Inorganic Chemistry, volume 50, issue 17, pages 8207-8213
Synthesis and characterization of fluorescent pyrrolyldipyrrinato Sn(IV) complexes.
1
Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada
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Publication type: Journal Article
Publication date: 2011-07-25
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of neutral, 5-coordinate pyrrolyldipyrrinato Sn(IV) complexes have been synthesized via reaction of a pyrrolyldipyrrin, or its corresponding hydrochloride salt, with dibutyltin or diphenyltin oxide. The complexes are structurally unique in that all three nitrogen atoms of the pyrrolyldipyrrinato ligand bind to the tin center, making these complexes the first examples of pyrrolyldipyrrins behaving as LX(2) ligands. The complexes are highly fluorescent, exhibiting fluorescence quantum yields between 0.28 and 0.61, and display interesting preliminary biological activity.
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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CRAWFORD S. M. et al. Synthesis and characterization of fluorescent pyrrolyldipyrrinato Sn(IV) complexes. // Inorganic Chemistry. 2011. Vol. 50. No. 17. pp. 8207-8213.
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CRAWFORD S. M., Al Sheikh Ali A., Cameron T. S., Thompson A. R. Synthesis and characterization of fluorescent pyrrolyldipyrrinato Sn(IV) complexes. // Inorganic Chemistry. 2011. Vol. 50. No. 17. pp. 8207-8213.
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TY - JOUR
DO - 10.1021/ic200731t
UR - https://doi.org/10.1021%2Fic200731t
TI - Synthesis and characterization of fluorescent pyrrolyldipyrrinato Sn(IV) complexes.
T2 - Inorganic Chemistry
AU - CRAWFORD, SARAH M.
AU - Al Sheikh Ali, Adeeb
AU - Cameron, T. Stanley
AU - Thompson, Alison R
PY - 2011
DA - 2011/07/25 00:00:00
PB - American Chemical Society (ACS)
SP - 8207-8213
IS - 17
VL - 50
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2011_CRAWFORD,
author = {SARAH M. CRAWFORD and Adeeb Al Sheikh Ali and T. Stanley Cameron and Alison R Thompson},
title = {Synthesis and characterization of fluorescent pyrrolyldipyrrinato Sn(IV) complexes.},
journal = {Inorganic Chemistry},
year = {2011},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021%2Fic200731t},
number = {17},
pages = {8207--8213},
doi = {10.1021/ic200731t}
}
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MLA
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CRAWFORD, SARAH M., et al. “Synthesis and characterization of fluorescent pyrrolyldipyrrinato Sn(IV) complexes..” Inorganic Chemistry, vol. 50, no. 17, Jul. 2011, pp. 8207-8213. https://doi.org/10.1021%2Fic200731t.