pπ-pπ Bonding Between Sulfur and the Heavier Elements of Group 15
Publication type: Journal Article
Publication date: 1989-01-01
scimago Q4
wos Q3
SJR: 0.264
CiteScore: 2.6
Impact factor: 1.6
ISSN: 10426507, 15635325, 10267719
Organic Chemistry
Biochemistry
Inorganic Chemistry
Abstract
As a contribution to the development of general stable pπ-pπ bonding throughout the p-block, the first dithiaphosphenium cation la has been prepared. Stable dicoordinate phosphorus without the presence of at least one nitrogen or carbon ligand is unique. Moreover, this compound contains an unprecedented example of thermodynamically stable pπ-pπ bonding between phosphorus and sulfur. In addition, cation la contains a rare example of pπ-pπ bonding between the heavier elements of different groups of the Periodic Table. The analogous arsenic and antimony derivatives have been prepared, demonstrating that the system offers potential generality for genuine pπ-pπ bonding between all heavy (n > 2) non-metal elements.
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Burford N. T., Royan B. W. pπ-pπ Bonding Between Sulfur and the Heavier Elements of Group 15 // Phosphorus, Sulfur and Silicon and the Related Elements. 1989. Vol. 41. No. 1-2. pp. 37-42.
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Burford N. T., Royan B. W. pπ-pπ Bonding Between Sulfur and the Heavier Elements of Group 15 // Phosphorus, Sulfur and Silicon and the Related Elements. 1989. Vol. 41. No. 1-2. pp. 37-42.
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RIS
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TY - JOUR
DO - 10.1080/10426508908039689
UR - https://doi.org/10.1080/10426508908039689
TI - pπ-pπ Bonding Between Sulfur and the Heavier Elements of Group 15
T2 - Phosphorus, Sulfur and Silicon and the Related Elements
AU - Burford, Neil T.
AU - Royan, Bruce W.
PY - 1989
DA - 1989/01/01
PB - Taylor & Francis
SP - 37-42
IS - 1-2
VL - 41
SN - 1042-6507
SN - 1563-5325
SN - 1026-7719
ER -
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BibTex (up to 50 authors)
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@article{1989_Burford,
author = {Neil T. Burford and Bruce W. Royan},
title = {pπ-pπ Bonding Between Sulfur and the Heavier Elements of Group 15},
journal = {Phosphorus, Sulfur and Silicon and the Related Elements},
year = {1989},
volume = {41},
publisher = {Taylor & Francis},
month = {jan},
url = {https://doi.org/10.1080/10426508908039689},
number = {1-2},
pages = {37--42},
doi = {10.1080/10426508908039689}
}
Cite this
MLA
Copy
Burford, Neil T., and Bruce W. Royan. “pπ-pπ Bonding Between Sulfur and the Heavier Elements of Group 15.” Phosphorus, Sulfur and Silicon and the Related Elements, vol. 41, no. 1-2, Jan. 1989, pp. 37-42. https://doi.org/10.1080/10426508908039689.