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Molecules, volume 27, issue 22, pages 7725
Coordination Polymers of Polyphenyl-Substituted Potassium Cyclopentadienides
Komarov Pavel D.
1
,
Birin Kirill P.
2
,
Vinogradov Alexander A
1
,
Varaksina Evgenia A.
1, 3
,
Puntus Lada N.
1, 4, 5
,
Nifant'ev Ilya E.
1, 6
,
Minyaev Mikhail E.
1, 8
,
Roitershtein Dmitrii M.
1, 8, 9
Publication type: Journal Article
Publication date: 2022-11-09
PubMed ID:
36431825
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
A series of potassium salts of di- and tri-arylsubstituted cyclopentadienes has been obtained by the metalation of the corresponding cyclopentadienes with benzylpotassium in THF media. Crystals of all compounds, afforded by recrystallization from THF/hexane, diglyme-THF/hexane and toluene/hexane mixtures, have been studied by X-ray diffraction. All studied potassium cyclopentadienides exhibit the luminescence at room temperature and overall quantum yield of photoluminescence for potassium salt of diarylsubstituted cyclopentadiene is 18%.
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Komarov P. D. et al. Coordination Polymers of Polyphenyl-Substituted Potassium Cyclopentadienides // Molecules. 2022. Vol. 27. No. 22. p. 7725.
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Komarov P. D., Birin K. P., Vinogradov A. A., Varaksina E. A., Puntus L. N., Lyssenko K. A., Churakov A. V., Nifant'ev I. E., Minyaev M. E., Roitershtein D. M. Coordination Polymers of Polyphenyl-Substituted Potassium Cyclopentadienides // Molecules. 2022. Vol. 27. No. 22. p. 7725.
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TY - JOUR
DO - 10.3390/molecules27227725
UR - https://doi.org/10.3390%2Fmolecules27227725
TI - Coordination Polymers of Polyphenyl-Substituted Potassium Cyclopentadienides
T2 - Molecules
AU - Komarov, Pavel D.
AU - Birin, Kirill P.
AU - Vinogradov, Alexander A
AU - Varaksina, Evgenia A.
AU - Puntus, Lada N.
AU - Lyssenko, Konstantin A.
AU - Churakov, Andrei V.
AU - Nifant'ev, Ilya E.
AU - Minyaev, Mikhail E.
AU - Roitershtein, Dmitrii M.
PY - 2022
DA - 2022/11/09 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 7725
IS - 22
VL - 27
PMID - 36431825
SN - 1420-3049
ER -
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@article{2022_Komarov,
author = {Pavel D. Komarov and Kirill P. Birin and Alexander A Vinogradov and Evgenia A. Varaksina and Lada N. Puntus and Konstantin A. Lyssenko and Andrei V. Churakov and Ilya E. Nifant'ev and Mikhail E. Minyaev and Dmitrii M. Roitershtein},
title = {Coordination Polymers of Polyphenyl-Substituted Potassium Cyclopentadienides},
journal = {Molecules},
year = {2022},
volume = {27},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {nov},
url = {https://doi.org/10.3390%2Fmolecules27227725},
number = {22},
pages = {7725},
doi = {10.3390/molecules27227725}
}
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Komarov, Pavel D., et al. “Coordination Polymers of Polyphenyl-Substituted Potassium Cyclopentadienides.” Molecules, vol. 27, no. 22, Nov. 2022, p. 7725. https://doi.org/10.3390%2Fmolecules27227725.