Journal of the American Chemical Society, volume 127, issue 16, pages 5740-5741

Stereochemically stable double-helicate dinuclear complexes of bis(dipyrromethene)s: a chiroptical study.

Wood Tabitha E. 1
Dalgleish Nathan D 1
Power Erin D 1
Thompson Alison R 1
Chen Xiaoming 1
OKAMOTO YOSHIO 1
1
 
Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, B3H 4J3, Canada, and EcoTopia Science Institute, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Japan
Publication typeJournal Article
Publication date2005-03-30
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor15
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Helical zinc(II) complexes of bis(dipyrromethene)s bearing homochiral amide substituents were synthesized. Analysis of the products by chiral HPLC showed two diastereomeric major products and showed that dipyrromethene double-nuclear helicates are stereochemically stable and do not interconvert. Circular dichroism (CD) studies showed that the complexation reactions had proceeded with modest diastereomeric excesses. Analysis of an analogous symmetric zinc(II) bis(dipyrromethene) lacking homochiral substituents that could act as chromophores discounted induced CD by the chiral auxiliaries.

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Wood T. E. et al. Stereochemically stable double-helicate dinuclear complexes of bis(dipyrromethene)s: a chiroptical study. // Journal of the American Chemical Society. 2005. Vol. 127. No. 16. pp. 5740-5741.
GOST all authors (up to 50) Copy
Wood T. E., Dalgleish N. D., Power E. D., Thompson A. R., Chen X., OKAMOTO Y. Stereochemically stable double-helicate dinuclear complexes of bis(dipyrromethene)s: a chiroptical study. // Journal of the American Chemical Society. 2005. Vol. 127. No. 16. pp. 5740-5741.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/ja0500613
UR - https://doi.org/10.1021%2Fja0500613
TI - Stereochemically stable double-helicate dinuclear complexes of bis(dipyrromethene)s: a chiroptical study.
T2 - Journal of the American Chemical Society
AU - Dalgleish, Nathan D
AU - Power, Erin D
AU - Chen, Xiaoming
AU - OKAMOTO, YOSHIO
AU - Wood, Tabitha E.
AU - Thompson, Alison R
PY - 2005
DA - 2005/03/30 00:00:00
PB - American Chemical Society (ACS)
SP - 5740-5741
IS - 16
VL - 127
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
Cite this
BibTex Copy
@article{2005_Wood,
author = {Nathan D Dalgleish and Erin D Power and Xiaoming Chen and YOSHIO OKAMOTO and Tabitha E. Wood and Alison R Thompson},
title = {Stereochemically stable double-helicate dinuclear complexes of bis(dipyrromethene)s: a chiroptical study.},
journal = {Journal of the American Chemical Society},
year = {2005},
volume = {127},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021%2Fja0500613},
number = {16},
pages = {5740--5741},
doi = {10.1021/ja0500613}
}
MLA
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MLA Copy
Wood, Tabitha E., et al. “Stereochemically stable double-helicate dinuclear complexes of bis(dipyrromethene)s: a chiroptical study..” Journal of the American Chemical Society, vol. 127, no. 16, Mar. 2005, pp. 5740-5741. https://doi.org/10.1021%2Fja0500613.
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