Cis/trans equilibrium as the way to form Pd carbene catalyst from trans-isocyanide complex
Publication type: Journal Article
Publication date: 2013-10-20
scimago Q3
wos Q3
SJR: 0.294
CiteScore: 3.4
Impact factor: 2.1
ISSN: 00958972, 10290389
Materials Chemistry
Physical and Theoretical Chemistry
Abstract
The behavior of Pd(II) bis-isocyanide complexes in solution was studied for examples of bis-(cyclohexylisocyanide)palladium(II) dichloride (1) and diiodide (2). The equilibrium between isomeric cis- and trans-forms of 1 was observed by NMR and IR spectroscopy. Complex 1 (which has the cis-configuration in the solid state) gives cis-/trans-isomeric mixture after dissolving in CDCl3 for several days at room temperature. The effect of heating on the equilibration rate was considered. The studied equilibrium leads to a purely cis-structure of Pd carbene complex (3) that was synthesized via the interaction of cis-/trans-isomeric mixture of 1 with benzophenone hydrazone.
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12
Total citations:
12
Citations from 2024:
1
(8%)
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GOST
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Yakimanskiy A. et al. Cis/trans equilibrium as the way to form Pd carbene catalyst from trans-isocyanide complex // Journal of Coordination Chemistry. 2013. Vol. 66. No. 20. pp. 3592-3601.
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Yakimanskiy A., Boyarskaya I., Boyarskiy V., Boyarskiy V. P. Cis/trans equilibrium as the way to form Pd carbene catalyst from trans-isocyanide complex // Journal of Coordination Chemistry. 2013. Vol. 66. No. 20. pp. 3592-3601.
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RIS
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TY - JOUR
DO - 10.1080/00958972.2013.847185
UR - https://doi.org/10.1080/00958972.2013.847185
TI - Cis/trans equilibrium as the way to form Pd carbene catalyst from trans-isocyanide complex
T2 - Journal of Coordination Chemistry
AU - Yakimanskiy, Anton
AU - Boyarskaya, Irina
AU - Boyarskiy, Vadim
AU - Boyarskiy, Vadim P
PY - 2013
DA - 2013/10/20
PB - Taylor & Francis
SP - 3592-3601
IS - 20
VL - 66
SN - 0095-8972
SN - 1029-0389
ER -
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BibTex (up to 50 authors)
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@article{2013_Yakimanskiy,
author = {Anton Yakimanskiy and Irina Boyarskaya and Vadim Boyarskiy and Vadim P Boyarskiy},
title = {Cis/trans equilibrium as the way to form Pd carbene catalyst from trans-isocyanide complex},
journal = {Journal of Coordination Chemistry},
year = {2013},
volume = {66},
publisher = {Taylor & Francis},
month = {oct},
url = {https://doi.org/10.1080/00958972.2013.847185},
number = {20},
pages = {3592--3601},
doi = {10.1080/00958972.2013.847185}
}
Cite this
MLA
Copy
Yakimanskiy, Anton, et al. “Cis/trans equilibrium as the way to form Pd carbene catalyst from trans-isocyanide complex.” Journal of Coordination Chemistry, vol. 66, no. 20, Oct. 2013, pp. 3592-3601. https://doi.org/10.1080/00958972.2013.847185.
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