory calculations, pointing out the crucial importance of intramolecular charge transfer to achieve strong two-photon absorption in the near-infrared, with measured cross sections up to 3300 GM at ca. 1200 nm and 1110 GM at telecommunication wavelengths (1500 nm). The evaluation of the optical power-limiting behavior of the series highlights that a [2 + 1] process, i.e., two-photon absorption, followed by excited-state absorption, was necessary for high optical power-limiting efficiencies. Tetra-functionalized aza-BODIPY, featuring an optimized overlap between two-photon absorption and excited-state absorption in the 1200–1600 nm range, is an ideal platform to obtain efficient broad-range optical limiter.

By date By citations

Citations by journals

	1 2 3
Dyes and Pigments	Dyes and Pigments, 3, 8.11% Dyes and Pigments 3 publications, 8.11%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 3, 8.11% Coordination Chemistry Reviews 3 publications, 8.11%
Chemistry - A European Journal	Chemistry - A European Journal, 3, 8.11% Chemistry - A European Journal 3 publications, 8.11%
Molecules	Molecules, 2, 5.41% Molecules 2 publications, 5.41%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 2, 5.41% Journal of Physical Chemistry C 2 publications, 5.41%
Journal of Physical Chemistry A	Journal of Physical Chemistry A, 2, 5.41% Journal of Physical Chemistry A 2 publications, 5.41%
Journal of Physical Chemistry B	Journal of Physical Chemistry B, 2, 5.41% Journal of Physical Chemistry B 2 publications, 5.41%
New Journal of Chemistry	New Journal of Chemistry, 2, 5.41% New Journal of Chemistry 2 publications, 5.41%
Optical Materials	Optical Materials, 1, 2.7% Optical Materials 1 publication, 2.7%
Journal of Nonlinear Optical Physics and Materials	Journal of Nonlinear Optical Physics and Materials, 1, 2.7% Journal of Nonlinear Optical Physics and Materials 1 publication, 2.7%
Nature Communications	Nature Communications, 1, 2.7% Nature Communications 1 publication, 2.7%
Scientific Reports	Scientific Reports, 1, 2.7% Scientific Reports 1 publication, 2.7%
IOP Conference Series: Materials Science and Engineering	IOP Conference Series: Materials Science and Engineering, 1, 2.7% IOP Conference Series: Materials Science and Engineering 1 publication, 2.7%
Tetrahedron	Tetrahedron, 1, 2.7% Tetrahedron 1 publication, 2.7%
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 1, 2.7% Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 1 publication, 2.7%
ACS Applied Polymer Materials	ACS Applied Polymer Materials, 1, 2.7% ACS Applied Polymer Materials 1 publication, 2.7%
Chemistry of Materials	Chemistry of Materials, 1, 2.7% Chemistry of Materials 1 publication, 2.7%
Journal of Porphyrins and Phthalocyanines	Journal of Porphyrins and Phthalocyanines, 1, 2.7% Journal of Porphyrins and Phthalocyanines 1 publication, 2.7%
ACS Applied Nano Materials	ACS Applied Nano Materials, 1, 2.7% ACS Applied Nano Materials 1 publication, 2.7%
Chemical Communications	Chemical Communications, 1, 2.7% Chemical Communications 1 publication, 2.7%
Dalton Transactions	Dalton Transactions, 1, 2.7% Dalton Transactions 1 publication, 2.7%
Chemical Society Reviews	Chemical Society Reviews, 1, 2.7% Chemical Society Reviews 1 publication, 2.7%
Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 1, 2.7% Physical Chemistry Chemical Physics 1 publication, 2.7%
Synlett	Synlett, 1, 2.7% Synlett 1 publication, 2.7%
Chemical Physics Impact	Chemical Physics Impact, 1, 2.7% Chemical Physics Impact 1 publication, 2.7%
Physica Scripta	Physica Scripta, 1, 2.7% Physica Scripta 1 publication, 2.7%
	1 2 3

