Journal of Physical Chemistry Letters, volume 2, issue 3, pages 223-227
Intersystem Crossing in Halogenated Bodipy Chromophores Used for Solar Hydrogen Production
Sabatini Randy P
1
,
McCormick Theresa M.
1
,
Wilson Kristina C
1
,
Eisenberg Richard B.
1
,
McCamant David W.
1
1
Department of Chemistry, University of Rochester, Rochester, New York 14627, United States
|
Publication type: Journal Article
Publication date: 2011-01-19
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.7
ISSN: 19487185
Physical and Theoretical Chemistry
General Materials Science
Abstract
A series of halogenated boron-dipyrromethene (Bodipy) chromophores with potential applications in solar energy conversion were synthesized and characterized by steady state and ultrafast laser spectroscopy. The ultrafast dynamics of the chromophores were compared between a series containing H, Br, or I at the 2,6 positions of the Bodipy dye. The parent Bodipy has a fluorescent lifetime (τfl) of 3−5 ns, a fluorescence quantum yield (Φfl) of 0.56, and negligible triplet state yield. Bromination enhances the intersystem crossing (ISC) such that τfl and Φfl decrease to ∼1.2 ns and 0.11, respectively, while iodination further accelerates ISC so that τfl is only ∼130 ps and Φfl is 0.011. Transient absorption experiments lead to the observation of excited state absorption bands from the singlet (S1) and triplet (T1) states at ∼345 and 447 nm, respectively, and characterization of ISC via the dynamics of these bands and the decay of S1 stimulated emission.
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Sabatini R. P. et al. Intersystem Crossing in Halogenated Bodipy Chromophores Used for Solar Hydrogen Production // Journal of Physical Chemistry Letters. 2011. Vol. 2. No. 3. pp. 223-227.
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Sabatini R. P., McCormick T. M., Lazarides T., Wilson K. C., Eisenberg R. B., McCamant D. W. Intersystem Crossing in Halogenated Bodipy Chromophores Used for Solar Hydrogen Production // Journal of Physical Chemistry Letters. 2011. Vol. 2. No. 3. pp. 223-227.
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TY - JOUR
DO - 10.1021/jz101697y
UR - https://doi.org/10.1021%2Fjz101697y
TI - Intersystem Crossing in Halogenated Bodipy Chromophores Used for Solar Hydrogen Production
T2 - Journal of Physical Chemistry Letters
AU - Wilson, Kristina C
AU - Sabatini, Randy P
AU - McCormick, Theresa M.
AU - Lazarides, Theodore
AU - Eisenberg, Richard B.
AU - McCamant, David W.
PY - 2011
DA - 2011/01/19 00:00:00
PB - American Chemical Society (ACS)
SP - 223-227
IS - 3
VL - 2
SN - 1948-7185
ER -
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@article{2011_Sabatini,
author = {Kristina C Wilson and Randy P Sabatini and Theresa M. McCormick and Theodore Lazarides and Richard B. Eisenberg and David W. McCamant},
title = {Intersystem Crossing in Halogenated Bodipy Chromophores Used for Solar Hydrogen Production},
journal = {Journal of Physical Chemistry Letters},
year = {2011},
volume = {2},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021%2Fjz101697y},
number = {3},
pages = {223--227},
doi = {10.1021/jz101697y}
}
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MLA
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Sabatini, Randy P., et al. “Intersystem Crossing in Halogenated Bodipy Chromophores Used for Solar Hydrogen Production.” Journal of Physical Chemistry Letters, vol. 2, no. 3, Jan. 2011, pp. 223-227. https://doi.org/10.1021%2Fjz101697y.