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Physical Review Letters, volume 124, issue 20, publication number 203401

Mode-Specific Vibrational Autodetachment following Excitation of Electronic Resonances by Electrons and Photons

Mensa Bonsu Golda 1
Mensa-Bonsu Golda 1
Nag Pamir 2
Ranković Miloš 2
Boichenko Anton N. 3
Fedor J 2
Publication typeJournal Article
Publication date2020-05-19
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor8.6
ISSN00319007, 10797114
General Physics and Astronomy
Abstract
Electronic resonances commonly decay via internal conversion to vibrationally hot anions and subsequent statistical electron emission. We observed vibrational structure in such an emission from the nitrobenzene anion, in both the 2D electron energy loss and 2D photoelectron spectroscopy of the neutral and anion, respectively. The emission peaks could be correlated with calculated nonadiabatic coupling elements for vibrational modes to the electronic continuum from a nonvalence dipole-bound state. This autodetachment mechanism via a dipole-bound state is likely to be a common feature in both electron and photoelectron spectroscopies.

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Anstöter C. S. et al. Mode-Specific Vibrational Autodetachment following Excitation of Electronic Resonances by Electrons and Photons // Physical Review Letters. 2020. Vol. 124. No. 20. 203401
GOST all authors (up to 50) Copy
Anstöter C. S., Mensa Bonsu G., Mensa-Bonsu G., Nag P., Ranković M., Kumar T. P. R., Boichenko A. N., Bochenkova A. V., Fedor J., Verlet J. R. Mode-Specific Vibrational Autodetachment following Excitation of Electronic Resonances by Electrons and Photons // Physical Review Letters. 2020. Vol. 124. No. 20. 203401
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RIS Copy
TY - JOUR
DO - 10.1103/PhysRevLett.124.203401
UR - https://doi.org/10.1103%2FPhysRevLett.124.203401
TI - Mode-Specific Vibrational Autodetachment following Excitation of Electronic Resonances by Electrons and Photons
T2 - Physical Review Letters
AU - Anstöter, Cate S.
AU - Mensa Bonsu, Golda
AU - Nag, Pamir
AU - Ranković, Miloš
AU - Kumar T. P., Ragesh
AU - Boichenko, Anton N.
AU - Bochenkova, Anastasia V.
AU - Fedor, J
AU - Verlet, Jan R. R.
AU - Mensa-Bonsu, Golda
PY - 2020
DA - 2020/05/19 00:00:00
PB - American Physical Society (APS)
IS - 20
VL - 124
SN - 0031-9007
SN - 1079-7114
ER -
BibTex
Cite this
BibTex Copy
@article{2020_Anstöter,
author = {Cate S. Anstöter and Golda Mensa Bonsu and Pamir Nag and Miloš Ranković and Ragesh Kumar T. P. and Anton N. Boichenko and Anastasia V. Bochenkova and J Fedor and Jan R. R. Verlet and Golda Mensa-Bonsu},
title = {Mode-Specific Vibrational Autodetachment following Excitation of Electronic Resonances by Electrons and Photons},
journal = {Physical Review Letters},
year = {2020},
volume = {124},
publisher = {American Physical Society (APS)},
month = {may},
url = {https://doi.org/10.1103%2FPhysRevLett.124.203401},
number = {20},
doi = {10.1103/PhysRevLett.124.203401}
}
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