Russian Journal of Organic Chemistry, volume 53, issue 4, pages 485-509

Trifluoromethanesulfonic acid in organic synthesis

Publication typeJournal Article
Publication date2017-04-01
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor0.8
ISSN10704280, 16083393
Organic Chemistry
Abstract
The review analyzes data published in the past decade on the use of trifluoromethanesulfonic acid (triflic acid, CF3SO3H, TfOH) in organic synthesis, in particular in electrophilic aromatic substitution (Friedel–Crafts) reactions, formation of carbon–carbon and carbon–heteroatom bonds, isomerizations, syntheses of carboand heterocyclic structures, and other reactions, as well as in natural and organometallic compounds chemistry. The high protonating power and low nucleophilicity makes trifluoromethanesulfonic acid capable of generating from organic molecules cationic species which can be detected by spectral methods (NMR, IR spectroscopy, etc.), and their transformations can be studied. Experimental simplicity and efficiency of reactions promoted by trifluoromethanesulfonic acid make it a convenient reagent for the synthesis of new organic compounds.

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Kazakova A. N., Vasilyev A. V. Trifluoromethanesulfonic acid in organic synthesis // Russian Journal of Organic Chemistry. 2017. Vol. 53. No. 4. pp. 485-509.
GOST all authors (up to 50) Copy
Kazakova A. N., Vasilyev A. V. Trifluoromethanesulfonic acid in organic synthesis // Russian Journal of Organic Chemistry. 2017. Vol. 53. No. 4. pp. 485-509.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S1070428017040017
UR - https://doi.org/10.1134%2FS1070428017040017
TI - Trifluoromethanesulfonic acid in organic synthesis
T2 - Russian Journal of Organic Chemistry
AU - Kazakova, A N
AU - Vasilyev, A. V.
PY - 2017
DA - 2017/04/01 00:00:00
PB - Pleiades Publishing
SP - 485-509
IS - 4
VL - 53
SN - 1070-4280
SN - 1608-3393
ER -
BibTex |
Cite this
BibTex Copy
@article{2017_Kazakova,
author = {A N Kazakova and A. V. Vasilyev},
title = {Trifluoromethanesulfonic acid in organic synthesis},
journal = {Russian Journal of Organic Chemistry},
year = {2017},
volume = {53},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134%2FS1070428017040017},
number = {4},
pages = {485--509},
doi = {10.1134/S1070428017040017}
}
MLA
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MLA Copy
Kazakova, A. N., et al. “Trifluoromethanesulfonic acid in organic synthesis.” Russian Journal of Organic Chemistry, vol. 53, no. 4, Apr. 2017, pp. 485-509. https://doi.org/10.1134%2FS1070428017040017.
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