volume 15 issue 2 pages 231-238

Preliminary Silylation for Structure Determination of Oligomeric Silsesquioxanes by Matrix-Assisted Laser Desorption/Ionisation Mass Spectrometry

Publication typeJournal Article
Publication date2009-04-01
scimago Q4
wos Q4
SJR0.243
CiteScore1.6
Impact factor0.8
ISSN14690667, 17516838, 13561049
PubMed ID:  19423908
Spectroscopy
General Medicine
Atomic and Molecular Physics, and Optics
Abstract

The potential of preliminary silylation for the determination of numbers of hydroxyl groups in separate molecules of oligomeric silsesquioxanes by matrix-assisted laser desorption/ionisation mass spectrometry has been demonstrated for the first time. Derivatisations allowing the introduction of trimethylsilyl, tert-butyldimethylsilyl and pentafluorophenyldimethylsilyl groups were tested. It was shown that more reliable structure elucidation of individual oligomers can be achieved knowing the number of hydroxyl groups thus determined.

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GOST Copy
Zaikin V. G. et al. Preliminary Silylation for Structure Determination of Oligomeric Silsesquioxanes by Matrix-Assisted Laser Desorption/Ionisation Mass Spectrometry // European Journal of Mass Spectrometry. 2009. Vol. 15. No. 2. pp. 231-238.
GOST all authors (up to 50) Copy
Zaikin V. G., Borisov R. S., Polovkov N. Yu., Filatov S. N., Kireev V. V. Preliminary Silylation for Structure Determination of Oligomeric Silsesquioxanes by Matrix-Assisted Laser Desorption/Ionisation Mass Spectrometry // European Journal of Mass Spectrometry. 2009. Vol. 15. No. 2. pp. 231-238.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1255/ejms.946
UR - https://doi.org/10.1255/ejms.946
TI - Preliminary Silylation for Structure Determination of Oligomeric Silsesquioxanes by Matrix-Assisted Laser Desorption/Ionisation Mass Spectrometry
T2 - European Journal of Mass Spectrometry
AU - Zaikin, V. G.
AU - Borisov, Roman S.
AU - Polovkov, N Yu
AU - Filatov, S N
AU - Kireev, V. V.
PY - 2009
DA - 2009/04/01
PB - SAGE
SP - 231-238
IS - 2
VL - 15
PMID - 19423908
SN - 1469-0667
SN - 1751-6838
SN - 1356-1049
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Zaikin,
author = {V. G. Zaikin and Roman S. Borisov and N Yu Polovkov and S N Filatov and V. V. Kireev},
title = {Preliminary Silylation for Structure Determination of Oligomeric Silsesquioxanes by Matrix-Assisted Laser Desorption/Ionisation Mass Spectrometry},
journal = {European Journal of Mass Spectrometry},
year = {2009},
volume = {15},
publisher = {SAGE},
month = {apr},
url = {https://doi.org/10.1255/ejms.946},
number = {2},
pages = {231--238},
doi = {10.1255/ejms.946}
}
MLA
Cite this
MLA Copy
Zaikin, V. G., et al. “Preliminary Silylation for Structure Determination of Oligomeric Silsesquioxanes by Matrix-Assisted Laser Desorption/Ionisation Mass Spectrometry.” European Journal of Mass Spectrometry, vol. 15, no. 2, Apr. 2009, pp. 231-238. https://doi.org/10.1255/ejms.946.