Citations by publishers

	2 4 6 8 10
Elsevier	Elsevier, 10, 27.03% Elsevier 10 publications, 27.03%
American Chemical Society (ACS)	American Chemical Society (ACS), 9, 24.32% American Chemical Society (ACS) 9 publications, 24.32%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 6, 16.22% Royal Society of Chemistry (RSC) 6 publications, 16.22%
Wiley	Wiley, 3, 8.11% Wiley 3 publications, 8.11%
World Scientific	World Scientific, 2, 5.41% World Scientific 2 publications, 5.41%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 5.41% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 5.41%
Springer Nature	Springer Nature, 2, 5.41% Springer Nature 2 publications, 5.41%
IOP Publishing	IOP Publishing, 2, 5.41% IOP Publishing 2 publications, 5.41%
Thieme	Thieme, 1, 2.7% Thieme 1 publication, 2.7%
	2 4 6 8 10

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

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Pascal S. et al. Unraveling the Two-Photon and Excited-State Absorptions of Aza-BODIPY Dyes for Optical Power Limiting in the SWIR Band // Journal of Physical Chemistry C. 2019. Vol. 123. No. 38. pp. 23661-23673.

GOST all authors (up to 50) Copy

Pascal S., Bellier Q., David S., Bouit P. A., Chi S. H., Makarov N., Guennic B. L., Chibani S., Berginc G., Feneyrou P., Jacquemin D., Perry J. Q., Maury O., Andraud C. Unraveling the Two-Photon and Excited-State Absorptions of Aza-BODIPY Dyes for Optical Power Limiting in the SWIR Band // Journal of Physical Chemistry C. 2019. Vol. 123. No. 38. pp. 23661-23673.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.jpcc.9b08376

UR - https://doi.org/10.1021%2Facs.jpcc.9b08376

TI - Unraveling the Two-Photon and Excited-State Absorptions of Aza-BODIPY Dyes for Optical Power Limiting in the SWIR Band

T2 - Journal of Physical Chemistry C

AU - Bellier, Quentin

AU - David, Sylvain

AU - Chibani, Siwar

AU - Feneyrou, Patrick

AU - Pascal, Simon

AU - Bouit, Pierre Antoine

AU - Makarov, Nikolay

AU - Guennic, Boris Le

AU - Jacquemin, Denis

AU - Perry, Joseph Q.

AU - Maury, Olivier

AU - Chi, San Hui

AU - Berginc, Gerard

AU - Andraud, Chantal

PY - 2019

DA - 2019/09/05 00:00:00

PB - American Chemical Society (ACS)

SP - 23661-23673

IS - 38

VL - 123

SN - 1932-7447

SN - 1932-7455

ER -

BibTex |

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BibTex Copy

@article{2019_Pascal,

author = {Quentin Bellier and Sylvain David and Siwar Chibani and Patrick Feneyrou and Simon Pascal and Pierre Antoine Bouit and Nikolay Makarov and Boris Le Guennic and Denis Jacquemin and Joseph Q. Perry and Olivier Maury and San Hui Chi and Gerard Berginc and Chantal Andraud},

title = {Unraveling the Two-Photon and Excited-State Absorptions of Aza-BODIPY Dyes for Optical Power Limiting in the SWIR Band},

journal = {Journal of Physical Chemistry C},

year = {2019},

volume = {123},

publisher = {American Chemical Society (ACS)},

month = {sep},

url = {https://doi.org/10.1021%2Facs.jpcc.9b08376},

number = {38},

pages = {23661--23673},

doi = {10.1021/acs.jpcc.9b08376}

}

MLA

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MLA Copy

Pascal, Simon, et al. “Unraveling the Two-Photon and Excited-State Absorptions of Aza-BODIPY Dyes for Optical Power Limiting in the SWIR Band.” Journal of Physical Chemistry C, vol. 123, no. 38, Sep. 2019, pp. 23661-23673. https://doi.org/10.1021%2Facs.jpcc.9b08376.

Found error?

Publisher

American Chemical Society (ACS)

Journal

Journal of Physical Chemistry C

Quartile SCImago

Quartile WOS

Impact factor

3.7

ISSN

19327447 (Print)
19327455 (Electronic)