Open Access
Crystals, volume 10, issue 8, pages 674
New Mononuclear Complex of Europium(III) and Benzoic Acid: From Synthesis and Crystal Structure Solution to Luminescence Emission
Hernández Fuentes Carlos
1
,
Ruiz Guerrero Rosario
1
,
Morales-Ramírez Á. de J.
1, 2
,
Molina Maldonado Paulina
1
,
Medina Velazquez Dulce
3
1
Centro de Investigación e Innovación Tecnológica, Instituto Politécnico Nacional, cerrada de Cecati Sta. Catarina Azcapotzalco CP. 02250 CDMX, Mexico
|
2
Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, Av. Luis Enrique Erro S/N, Unidad Profesional Adolfo López Mateos, Zacatenco, GAM, C.P. 07738 CDMX, Mexico
|
3
División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Azcapotzalco, C.P. 02200 CDMX, Mexico
|
Publication type: Journal Article
Publication date: 2020-08-04
Inorganic Chemistry
General Chemical Engineering
Condensed Matter Physics
General Materials Science
Abstract
This study presents a general method which can be used for the synthesis of mononuclear complexes with europium(III) and organic ligands with carboxylic groups. It describes the procedure for preparing a new mononuclear coordination complex with europium(III) and carboxylate ligands sourced from benzoic acid. The construction of mononuclear complexes with a coordination sphere saturated in carboxylic ligands must go through the preparation and purification of a europium(III) intermediate complex that presents a coordination sphere with anions that will be later exchanged for carboxylic groups and finally precipitated as a solvent-free or anion-free complex within the coordination sphere. The detailed synthesis procedure for powders of a new complex, as well as studies of its structural composition at each phase and luminescent properties, are detailed in this study. Analytical and spectroscopic data reveal the formation of a new mononuclear complex of the general formula [Eu(OOCC6H5)3·(HOOCC6H5)2]. The crystal structure of the Eu(III) complex was solved using X-ray powder diffraction data and EXPO2014 software, and the crystal structure result was deposited in the CCDC service with number 19771999.
Citations by journals
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1
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Journal of Alloys and Compounds
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Journal of Alloys and Compounds
1 publication, 14.29%
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Metals
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Metals
1 publication, 14.29%
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Dyes and Pigments
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Dyes and Pigments
1 publication, 14.29%
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Coloration Technology
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Coloration Technology
1 publication, 14.29%
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Dalton Transactions
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Dalton Transactions
1 publication, 14.29%
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Journal of Luminescence
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Journal of Luminescence
1 publication, 14.29%
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Materials
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Materials
1 publication, 14.29%
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1
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Citations by publishers
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1
2
3
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Elsevier
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Elsevier
3 publications, 42.86%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 28.57%
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Wiley
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Wiley
1 publication, 14.29%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 14.29%
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1
2
3
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Hernández Fuentes C. et al. New Mononuclear Complex of Europium(III) and Benzoic Acid: From Synthesis and Crystal Structure Solution to Luminescence Emission // Crystals. 2020. Vol. 10. No. 8. p. 674.
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Hernández Fuentes C., Ruiz Guerrero R., Morales-Ramírez &. D. J., Molina Maldonado P., Medina Velazquez D. New Mononuclear Complex of Europium(III) and Benzoic Acid: From Synthesis and Crystal Structure Solution to Luminescence Emission // Crystals. 2020. Vol. 10. No. 8. p. 674.
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TY - JOUR
DO - 10.3390/cryst10080674
UR - https://doi.org/10.3390%2Fcryst10080674
TI - New Mononuclear Complex of Europium(III) and Benzoic Acid: From Synthesis and Crystal Structure Solution to Luminescence Emission
T2 - Crystals
AU - Hernández Fuentes, Carlos
AU - Ruiz Guerrero, Rosario
AU - Molina Maldonado, Paulina
AU - Medina Velazquez, Dulce
AU - Morales-Ramírez, Á. de J.
PY - 2020
DA - 2020/08/04 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 674
IS - 8
VL - 10
SN - 2073-4352
SN - 0172-5076
ER -
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@article{2020_Hernández Fuentes,
author = {Carlos Hernández Fuentes and Rosario Ruiz Guerrero and Paulina Molina Maldonado and Dulce Medina Velazquez and Á. de J. Morales-Ramírez},
title = {New Mononuclear Complex of Europium(III) and Benzoic Acid: From Synthesis and Crystal Structure Solution to Luminescence Emission},
journal = {Crystals},
year = {2020},
volume = {10},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {aug},
url = {https://doi.org/10.3390%2Fcryst10080674},
number = {8},
pages = {674},
doi = {10.3390/cryst10080674}
}
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Hernández Fuentes, Carlos, et al. “New Mononuclear Complex of Europium(III) and Benzoic Acid: From Synthesis and Crystal Structure Solution to Luminescence Emission.” Crystals, vol. 10, no. 8, Aug. 2020, p. 674. https://doi.org/10.3390%2Fcryst10080674.