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Petroleum Chemistry, volume 61, issue 7, pages 794-805

Novel Molybdenite-Based Nanopowder Catalysts for Hydrodesulfurization

Publication typeJournal Article
Publication date2021-07-07
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.4
ISSN09655441, 15556239
General Chemistry
General Chemical Engineering
Geochemistry and Petrology
Energy Engineering and Power Technology
Fuel Technology
Abstract
Novel bulk single-component sulfide catalysts were prepared under the conditions of solid-phase dispersion of МoS2 molybdenite at various mechanical treatment times and various amounts of polar and nonpolar liquid microadditives. The chemical degradation of the samples in the air was found to lead to the formation of surface sulfate anions that shield catalytically active Mo sites. Indirect correlations of the hydrodesulfurization ability of MoS2 powders with the concentration of sulfate anions on their surface, and with the aqueous pH in the powder suspensions, including the dielectric permittivity of the organic dopants, can serve as reference indicators of high catalytic activity in the model reaction of dibenzothiophene hydrogenolysis. The study identified the most active sample able to run for an extended time during multiple cycles without losing its catalytic properties. Also, the paper discusses the dibenzothiophene conversion routes, the product composition, the probable structure of active sites in the catalysts, and the desulfurization degree of diesel fuel components.

Citations by journals

1
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Citations by publishers

1
Multidisciplinary Digital Publishing Institute (MDPI)
Multidisciplinary Digital Publishing Institute (MDPI), 1, 33.33%
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 33.33%
Pleiades Publishing
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1
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Feduschak T. et al. Novel Molybdenite-Based Nanopowder Catalysts for Hydrodesulfurization // Petroleum Chemistry. 2021. Vol. 61. No. 7. pp. 794-805.
GOST all authors (up to 50) Copy
Feduschak T., Uimin M., Maikov V. V., Akimov A. S., Zhuravkov S. P., Vosmerikov A. V., Prosvirin I. P., Velichkina L. M., Stepanov A. A., Kogan V. Novel Molybdenite-Based Nanopowder Catalysts for Hydrodesulfurization // Petroleum Chemistry. 2021. Vol. 61. No. 7. pp. 794-805.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0965544121070033
UR - https://doi.org/10.1134%2FS0965544121070033
TI - Novel Molybdenite-Based Nanopowder Catalysts for Hydrodesulfurization
T2 - Petroleum Chemistry
AU - Feduschak, Taisia
AU - Uimin, M.A.
AU - Maikov, V V
AU - Akimov, A S
AU - Zhuravkov, S P
AU - Vosmerikov, A V
AU - Prosvirin, Igor P.
AU - Velichkina, L M
AU - Stepanov, A A
AU - Kogan, V.M
PY - 2021
DA - 2021/07/07 00:00:00
PB - Pleiades Publishing
SP - 794-805
IS - 7
VL - 61
SN - 0965-5441
SN - 1555-6239
ER -
BibTex |
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BibTex Copy
@article{2021_Feduschak,
author = {Taisia Feduschak and M.A. Uimin and V V Maikov and A S Akimov and S P Zhuravkov and A V Vosmerikov and Igor P. Prosvirin and L M Velichkina and A A Stepanov and V.M Kogan},
title = {Novel Molybdenite-Based Nanopowder Catalysts for Hydrodesulfurization},
journal = {Petroleum Chemistry},
year = {2021},
volume = {61},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134%2FS0965544121070033},
number = {7},
pages = {794--805},
doi = {10.1134/S0965544121070033}
}
MLA
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MLA Copy
Feduschak, Taisia, et al. “Novel Molybdenite-Based Nanopowder Catalysts for Hydrodesulfurization.” Petroleum Chemistry, vol. 61, no. 7, Jul. 2021, pp. 794-805. https://doi.org/10.1134%2FS0965544121070033.
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