Open Access
Science, volume 309, issue 5732, pages 278-281
Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18
Troshin Pavel A.
1, 2, 3
,
Avent Anthony G.
1, 2, 3
,
Darwish Adam D
1, 2, 3
,
Martsinovich Natalia
1, 2, 3
,
Abdul-Sada Ala’a K.
1, 2, 3
,
Street Joan M
1, 2, 3
,
Taylor Roger
1, 2, 3
1
Chemistry Department, Sussex University, Brighton BN1 9QJ, UK.
|
Publication type: Journal Article
Publication date: 2005-07-08
Multidisciplinary
Abstract
Fluorination of C60 at 550°C leads to milligram quantities of two stable fullerene derivatives with 58-carbon cage structures: C58F18 and C58F17CF3. The compounds were characterized by mass spectrometry and fluorine nuclear magnetic resonance spectroscopy, and the data support a heptagonal ring in the framework. The resulting strain, which has hindered past attempts to prepare these smaller quasi-fullerenes, is mitigated here by hybridization change of some of the carbons in the pentagons from sp2 to sp3 because of fluorine addition. The loss of carbon from C60 is believed to occur via sequential fluorine addition to a C–C single bond and an adjacent C[dbond]C bond, followed by loss of a :CF2 carbene.
Citations by journals
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2 publications, 1.36%
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1 publication, 0.68%
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Physical Review Letters
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1 publication, 0.68%
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Physical Review B
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1 publication, 0.68%
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Materials
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Materials
1 publication, 0.68%
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Journal of Theoretical and Computational Chemistry
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Journal of Theoretical and Computational Chemistry
1 publication, 0.68%
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Frontiers in Chemistry
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Frontiers in Chemistry
1 publication, 0.68%
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Citations by publishers
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5
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35
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American Chemical Society (ACS)
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American Chemical Society (ACS)
35 publications, 23.81%
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Wiley
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Wiley
35 publications, 23.81%
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Elsevier
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19 publications, 12.93%
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Royal Society of Chemistry (RSC)
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16 publications, 10.88%
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Springer Nature
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10 publications, 6.8%
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American Institute of Physics (AIP)
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7 publications, 4.76%
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Taylor & Francis
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4 publications, 2.72%
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American Physical Society (APS)
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2 publications, 1.36%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 0.68%
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World Scientific
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World Scientific
1 publication, 0.68%
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Frontiers Media S.A.
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Frontiers Media S.A.
1 publication, 0.68%
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IOP Publishing
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IOP Publishing
1 publication, 0.68%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 0.68%
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SPIE
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SPIE
1 publication, 0.68%
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Thieme
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Thieme
1 publication, 0.68%
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5
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35
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Troshin P. A. et al. Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18 // Science. 2005. Vol. 309. No. 5732. pp. 278-281.
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Troshin P. A., Avent A. G., Darwish A. D., Martsinovich N., Abdul-Sada A. K., Street J. M., Taylor R. Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18 // Science. 2005. Vol. 309. No. 5732. pp. 278-281.
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RIS
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TY - JOUR
DO - 10.1126/science.1111904
UR - https://doi.org/10.1126%2Fscience.1111904
TI - Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18
T2 - Science
AU - Troshin, Pavel A.
AU - Avent, Anthony G.
AU - Darwish, Adam D
AU - Martsinovich, Natalia
AU - Abdul-Sada, Ala’a K.
AU - Street, Joan M
AU - Taylor, Roger
PY - 2005
DA - 2005/07/08 00:00:00
PB - American Association for the Advancement of Science (AAAS)
SP - 278-281
IS - 5732
VL - 309
SN - 0036-8075
SN - 1095-9203
ER -
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@article{2005_Troshin,
author = {Pavel A. Troshin and Anthony G. Avent and Adam D Darwish and Natalia Martsinovich and Ala’a K. Abdul-Sada and Joan M Street and Roger Taylor},
title = {Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18},
journal = {Science},
year = {2005},
volume = {309},
publisher = {American Association for the Advancement of Science (AAAS)},
month = {jul},
url = {https://doi.org/10.1126%2Fscience.1111904},
number = {5732},
pages = {278--281},
doi = {10.1126/science.1111904}
}
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MLA
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Troshin, Pavel A., et al. “Isolation of Two Seven-Membered Ring C58 Fullerene Derivatives: C58F17CF3 and C58F18.” Science, vol. 309, no. 5732, Jul. 2005, pp. 278-281. https://doi.org/10.1126%2Fscience.1111904.
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