ACS applied materials & interfaces, volume 11, issue 28, pages 25595-25604

All-Optical Reversible Azo-Based Wrinkling Patterns with High Aspect Ratio and Polarization-Independent Orientation for Light-Responsive Soft Photonics

Wang Juanjuan 1, 2
Zheng Yang 3
Li Lele 1
Liu Enping 1
Zong Chuanyong 1
Zhao Jingxin 1
Xie Jixun 1
Xu Fan 4
König Tobias A.F. 2, 5
CAO YANPING 3
Fery Andreas 2, 5
Lu Conghua 1
Publication typeJournal Article
Publication date2019-06-20
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor9.5
ISSN19448244, 19448252
General Materials Science
Abstract
Azobenzene-containing polymers (azopolymers) can serve as building blocks for an emerging class of soft photonics. Using their photoresponses for the micro/nanofabrication of smart surface is a key but still a challenging step. Here, we report a simple visible-light-illumination strategy to trigger diverse configurations of surface wrinkling on azopolymer-based film/substrate systems, which can be switched between flat and wrinkled states by controlling the intensity of the incident light. Different photoresponsive characteristics of azobenzene are involved in driving the wrinkling/dewrinkling switch. For the first time, we achieve the controlled wrinkling with an unexpected high aspect ratio and surprisingly polarization-independent ordered orientation by exploiting the unique photosoftening effect of azobenzene. Theoretical analysis reveals that an in situ photoinduced reversible soft/hard-contrast boundary determines the wrinkling orientation, which is used to fabricate diverse on-demand hierarchical wrinkles. These photoresponsive systems find broad photonic applications that are not easily accessible to other systems, e.g., optically reversible smart display, information security, and well-regulated optical devices.

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Wang J. et al. All-Optical Reversible Azo-Based Wrinkling Patterns with High Aspect Ratio and Polarization-Independent Orientation for Light-Responsive Soft Photonics // ACS applied materials & interfaces. 2019. Vol. 11. No. 28. pp. 25595-25604.
GOST all authors (up to 50) Copy
Wang J., Zheng Y., Li L., Liu E., Zong C., Zhao J., Xie J., Xu F., König T. A., Saphiannikova M., CAO Y., Fery A., Lu C. All-Optical Reversible Azo-Based Wrinkling Patterns with High Aspect Ratio and Polarization-Independent Orientation for Light-Responsive Soft Photonics // ACS applied materials & interfaces. 2019. Vol. 11. No. 28. pp. 25595-25604.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsami.9b07349
UR - https://doi.org/10.1021%2Facsami.9b07349
TI - All-Optical Reversible Azo-Based Wrinkling Patterns with High Aspect Ratio and Polarization-Independent Orientation for Light-Responsive Soft Photonics
T2 - ACS applied materials & interfaces
AU - Wang, Juanjuan
AU - Zheng, Yang
AU - Li, Lele
AU - Liu, Enping
AU - Xie, Jixun
AU - Zong, Chuanyong
AU - König, Tobias A.F.
AU - Saphiannikova, M
AU - Fery, Andreas
AU - Lu, Conghua
AU - Zhao, Jingxin
AU - Xu, Fan
AU - CAO, YANPING
PY - 2019
DA - 2019/06/20 00:00:00
PB - American Chemical Society (ACS)
SP - 25595-25604
IS - 28
VL - 11
SN - 1944-8244
SN - 1944-8252
ER -
BibTex |
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BibTex Copy
@article{2019_Wang,
author = {Juanjuan Wang and Yang Zheng and Lele Li and Enping Liu and Jixun Xie and Chuanyong Zong and Tobias A.F. König and M Saphiannikova and Andreas Fery and Conghua Lu and Jingxin Zhao and Fan Xu and YANPING CAO},
title = {All-Optical Reversible Azo-Based Wrinkling Patterns with High Aspect Ratio and Polarization-Independent Orientation for Light-Responsive Soft Photonics},
journal = {ACS applied materials & interfaces},
year = {2019},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021%2Facsami.9b07349},
number = {28},
pages = {25595--25604},
doi = {10.1021/acsami.9b07349}
}
MLA
Cite this
MLA Copy
Wang, Juanjuan, et al. “All-Optical Reversible Azo-Based Wrinkling Patterns with High Aspect Ratio and Polarization-Independent Orientation for Light-Responsive Soft Photonics.” ACS applied materials & interfaces, vol. 11, no. 28, Jun. 2019, pp. 25595-25604. https://doi.org/10.1021%2Facsami.9b07349.
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