Thermolysis of thiete 1,1-dioxide and related species
Publication type: Journal Article
Publication date: 1970-12-01
scimago Q3
wos Q4
SJR: 0.254
CiteScore: 2.0
Impact factor: 1.0
ISSN: 00084042, 14803291
DOI:
10.1139/v70-619
General Chemistry
Catalysis
Organic Chemistry
Abstract
Thiete 1,1-dioxide (1) rearranges to 5H-1,2-oxathiole-2-oxide (3) on heating in solution or in the vapor phase. The presence of phenol in the solution leads to formation of phenyl 2-propene-1-sulfonate (CH2=CHCH2SO2OPh) in 15% yield. The results are rationalized in terms of a mechanism involving vinylsulfene (2). Flash thermolysis of some thietane 1,1-dioxides (16) and 3-thietanone 1,1-dioxides (15) gave products derived from extrusion processes, but 3-thietanol 1,1-dioxide (17) yielded, among other products, acetaldehyde and formaldehyde. The latter is believed to arise by "desulfinylation" of sulfene (CH2=SO2) formed along with the enol form of acetaldehyde by cycloreversion from 17.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
|
|
|
Tetrahedron Letters
11 publications, 12.94%
|
|
|
Tetrahedron
8 publications, 9.41%
|
|
|
Angewandte Chemie
5 publications, 5.88%
|
|
|
Chemistry of Functional Groups
4 publications, 4.71%
|
|
|
Journal of Organometallic Chemistry
3 publications, 3.53%
|
|
|
Journal of Heterocyclic Chemistry
3 publications, 3.53%
|
|
|
Sulfur Reports
3 publications, 3.53%
|
|
|
Organic Chemistry
3 publications, 3.53%
|
|
|
Bulletin of the Chemical Society of Japan
2 publications, 2.35%
|
|
|
International Journal of Chemical Kinetics
2 publications, 2.35%
|
|
|
Chemische Berichte
2 publications, 2.35%
|
|
|
Synthetic Communications
2 publications, 2.35%
|
|
|
Cumulative Index of Heterocyclic Systems
2 publications, 2.35%
|
|
|
Organic Letters
1 publication, 1.18%
|
|
|
Chemical Reviews
1 publication, 1.18%
|
|
|
Angewandte Chemie - International Edition
1 publication, 1.18%
|
|
|
Chemistry of Heterocyclic Compounds
1 publication, 1.18%
|
|
|
Russian Chemical Reviews
1 publication, 1.18%
|
|
|
Journal of Analytical and Applied Pyrolysis
1 publication, 1.18%
|
|
|
Journal of Molecular Structure
1 publication, 1.18%
|
|
|
Chemical Physics Letters
1 publication, 1.18%
|
|
|
Chemischer Informationsdienst Organische Chemie
1 publication, 1.18%
|
|
|
Fette Seifen Anstrichmittel
1 publication, 1.18%
|
|
|
Recueil des Travaux Chimiques des Pays-Bas
1 publication, 1.18%
|
|
|
Journal für praktische Chemie
1 publication, 1.18%
|
|
|
Phosphorous and Sulfur and the Related Elements
1 publication, 1.18%
|
|
|
Bulletin des Sociétés Chimiques Belges
1 publication, 1.18%
|
|
|
Synthetic and Stereochemical Aspects
1 publication, 1.18%
|
|
|
Palladium in Heterocyclic Chemistry - A Guide for the Synthetic Chemist
1 publication, 1.18%
|
|
|
2
4
6
8
10
12
|
Publishers
|
5
10
15
20
25
30
35
40
|
|
|
Elsevier
40 publications, 47.06%
|
|
|
Wiley
27 publications, 31.76%
|
|
|
Taylor & Francis
6 publications, 7.06%
|
|
|
American Chemical Society (ACS)
2 publications, 2.35%
|
|
|
The Chemical Society of Japan
2 publications, 2.35%
|
|
|
Springer Nature
1 publication, 1.18%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.18%
|
|
|
Shanghai Institute of Organic Chemistry
1 publication, 1.18%
|
|
|
5
10
15
20
25
30
35
40
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
85
Total citations:
85
Citations from 2024:
3
(3%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
KING J. F. et al. Thermolysis of thiete 1,1-dioxide and related species // Canadian Journal of Chemistry. 1970. Vol. 48. No. 23. pp. 3704-3715.
GOST all authors (up to 50)
Copy
KING J. F., Mayo P. D., McIntosh C. L., Piers K., Smith D. J. H., Smith D. C. Thermolysis of thiete 1,1-dioxide and related species // Canadian Journal of Chemistry. 1970. Vol. 48. No. 23. pp. 3704-3715.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1139/v70-619
UR - https://doi.org/10.1139/v70-619
TI - Thermolysis of thiete 1,1-dioxide and related species
T2 - Canadian Journal of Chemistry
AU - KING, J F
AU - Mayo, P. de
AU - McIntosh, C L
AU - Piers, K.
AU - Smith, David J. H.
AU - Smith, David C.
PY - 1970
DA - 1970/12/01
PB - Canadian Science Publishing
SP - 3704-3715
IS - 23
VL - 48
SN - 0008-4042
SN - 1480-3291
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1970_KING,
author = {J F KING and P. de Mayo and C L McIntosh and K. Piers and David J. H. Smith and David C. Smith},
title = {Thermolysis of thiete 1,1-dioxide and related species},
journal = {Canadian Journal of Chemistry},
year = {1970},
volume = {48},
publisher = {Canadian Science Publishing},
month = {dec},
url = {https://doi.org/10.1139/v70-619},
number = {23},
pages = {3704--3715},
doi = {10.1139/v70-619}
}
Cite this
MLA
Copy
KING, J. F., et al. “Thermolysis of thiete 1,1-dioxide and related species.” Canadian Journal of Chemistry, vol. 48, no. 23, Dec. 1970, pp. 3704-3715. https://doi.org/10.1139/v70-619.