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Open access
Molecules, том 27, издание 20, номер публикации: 7029

Morphotropic Phase Boundary Enhanced Photocatalysis in Sm Doped BiFeO3

Orudzhev Farid 1, 2, 3
Sobola Dinara 2, 4, 5
Murtazali Rabadanov Kh. 2
Ismailov Etibar H. 6
Aliev Akif Sh. 6
Department of Physics, Faculty of Electrical Engineering and Communication, Brno University of Technology, Technicka 10, 616 00 Brno, Czech Republic
Central European Institute of Technology, Purkyňova 656/123, 612 00 Brno, Czech Republic
Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, H. Cavid Ave. 113, AZ 1143 Baku, Azerbaijan
Institute of Radiation Problems, Azerbaijan National Academy of Sciences, 9 B. Vahabzade Str., AZ 1143 Baku, Azerbaijan
Directorate of Research, Development and Innovation Management (DMCDI), Technical University of Cluj-Napoca, Constantin Daicoviciu Street, No. 15, 400020 Cluj-Napoca, Romania
Тип документа
Дата публикации2022-10-18
ИздательMultidisciplinary Digital Publishing Institute (MDPI)
Название журналаMolecules
Квартиль по SCImagoQ1
Квартиль по Web of ScienceQ2
Импакт-фактор 20214.93
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Краткое описание
This paper presents the results of the synthesis of samarium-doped bismuth ferrite (BFO) nanoparticles by the solution combustion method. The dependence of BFO properties on the amount of the samarium (Sm) in the composition was studied. The synthesized nanocomposites were characterized by scanning electron microscopy SEM), X-ray diffractometry (XRD), Raman, Electron Diffuse Reflectance Spectroscopy (EDRS) and Electron Magnetic Resonance (EMR). The photocatalytic (PC) measurements showed the absence of a strict correlation between the PC activity and the crystallite size and band gap. An increase in the PC activity of BFO samples with 10 and 15% doping was observed and it was concluded that in controlling the PC properties in doped BFO, the processes of interfacial polarization at the boundaries of the morphotropic phase transition are of decisive importance. It was supposed that the internal electric field formed at these boundaries contributes to the efficient separation of photogenerated charge carriers.
Пристатейные ссылки: 64


1. Orudzhev F. F. и др. Morphotropic Phase Boundary Enhanced Photocatalysis in Sm Doped BiFeO3 // Molecules. 2022. Т. 27. № 20. С. 7029.


DO - 10.3390/molecules27207029

UR -

TI - Morphotropic Phase Boundary Enhanced Photocatalysis in Sm Doped BiFeO3

T2 - Molecules

AU - Orudzhev, Farid F.

AU - Alikhanov, Nariman M.-R.

AU - Ramazanov, Shikhgasan M.

AU - Sobola, Dinara S.

AU - Murtazali, Rabadanov Kh.

AU - Ismailov, Etibar H.

AU - Gasimov, Rashid D.

AU - Aliev, Akif Sh.

AU - Ţălu, Ştefan

PY - 2022

DA - 2022/10/18


SP - 7029

IS - 20

VL - 27

SN - 1420-3049

ER -

BibTex |


doi = {10.3390/molecules27207029},

url = {},

year = 2022,

month = {oct},

publisher = {{MDPI} {AG}},

volume = {27},

number = {20},

pages = {7029},

author = {Farid F. Orudzhev and Nariman M.-R. Alikhanov and Shikhgasan M. Ramazanov and Dinara S. Sobola and Rabadanov Kh. Murtazali and Etibar H. Ismailov and Rashid D. Gasimov and Akif Sh. Aliev and {\c{S}}tefan {\c{T}}{\u{a}}lu},

title = {Morphotropic Phase Boundary Enhanced Photocatalysis in Sm Doped {BiFeO}3},

journal = {Molecules}


Orudzhev, Farid F., et al. “Morphotropic Phase Boundary Enhanced Photocatalysis in Sm Doped BiFeO3.” Molecules, vol. 27, no. 20, Oct. 2022, p. 7029. Crossref,