Physical Review Applied, volume 15, issue 5, publication number 054009

Giant Third-Order Nonlinear Response of Liquids at Terahertz Frequencies

Tcypkin Anton N. ¹

Zhukova Maria O. ¹

Melnik Maksim ¹

Vorontsova Irina ¹

Kulya M.S. ¹

Putilin Sergey E. ¹

Putilin Sergey ¹

Kozlov S. ¹

Choudhary Saumya ²

Boyd Robert W. ^{2, 3}

Hide authors affiliations Show authors affiliations: 3 affiliations

Laboratory of Femtosecond Optics and Femtotechnology, ITMO University, Saint-Petersburg, 197101, Russia |

The Institute of Optics, University of Rochester, Rochester, New York 14627, USA |

Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada |

Publication type: Journal Article

Publication date: 2021-05-05

American Physical Society (APS)

Journal: Physical Review Applied

Quartile SCImago

Quartile WOS

Impact factor: 4.6

ISSN: 23317019

DOI: 10.1103/PhysRevApplied.15.054009

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General Physics and Astronomy

Abstract

The nonlinear response of liquids in the terahertz regime has recently attracted significant interest, even though very few measurements have been reported. Here, we report on our measurements based on a zscan technique of the nonlinear refractive-index coefficient n2 at terahertz frequencies for several liquids with noncentrosymmetric molecules, specifically, water, ethanol, and α-pinene. We describe how the value of n2 depends on the physical parameters of these molecules. The measured values of n2 of the liquids in the terahertz region are as much as 6 orders of magnitude larger than their corresponding values in the visible or near-IR. Through a simple theoretical model, we confirm that the predominant source of this large third-order nonlinearity is the second-order perturbative component of the vibrational response of these molecules, which have resonances in the mid-IR.

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Citations by journals

	1 2
Optics Express	Optics Express, 2, 8% Optics Express 2 publications, 8%
Journal of the Optical Society of America B: Optical Physics	Journal of the Optical Society of America B: Optical Physics, 1, 4% Journal of the Optical Society of America B: Optical Physics 1 publication, 4%
Scientific Reports	Scientific Reports, 1, 4% Scientific Reports 1 publication, 4%
Bulletin of the Russian Academy of Sciences: Physics	Bulletin of the Russian Academy of Sciences: Physics, 1, 4% Bulletin of the Russian Academy of Sciences: Physics 1 publication, 4%
Applied Physics Letters	Applied Physics Letters, 1, 4% Applied Physics Letters 1 publication, 4%
AIP Advances	AIP Advances, 1, 4% AIP Advances 1 publication, 4%
Review of Scientific Instruments	Review of Scientific Instruments, 1, 4% Review of Scientific Instruments 1 publication, 4%
Optics Letters	Optics Letters, 1, 4% Optics Letters 1 publication, 4%
Optical and Quantum Electronics	Optical and Quantum Electronics, 1, 4% Optical and Quantum Electronics 1 publication, 4%
European Physical Journal: Special Topics	European Physical Journal: Special Topics, 1, 4% European Physical Journal: Special Topics 1 publication, 4%
Chinese Journal of Chemical Physics	Chinese Journal of Chemical Physics, 1, 4% Chinese Journal of Chemical Physics 1 publication, 4%
Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 1, 4% Physical Chemistry Chemical Physics 1 publication, 4%
Opto-Electronic Science	Opto-Electronic Science, 1, 4% Opto-Electronic Science 1 publication, 4%
Advanced Optical Materials	Advanced Optical Materials, 1, 4% Advanced Optical Materials 1 publication, 4%
Infrared, Millimeter-Wave, and Terahertz Technologies IX	Infrared, Millimeter-Wave, and Terahertz Technologies IX, 1, 4% Infrared, Millimeter-Wave, and Terahertz Technologies IX 1 publication, 4%
IEEE Transactions on Terahertz Science and Technology	IEEE Transactions on Terahertz Science and Technology, 1, 4% IEEE Transactions on Terahertz Science and Technology 1 publication, 4%
	1 2

Citations by publishers

	1 2 3 4
Optical Society of America	Optical Society of America, 4, 16% Optical Society of America 4 publications, 16%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 4, 16% American Institute of Physics (AIP) 4 publications, 16%
Springer Nature	Springer Nature, 3, 12% Springer Nature 3 publications, 12%
IEEE	IEEE, 2, 8% IEEE 2 publications, 8%
Pleiades Publishing	Pleiades Publishing, 1, 4% Pleiades Publishing 1 publication, 4%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 4% Royal Society of Chemistry (RSC) 1 publication, 4%
Opto-Electronic Advances	Opto-Electronic Advances, 1, 4% Opto-Electronic Advances 1 publication, 4%
Wiley	Wiley, 1, 4% Wiley 1 publication, 4%
SPIE	SPIE, 1, 4% SPIE 1 publication, 4%
	1 2 3 4

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Tcypkin A. N. et al. Giant Third-Order Nonlinear Response of Liquids at Terahertz Frequencies // Physical Review Applied. 2021. Vol. 15. No. 5. 054009

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Tcypkin A. N., Zhukova M. O., Melnik M., Vorontsova I., Kulya M., Putilin S., Putilin S. E., Kozlov S., Choudhary S., Boyd R. W. Giant Third-Order Nonlinear Response of Liquids at Terahertz Frequencies // Physical Review Applied. 2021. Vol. 15. No. 5. 054009

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RIS Copy

TY - JOUR

DO - 10.1103/PhysRevApplied.15.054009

UR - https://doi.org/10.1103%2FPhysRevApplied.15.054009

TI - Giant Third-Order Nonlinear Response of Liquids at Terahertz Frequencies

T2 - Physical Review Applied

AU - Tcypkin, Anton N.

AU - Zhukova, Maria O.

AU - Melnik, Maksim

AU - Vorontsova, Irina

AU - Kulya, M.S.

AU - Putilin, Sergey

AU - Kozlov, S.

AU - Choudhary, Saumya

AU - Boyd, Robert W.

AU - Putilin, Sergey E.

PY - 2021

DA - 2021/05/05 00:00:00

PB - American Physical Society (APS)

IS - 5

VL - 15

SN - 2331-7019

ER -

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Cite this

BibTex Copy

@article{2021_Tcypkin,

author = {Anton N. Tcypkin and Maria O. Zhukova and Maksim Melnik and Irina Vorontsova and M.S. Kulya and Sergey Putilin and S. Kozlov and Saumya Choudhary and Robert W. Boyd and Sergey E. Putilin},

title = {Giant Third-Order Nonlinear Response of Liquids at Terahertz Frequencies},

journal = {Physical Review Applied},

year = {2021},

volume = {15},

publisher = {American Physical Society (APS)},

month = {may},

url = {https://doi.org/10.1103%2FPhysRevApplied.15.054009},

number = {5},

doi = {10.1103/PhysRevApplied.15.054009}

}

Found error?

Publisher

American Physical Society (APS)

Journal

Physical Review Applied

Quartile SCImago

Quartile WOS

Impact factor

4.6

ISSN

23317019 (Electronic)

Labs

Laboratory of Femtosecond Optics and Femtotechnology

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