Dalton Transactions, volume 43, issue 22, pages 8499-8507
A simple BODIPY-aniline-based fluorescent chemosensor as multiple logic operations for the detection of pH and CO2 gas.
2
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou, Fujian 350002, P. R. China
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Publication type: Journal Article
Publication date: 2014-03-06
Journal:
Dalton Transactions
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4
ISSN: 14779226, 14779234
Inorganic Chemistry
Abstract
A simple 4-aniline boron-dipyrromethene (BODIPY) dye (1) was developed as a highly sensitive acidic pH fluorescent probe excitable with visible light based on a photoinduced electron transfer (PeT) mechanism. The pH titration indicates that the fluorescence intensity increases more than 500-fold within the pH range of 4.12-1.42 with a pKa value of 3.24 in methanol-water (1 : 1, v/v) solution, which is valuable for studying strongly acidic conditions. Density functional theory (DFT) calculations reproduce the fluorescence off-on behavior. 1 has also been used as a fluorescent chemosensor for the visual detection of dissolved carbon dioxide (CO2) gas. The underlying mechanism of the sensing process is rationalized. This probe can be recovered by bubbling nitrogen (N2) gas into CO2-treated solutions for over 10 cycles. In addition, two logic gates (OR and INH) have been achieved at the molecular level by changing the initial states of system 1 and chemical inputs.
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5
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15
20
25
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Pan Z. H. et al. A simple BODIPY-aniline-based fluorescent chemosensor as multiple logic operations for the detection of pH and CO2 gas. // Dalton Transactions. 2014. Vol. 43. No. 22. pp. 8499-8507.
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Pan Z. H., Luo G., Zhou J., Xia J. X., Fang K., Wu R. A simple BODIPY-aniline-based fluorescent chemosensor as multiple logic operations for the detection of pH and CO2 gas. // Dalton Transactions. 2014. Vol. 43. No. 22. pp. 8499-8507.
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TY - JOUR
DO - 10.1039/C4DT00395K
UR - https://doi.org/10.1039%2FC4DT00395K
TI - A simple BODIPY-aniline-based fluorescent chemosensor as multiple logic operations for the detection of pH and CO2 gas.
T2 - Dalton Transactions
AU - Pan, Zhong Hua
AU - Zhou, Jing-Wei
AU - Xia, Jiu Xu
AU - Fang, Kai
AU - Luo, Geng-Geng
AU - Wu, Ruibo
PY - 2014
DA - 2014/03/06 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 8499-8507
IS - 22
VL - 43
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2014_Pan,
author = {Zhong Hua Pan and Jing-Wei Zhou and Jiu Xu Xia and Kai Fang and Geng-Geng Luo and Ruibo Wu},
title = {A simple BODIPY-aniline-based fluorescent chemosensor as multiple logic operations for the detection of pH and CO2 gas.},
journal = {Dalton Transactions},
year = {2014},
volume = {43},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://doi.org/10.1039%2FC4DT00395K},
number = {22},
pages = {8499--8507},
doi = {10.1039/C4DT00395K}
}
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MLA
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Pan, Zhong Hua, et al. “A simple BODIPY-aniline-based fluorescent chemosensor as multiple logic operations for the detection of pH and CO2 gas..” Dalton Transactions, vol. 43, no. 22, Mar. 2014, pp. 8499-8507. https://doi.org/10.1039%2FC4DT00395K.