Journal of the American Chemical Society, volume 136, issue 25, pages 8859-8862

High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal–Organic Graphene Analogue

Sheberla Dennis ¹

Sun Lei ¹

Blood-Forsythe M. ²

Er Süleyman ²

Wade Casey R ¹

Brozek Carl K ¹

Aspuru-Guzik Alan ²

Dincă Mircea ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States |

Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States |

Publication type: Journal Article

Publication date: 2014-04-25

American Chemical Society (ACS)

Journal: Journal of the American Chemical Society

Quartile SCImago

Quartile WOS

Impact factor: 15

ISSN: 00027863, 15205126

DOI: 10.1021/ja502765n

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General Chemistry

Catalysis

Biochemistry

Colloid and Surface Chemistry

Abstract

Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni(2+) in aqueous NH3 solution under aerobic conditions produces Ni3(HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal-organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm(-1), respectively, both records for MOFs and among the best for any coordination polymer.

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American Chemical Society (ACS)	American Chemical Society (ACS), 212, 24.28% American Chemical Society (ACS) 212 publications, 24.28%
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Sheberla D. et al. High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal–Organic Graphene Analogue // Journal of the American Chemical Society. 2014. Vol. 136. No. 25. pp. 8859-8862.

GOST all authors (up to 50) Copy

Sheberla D., Sun L., Blood-Forsythe M., Er S., Wade C. R., Brozek C. K., Aspuru-Guzik A., Dincă M. High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal–Organic Graphene Analogue // Journal of the American Chemical Society. 2014. Vol. 136. No. 25. pp. 8859-8862.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/ja502765n

UR - https://doi.org/10.1021%2Fja502765n

TI - High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal–Organic Graphene Analogue

T2 - Journal of the American Chemical Society

AU - Dincă, Mircea

AU - Sheberla, Dennis

AU - Sun, Lei

AU - Blood-Forsythe, M.

AU - Er, Süleyman

AU - Wade, Casey R

AU - Brozek, Carl K

AU - Aspuru-Guzik, Alan

PY - 2014

DA - 2014/04/25 00:00:00

PB - American Chemical Society (ACS)

SP - 8859-8862

IS - 25

VL - 136

SN - 0002-7863

SN - 1520-5126

ER -

BibTex |

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BibTex Copy

@article{2014_Sheberla,

author = {Mircea Dincă and Dennis Sheberla and Lei Sun and M. Blood-Forsythe and Süleyman Er and Casey R Wade and Carl K Brozek and Alan Aspuru-Guzik},

title = {High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal–Organic Graphene Analogue},

journal = {Journal of the American Chemical Society},

year = {2014},

volume = {136},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021%2Fja502765n},

number = {25},

pages = {8859--8862},

doi = {10.1021/ja502765n}

}

MLA

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MLA Copy

Sheberla, Dennis, et al. “High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal–Organic Graphene Analogue.” Journal of the American Chemical Society, vol. 136, no. 25, Apr. 2014, pp. 8859-8862. https://doi.org/10.1021%2Fja502765n.

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Publisher

American Chemical Society (ACS)

Journal

Journal of the American Chemical Society

Quartile SCImago

Quartile WOS

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ISSN

00027863 (Print)
15205126 (Electronic)