Hiyama Cross-Coupling Reaction in the Stereospecific Synthesis of Retinoids
Тип публикации: Journal Article
Дата публикации: 2008-12-09
scimago Q1
wos Q1
БС1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
19067594
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
The first application of the Hiyama reaction to the synthesis of retinoids is reported. A range of organosilicon moieties (siloxanes, silanols and three kinds of "safety-catch" silanols) were successfully coupled, under activation, to obtain trans-retinol or 11-cis-retinol with high yield and stereoselectivity. The advantageous properties of the silicon-based coupling partners and the mild reaction conditions firmly establish the Hiyama reaction as a viable (even superior) alternative to the traditional Suzuki and Stille couplings in the retinoid field.
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ГОСТ
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Montenegro J. et al. Hiyama Cross-Coupling Reaction in the Stereospecific Synthesis of Retinoids // Organic Letters. 2008. Vol. 11. No. 1. pp. 141-144.
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Montenegro J., Bergueiro J., Saá C., López S. Hiyama Cross-Coupling Reaction in the Stereospecific Synthesis of Retinoids // Organic Letters. 2008. Vol. 11. No. 1. pp. 141-144.
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TY - JOUR
DO - 10.1021/ol802551a
UR - https://doi.org/10.1021/ol802551a
TI - Hiyama Cross-Coupling Reaction in the Stereospecific Synthesis of Retinoids
T2 - Organic Letters
AU - Montenegro, Javier
AU - Bergueiro, Julián
AU - Saá, Carlos
AU - López, Susana
PY - 2008
DA - 2008/12/09
PB - American Chemical Society (ACS)
SP - 141-144
IS - 1
VL - 11
PMID - 19067594
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (до 50 авторов)
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@article{2008_Montenegro,
author = {Javier Montenegro and Julián Bergueiro and Carlos Saá and Susana López},
title = {Hiyama Cross-Coupling Reaction in the Stereospecific Synthesis of Retinoids},
journal = {Organic Letters},
year = {2008},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ol802551a},
number = {1},
pages = {141--144},
doi = {10.1021/ol802551a}
}
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MLA
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Montenegro, Javier, et al. “Hiyama Cross-Coupling Reaction in the Stereospecific Synthesis of Retinoids.” Organic Letters, vol. 11, no. 1, Dec. 2008, pp. 141-144. https://doi.org/10.1021/ol802551a.